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Chapter 4 Study Guide
Chapter 4 Study Guide

... Separate numbers with commas. Separate numbers from letters with dashes. If there are two substituents on the same carbon you must use the number twice. The position of double and triple bonds are indicated by a number in front of the base name. If there are more than one double or triple bond you u ...
[Co(en)3][B2P3O11(OH)2]: A Novel
[Co(en)3][B2P3O11(OH)2]: A Novel

... heating is amorphous (same is the result of heating 2 at that temperature). In conclusion, it should be pointed out that the fact that borophosphates can be “templated” with transition-metal complexes is yet another similarity of this class of compounds with the much larger class of alumino- and gal ...
Benzene, amines, amino acids and polymers File
Benzene, amines, amino acids and polymers File

... Of the standard α-amino acids, all but glycine can exist in either of two enantiomers, called L or D amino acids, which are mirror images of each other. While L-amino acids represent all of the amino acids found in proteins during translation in the ribosome, D-amino acids are found in some proteins ...
Ch 17- Aldehydes and Ketones
Ch 17- Aldehydes and Ketones

... have an -OH in the molecule, find the longest chain that contains both the carbon of the carbonyl and the carbon bonded to the -OH group • Number the chain to give the carbon of the carbonyl the lowest number • The -OH will be named as a substituent! • When the -OH group is named as a substituent, i ...
Organic Functional Groups Organic Functional Groups
Organic Functional Groups Organic Functional Groups

Workshop #1 Part 1. Organic Chemistry Nomenclature
Workshop #1 Part 1. Organic Chemistry Nomenclature

... 13. Mono-substituted cycloalkanes do not include the “1” locant. Thus, 1-methylcyclohexane is inaccurate. Draw methylcyclohexane; explain why adding a locant does not add any new information. D. Nomenclature of Alkenes: Functional Group = the particular group of atoms in a molecule that primarily de ...
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Document

... series, the atomic radii actually ____________again. At the beginning of the series, the increase in __________ _______________ with atomic number pulls in the electron cloud, resulting in a reduction of atomic size. Since electrons are added to an inner d subshell across the series, this adds to th ...
CHM_221_201620 - Oakton Community College
CHM_221_201620 - Oakton Community College

... polarity, boiling point, heat of combustion, acidity, solubility, bond strength, stability and reactivity, based on their structural features. 5. Classify isomers as either constitutional or one of the categories of stereoisomer: conformational, configurational, geometrical, optical, enantiomer, dia ...
CHM_223_201620 - Oakton Community College
CHM_223_201620 - Oakton Community College

... polarity, boiling point, heat of combustion, acidity, solubility, bond strength, stability and reactivity, based on their structural features. 5. Classify isomers as either constitutional or one of the categories of stereoisomer: conformational, configurational, geometrical, optical, enantiomer, dia ...
Abbreviated Chapter 17 Powerpoint
Abbreviated Chapter 17 Powerpoint

... Deactivators and Meta-Directors • Most electron-withdrawing groups are deactivators and meta-directors. • The atom attached to the aromatic ring has a positive or partial positive charge. • Electron density is withdrawn inductively along the sigma bond, so the ring has less electron density than be ...
Small Dopant Effect on Static Grain Growth and Flow Stress in
Small Dopant Effect on Static Grain Growth and Flow Stress in

... ceramics. Tetragonal ZrO2 polycrystal (TZP) with an average grain size of less than 1 mm is one of the most representative ceramic materials, which exhibit large tensile elongation at high temperature.2–7) For instance, the elongation of 800% was obtained in TZP at 1550 C under the strain rate of 8 ...
Class 11 Class 12 The p- Block Element • Group13 (B to Tl
Class 11 Class 12 The p- Block Element • Group13 (B to Tl

... •   Boron show  diagonal relationship with  Silicon;    both are  semiconductors metalloids & forms covalent compounds. •    Boron compounds are electron deficient, they are lack of an octet of electrons about the B atom . •   diborane B 2 H 6 is  simplest boron hydride •   Structure: three-center t ...
Chemistry Packet: Chemical Bonding
Chemistry Packet: Chemical Bonding

Chemistry 210 - MiraCosta College
Chemistry 210 - MiraCosta College

... OUTSIDE-OF-CLASS ASSIGNMENTS (READING/WRITING/OTHER) Outside-of-class assignments will be consistent with, but not limited by, the following types and examples: ...
7 Organic 2
7 Organic 2

... •  Can we use information about bonding, connectivity of atoms, molecular formulas, etc. to predict the shapes (and properties) of ...
a.     b.     c.      d.
a. b. c. d.

... TWO
spectroscopic
features
from
each
sample
(each
of
the
two
coming
from
a
different
method
–
for
example
 you
could
use
the
IR
and
H‐NMR
or
samples
A
&
B
and
perhaps
the
H‐NMR
and
C‐NMR
of
C
to
determine
the
 correct
identity
of
each,
which
ever
two
are
most
helpful).
 ...
Interaction of the Adenine-Thymine Watson
Interaction of the Adenine-Thymine Watson

... with A‚AT triplets10 revealed that there has been no minimum on the potential energy surface corresponding to a planar H-bonded base pair. At first, the initial planar structure was somewhat destabilized by an interaction between a water molecule and the amino group nitrogen atom. Pyramidalization o ...
CHAPTER 2 ATOMS, MOLECULES, AND IONS Questions
CHAPTER 2 ATOMS, MOLECULES, AND IONS Questions

... neutrons, and protons are the key smaller parts of an atom. b. All atoms of hydrogen have 1 proton in the nucleus. Different isotopes of hydrogen have 0, 1, or 2 neutrons in the nucleus. Because we are talking about atoms, this implies a neutral charge, which dictates 1 electron present for all hydr ...
ORGANIC NOMENCLATURE
ORGANIC NOMENCLATURE

... simplest classification is that of the hydrocarbons, compounds of carbon and hydrogen. Hydrocarbons are further identified as being aliphatic or aromatic (nothing to do with smell). The aliphatics may be alkanes, alkenes or alkynes; aromatic hydrocarbons contain one or more benzene rings. It is impo ...
CHAPTER 2 ATOMS, MOLECULES, AND IONS Questions
CHAPTER 2 ATOMS, MOLECULES, AND IONS Questions

... neutrons, and protons are the key smaller parts of an atom. b. All atoms of hydrogen have 1 proton in the nucleus. Different isotopes of hydrogen have 0, 1, or 2 neutrons in the nucleus. Because we are talking about atoms, this implies a neutral charge, which dictates 1 electron present for all hydr ...
Expedient synthesis of 1,2,4-triazolin-3
Expedient synthesis of 1,2,4-triazolin-3

... (methine and methylene protons) have shown a characteristic feature and form an ABX pattern. The methylene protons can be assigned as HA, HB and the methine proton as Hx. HA and HB are diastereotopic and also anisochronous as they differ in chemical shifts and since this difference is not large as t ...
aryl halides
aryl halides

... sp2 hybridized and not prone to nucleophilic substitution. In a manner analogous to the phenols & alcohols, we have the same functional group in the two families, aryl halides and alkyl halides, but very different chemistries. ...
IOSR Journal of Applied Chemistry (IOSR-JAC)
IOSR Journal of Applied Chemistry (IOSR-JAC)

... which is susceptible to oxidative degradation under demanding reaction conditions. The conventional two step method, however, is not without practical difficulties like loss of yield associated with the isolation and purification of the amine as the reduction product. In some cases e.g. the aminophe ...
TV RajanBabu Chemistry, 730 Autumn 1997
TV RajanBabu Chemistry, 730 Autumn 1997

... Axial vs equatorial approach to cyclic carbonyl compounds by nucleophiles Klein / Cieplak models Tortional interactions in bicyclic systems Ring closure and ring size (Baldwin’s rules) - enthalpy and entropy of activation Bürgi-Dunitz angle, Radical cyclization reactions under kinetic vs thermodynam ...
Chemistry - Tiwariacademy.net
Chemistry - Tiwariacademy.net

... (iii) Four isomeric monochlorides. Answer (i) ...
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Homoaromaticity



Homoaromaticity in organic chemistry refers to a special case of aromaticity in which conjugation is interrupted by a single sp3 hybridized carbon atom. Although this sp3 center disrupts the continuous overlap of p-orbitals, traditionally thought to be a requirement for aromaticity, considerable thermodynamic stability and many of the spectroscopic, magnetic, and chemical properties associated with aromatic compounds are still observed for such compounds. This formal discontinuity is apparently bridged by p-orbital overlap, maintaining a contiguous cycle of π electrons that is responsible for this preserved chemical stability.The concept of homoaromaticity was pioneered by Saul Winstein in 1959, prompted by his studies of the “tris-homocyclopropenyl” cation. Since the publication of Winstein's paper, much research has been devoted to understanding and classifying these molecules, which represent an additional “class” of aromatic molecules included under the continuously broadening definition of aromaticity. To date, homoaromatic compounds are known to exist as cationic and anionic species, and some studies support the existence of neutral homoaromatic molecules, though these are less common. The 'homotropylium' cation (C8H9+) is perhaps the best studied example of a homoaromatic compound.
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