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Fluorinated Butatrienes - diss.fu-berlin.de
Fluorinated Butatrienes - diss.fu-berlin.de

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... nucleophile and the primary alkyl halide is a good electrophile but it does not. We can, however, do this coupling reaction by using an organocopper reagent. Without going into all of the details, we can see from the periodic table that copper (electronegativity 1.90) is much more electronegative th ...
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... In the reaction A+B DC+D If 0.2 mol of A is mixed with 0.5 mol of B in 1.0 L, find the equilibrium concentrations of A, B, C, and D. The equilibrium constant of the reaction is 4.0x108. It is clear that we have a high equilibrium constant which suggests that very little reactants may have been left ...
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George S. Hammond

George Simms Hammond (May 22, 1921 – October 5, 2005) was a chemist at Iowa State University and the California Institute of Technology. Born and raised in Auburn, Maine, he attended nearby Bates College in Lewiston, Maine where he graduated Magna Cum Laude with a B.S. in Chemistry in 1943. He completed his doctorate at Harvard in 1947, under the mentorship ofPaul D. Bartlett, and a postdoc at UCLA with Saul Winstein in 1948.Among his awards were the Norris Award in 1968, the Priestley Medal in 1976, the National Medal of Science in 1994, and the Othmer Gold Medal in 2003.Hammond was a leader in the field of photochemistry and was widely credited with creating the discipline of organic photochemistry. Hammond's postulate, also known as the Hammond-Leffler postulate, was based on his 1955 publication.
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