Ch. 6 - Department of Chemistry and Biochemistry
... Professor William Tam received his B.Sc. at the University of Hong Kong in 1990 and his Ph.D. at the University of Toronto (Canada) in 1995. He was an NSERC postdoctoral fellow at the Imperial College (UK) and at Harvard University (USA). He joined the Department of Chemistry at the University of Gu ...
... Professor William Tam received his B.Sc. at the University of Hong Kong in 1990 and his Ph.D. at the University of Toronto (Canada) in 1995. He was an NSERC postdoctoral fellow at the Imperial College (UK) and at Harvard University (USA). He joined the Department of Chemistry at the University of Gu ...
word - My eCoach
... remain attached to the crystal. Ionic solids that contain a definite amount of water are called hydrates or hydrated salts and the water in the crystal structure is called water of hydration. The water is loosely bound to the ionic solid so it is possible to dehydrate or remove the water by heating. ...
... remain attached to the crystal. Ionic solids that contain a definite amount of water are called hydrates or hydrated salts and the water in the crystal structure is called water of hydration. The water is loosely bound to the ionic solid so it is possible to dehydrate or remove the water by heating. ...
Aldehydes can react with alcohols to form hemiacetals
... Cyclic acetals like this are more resistant to hydrolysis than acyclic ones and easier to make—they form quite readily even from ketones. Again, we have entropic factors to thank for their stability. For the formation of a cyclic acetal, two molecules go in (ketone plus diol) and two molecules come ...
... Cyclic acetals like this are more resistant to hydrolysis than acyclic ones and easier to make—they form quite readily even from ketones. Again, we have entropic factors to thank for their stability. For the formation of a cyclic acetal, two molecules go in (ketone plus diol) and two molecules come ...
Chapter 18
... Mechanism is not an insertion, but rather a reaction at carbonyl followed by a migration ...
... Mechanism is not an insertion, but rather a reaction at carbonyl followed by a migration ...
Ethers and Epoxides
... nucleophile such as –SH The alkylthiol product can undergo further reaction with the alkyl halide to give a symmetrical sulfide, giving a poorer yield of the thiol ...
... nucleophile such as –SH The alkylthiol product can undergo further reaction with the alkyl halide to give a symmetrical sulfide, giving a poorer yield of the thiol ...
Mock Exam One
... b.) In general, aldehydes are more reactive than ketones. c.) Nucleophilic addition to carbonyl groups can be catalyzed by acid or base. d.) Addition of a nucleophile to a carbonyl group changes the hybridization of the carbonyl carbon from sp3 to sp2. ...
... b.) In general, aldehydes are more reactive than ketones. c.) Nucleophilic addition to carbonyl groups can be catalyzed by acid or base. d.) Addition of a nucleophile to a carbonyl group changes the hybridization of the carbonyl carbon from sp3 to sp2. ...
07. Aldehydes and ketones
... 4. Reactions of condensation 1). Aldol condensation As noted earlier, an aldehyde is partially converted to its enolate anion by bases such as hydroxide ion and alkoxide ions. This type of condensations is character for aldehydes which have hydrogen atoms at the α-carbon atom. ...
... 4. Reactions of condensation 1). Aldol condensation As noted earlier, an aldehyde is partially converted to its enolate anion by bases such as hydroxide ion and alkoxide ions. This type of condensations is character for aldehydes which have hydrogen atoms at the α-carbon atom. ...
Scheme B - RHS Intranet
... metals compared with the extraction of metals understand the environmental advantages of using scrap iron to extract copper from aqueous solutions compared with the high-temperature carbon reduction of copper oxide know that the usual source of such aqueous solutions is low grade ore ...
... metals compared with the extraction of metals understand the environmental advantages of using scrap iron to extract copper from aqueous solutions compared with the high-temperature carbon reduction of copper oxide know that the usual source of such aqueous solutions is low grade ore ...
CHEMICAL EQUILIBRIUM
... ***** Arsenic can be extracted from its ores by first reacting the ore with oxygen to form solid As 4O6, which is then reduced using carbon: As4O6 (s) + 6 C (s) ↔ As4 (g) + 6 CO (g) Predict the direction of the shift of the equilibrium position in response to each of the following changes in ...
... ***** Arsenic can be extracted from its ores by first reacting the ore with oxygen to form solid As 4O6, which is then reduced using carbon: As4O6 (s) + 6 C (s) ↔ As4 (g) + 6 CO (g) Predict the direction of the shift of the equilibrium position in response to each of the following changes in ...
Disproportionation of Monolithium Acetylide into
... most widely used ethynylation and alkynylation reaction.1 Monolithium acetylide (1) disproportionates readily above -25 °C into the more stable dilithium carbide (2) and acetylene.2 Liquid ammonia which is utilized in processes claimed to have industrial economics1,3 serves not only as a solvent but ...
... most widely used ethynylation and alkynylation reaction.1 Monolithium acetylide (1) disproportionates readily above -25 °C into the more stable dilithium carbide (2) and acetylene.2 Liquid ammonia which is utilized in processes claimed to have industrial economics1,3 serves not only as a solvent but ...