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Ch 22: Organic Chemistry
Ch 22: Organic Chemistry

... number. If numbering from both ends gives the same numbers, then number from the end nearest the first alkyl group. 4. Insert Position Numbers: place double-bond position numbers before the name of the parent hydrocarbon and the alkyl group position numbers before the name of the corresponding alkyl ...
chapter 4 carbon and the molecular diversity of life
chapter 4 carbon and the molecular diversity of life

... isomers can dramatically affect the biological activities of organic molecules. For example, the biochemistry of vision involves a light-induced change of rhodopsin, a chemical compound in the eye, from one geometric isomer to another. Enantiomers are molecules that are mirror images of each other. ...
chapter 12_13_14_16_17 Organic Nomenclature
chapter 12_13_14_16_17 Organic Nomenclature

... ► Very similar rules as for alkanes ► Additional rules: ►Choose longest chain that contains the double or triple bond ►Suffix for alkenes: -ene ►Suffix for alkynes: -yne ►Include a number with the parent to indicate which carbon the double/triple bond starts on. ...
2 Chemical bonding is a genuinely quantum effect, which cannot be
2 Chemical bonding is a genuinely quantum effect, which cannot be

... • Hybridization: clearly, an sp3 carbon with four single bonds differs from an sp2 carbon with a double bond or even an sp carbon with a triple bond. So, we need different potentials for the C–C, C=C and C≡C bonds. Also, there will be various different C atom types as well, like an aromatic carbon e ...
chem1a_ch02_lecture - Santa Rosa Junior College
chem1a_ch02_lecture - Santa Rosa Junior College

... the same number of electrons as 18Ar. The ion is Ca2+ (c) Aluminum is a metal in Group 13. It loses three electrons to have the same number of electrons as 10Ne. The ion is Al3+ ...
chem1a_ch02_lecture - Santa Rosa Junior College
chem1a_ch02_lecture - Santa Rosa Junior College

... the same number of electrons as 18Ar. The ion is Ca2+ (c) Aluminum is a metal in Group 13. It loses three electrons to have the same number of electrons as 10Ne. The ion is Al3+ ...
Chapter 5. ACIDITY AND BASICITY OF ORGANIC COMPOUNDS
Chapter 5. ACIDITY AND BASICITY OF ORGANIC COMPOUNDS

... electrons are far from the nucleus is much more polarizable than fluorine whose electrons are close to the nucleus. Thus, polarizability of halogens increases in the following order: F < Cl < Br < I. Stability of the corresponding halide ions increases in the same order. Problem 5.2. Fluorine is muc ...
chemistry in the 8th grade
chemistry in the 8th grade

... they can share electrons with other atoms to achieve a stable configuration. Ionic Bonds: The first way that atoms can form chemical bonds to build molecules is by loss or gain of electrons. Atoms with 3 or fewer outer (valence) electrons can lose electrons to gain a stable configuration. Take the s ...
GRADE 12A: Chemistry 6
GRADE 12A: Chemistry 6

... Ask students to use the library or the Internet to research the work of Otto Witt and describe his contribution to the azo dye industry. Also ask them to research azo dye production worldwide and present the data in a suitable format. Describe to the whole class the stages of synthesising an azo dye ...
Final Exam from 2006 - Department of Chemistry | Oregon State
Final Exam from 2006 - Department of Chemistry | Oregon State

ELECTROLYSIS G10 worksheet for Electrloysis
ELECTROLYSIS G10 worksheet for Electrloysis

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... The Electron Paramagnetic Resonance (EPR) and magnetic research are a very useful technique for investigation of complexation of gadolinium complexes, although so far, there are not enough reports on EPR spectra of these complexes. Current interest in new gadolinium compounds derives from their pot ...
Worksheet 3A on Molecules
Worksheet 3A on Molecules

... Of the species listed, only O3 and CO are polar. CO is polar due to the difference in electronegativity between O and C; O3 is polar because it has 3 RHED and one lone pair on the central atom. This lone pair is an area where negative charge is concentrated, so this results in the molecule having an ...
ether - TeacherWeb
ether - TeacherWeb

... •The hydroxyl group can also be attached to an aromatic hydrocarbon. •Phenol: An organic compound that has a hydroxyl group bonded to a benzene ring. **In a case where benzene has multiple hydroxyl groups, benzene is used as the root word. ...
23 • Organic Chemistry
23 • Organic Chemistry

... He usually allowed the salt solution to evaporate overnight, but tried heating it to hurry the process. The result was a crystal that he recognized as urea (H2NCONH2). ...
alcohol - Portal UniMAP
alcohol - Portal UniMAP

Chapter 2 - Chemistry
Chapter 2 - Chemistry

... Atomic Symbols and Models Atomic symbol - a one- or two-letter notation used to represent an atom corresponding to a particular element - convention: first letter capital second letter lowercase - origin: from the name of the element from a name in another language (Latin) Atomic Models - Dalton us ...
Thursday, September 4
Thursday, September 4

...  Isomers are compounds with the same molecular formula but different structures and properties  Structural isomers have different covalent arrangements of their atoms  cis-trans (Geometric) isomers have the same covalent bonds but differ in spatial arrangements  Enantiomers are isomers that are ...
Final Review 2
Final Review 2

... 68) Which of the following elements has three valence electrons? a) lithium b) boron c) nitrogen d) more than one of the above 69) The electron configuration for gallium is: a) [Ar] 4s24d104p1 b) [Ar] 4s23d103p1 c) [Ar] 4s23d104p1 d) none of these answers is correct. 70) Which element has the larges ...
Synthesis, Characterization, and Electronic Structure of Ba5In4Bi5
Synthesis, Characterization, and Electronic Structure of Ba5In4Bi5

... known and the units have been found as isolated [TrPn3]6, edge-sharing in dimers of [Tr2Pn4]6, and corner-sharing in a ring-like trimer of [Tr3Pn6]9.[2a] Recent studies, however, have revealed that often the anionic substructures of such compounds are far more diverse and beyond the grasp of the ...
Name: David Kett Id Number: 0564591
Name: David Kett Id Number: 0564591

... Aim: To observe the solubility of organic compounds and the hydrocarbon Hexane in both water and acetone and to examine the effects of increased carbon-chain on solubility. Target Group: Suitable for a Senior cycle Chemistry class with sufficient prior knowledge and understanding of the concepts dea ...
AP Chemistry - Dorman High School
AP Chemistry - Dorman High School

... o Oxides and Carbonates are considered inorganic substances. o Original ideas to distinguish between organic and inorganic: ...
Name of alkane Chemical formula Displayed formula Methane CH4
Name of alkane Chemical formula Displayed formula Methane CH4

... atoms; alkanes are examples of saturated compounds. An unsaturated compound is one that has at least one double covalent bond between carbon atoms. Alkenes are examples of unsaturated compounds. Polymerisation: Additional polymerisation is the process where lots of monomer alkene monomers react to g ...
A Guide to Organic Molecules
A Guide to Organic Molecules

... The unsaturated compound quickly decolourises, i.e. changes colour from red brown to pale yellow or colourless. ...
A Review of High School Chemistry
A Review of High School Chemistry

... procedures for naming BINARY compounds, which are formed by combining two elements, and TERNARY compounds, formed by putting together three elements. To assist us in our endeavor, it will be of great assistance to memorize the now expanded list of common cations and anions shown in the Table below. ...
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Homoaromaticity



Homoaromaticity in organic chemistry refers to a special case of aromaticity in which conjugation is interrupted by a single sp3 hybridized carbon atom. Although this sp3 center disrupts the continuous overlap of p-orbitals, traditionally thought to be a requirement for aromaticity, considerable thermodynamic stability and many of the spectroscopic, magnetic, and chemical properties associated with aromatic compounds are still observed for such compounds. This formal discontinuity is apparently bridged by p-orbital overlap, maintaining a contiguous cycle of π electrons that is responsible for this preserved chemical stability.The concept of homoaromaticity was pioneered by Saul Winstein in 1959, prompted by his studies of the “tris-homocyclopropenyl” cation. Since the publication of Winstein's paper, much research has been devoted to understanding and classifying these molecules, which represent an additional “class” of aromatic molecules included under the continuously broadening definition of aromaticity. To date, homoaromatic compounds are known to exist as cationic and anionic species, and some studies support the existence of neutral homoaromatic molecules, though these are less common. The 'homotropylium' cation (C8H9+) is perhaps the best studied example of a homoaromatic compound.
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