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Cell Molecules
Cell Molecules

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... • The boiling points of aldehydes and ketones are higher than hydrocarbons and ethers due to dipole dipoe interaction and lower than those of alcohols due to absence of intermolecular hydrogen bonding. • The lower members of aldehydes and ketones are miscible with water due to hydrogen bonding. 1. C ...
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CHEMICAL REACTIONS
CHEMICAL REACTIONS

... (s) after the formula –solid Cu(s) (g) after the formula –gas H2 (g) (l) after the formula -liquid H2O(l) (aq) after the formula - dissolved in water, an aqueous solution. CaCl2 (aq) used after a product indicates a gas (same as (g)) O2 used after a product indicates a solid (same as (s)) ...
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... electronegative than carbon, and so exserts a stronger pull on the shared electrons in the carbon-halogen bond. ■ As a result, the halogen gains a partial negative charge and the carbon gains a partial positive charge, and it is said to be electron deficient. ...
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Asymmetric induction



Asymmetric induction (also enantioinduction) in stereochemistry describes the preferential formation in a chemical reaction of one enantiomer or diastereoisomer over the other as a result of the influence of a chiral feature present in the substrate, reagent, catalyst or environment. Asymmetric induction is a key element in asymmetric synthesis.Asymmetric induction was introduced by Hermann Emil Fischer based on his work on carbohydrates. Several types of induction exist.Internal asymmetric induction makes use of a chiral center bound to the reactive center through a covalent bond and remains so during the reaction. The starting material is often derived from chiral pool synthesis. In relayed asymmetric induction the chiral information is introduced in a separate step and removed again in a separate chemical reaction. Special synthons are called chiral auxiliaries. In external asymmetric induction chiral information is introduced in the transition state through a catalyst of chiral ligand. This method of asymmetric synthesis is economically most desirable.
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