• Study Resource
  • Explore Categories
    • Arts & Humanities
    • Business
    • Engineering & Technology
    • Foreign Language
    • History
    • Math
    • Science
    • Social Science

    Top subcategories

    • Advanced Math
    • Algebra
    • Basic Math
    • Calculus
    • Geometry
    • Linear Algebra
    • Pre-Algebra
    • Pre-Calculus
    • Statistics And Probability
    • Trigonometry
    • other →

    Top subcategories

    • Astronomy
    • Astrophysics
    • Biology
    • Chemistry
    • Earth Science
    • Environmental Science
    • Health Science
    • Physics
    • other →

    Top subcategories

    • Anthropology
    • Law
    • Political Science
    • Psychology
    • Sociology
    • other →

    Top subcategories

    • Accounting
    • Economics
    • Finance
    • Management
    • other →

    Top subcategories

    • Aerospace Engineering
    • Bioengineering
    • Chemical Engineering
    • Civil Engineering
    • Computer Science
    • Electrical Engineering
    • Industrial Engineering
    • Mechanical Engineering
    • Web Design
    • other →

    Top subcategories

    • Architecture
    • Communications
    • English
    • Gender Studies
    • Music
    • Performing Arts
    • Philosophy
    • Religious Studies
    • Writing
    • other →

    Top subcategories

    • Ancient History
    • European History
    • US History
    • World History
    • other →

    Top subcategories

    • Croatian
    • Czech
    • Finnish
    • Greek
    • Hindi
    • Japanese
    • Korean
    • Persian
    • Swedish
    • Turkish
    • other →
 
Profile Documents Logout
Upload
Chemistry 2014 - SC3210 IC Scope and Sequence
Chemistry 2014 - SC3210 IC Scope and Sequence

... Describe the experimental basis for Einstein's explanation of the photoelectric effect. Describe the modern (electron cloud) model of the atom. Explain Bohr's model of the atom and how it accounts for the existence of spectral lines. Science Practice: Compare Dalton's atomic model with the current q ...
Experiment 2 Chemistry with Light – Using Photons as Reagents
Experiment 2 Chemistry with Light – Using Photons as Reagents

... photochemistry in Nature is photosynthesis, where plants and algae use the energy from light to make glucose from carbon dioxide and water. Photodegradation, where sunlight is used to break down plastic bags, is an environmental aspect of photochemistry. Photochemistry can also be found in other are ...
Chapter 9 Reaction Energetics
Chapter 9 Reaction Energetics

... Conditions of constant pressure and temperature are quite common, so our treatment of thermodynamics is limited to processes carried out under these conditions. The gases that escape to the atmosphere carry some of the energy change of the reaction with them. This energy is lost, so chemists typical ...
chemistry
chemistry

... “Reaction Time (s).” An appropriate scale is one that allows a trend to be seen. [1] 58 On the same grid, plot the data from the data table. Circle and connect the points. [1] Example: ...
Oxidation-Reduction and Electrochemistry
Oxidation-Reduction and Electrochemistry

... our present expression, enters: it is the negative extremity of the  decomposing body; is where oxygen, chlorine, acids, etc., are evolved; and is  against or opposite the positive electrode.  The cathode is that surface at which the current leaves the decomposing  body, and is its positive extremit ...
Chemistry
Chemistry

... smallest particle of matter. It translates to mean something that is indivisible. In the eighteenth century, the chemist John Dalton, revived the term when he suggested that each element was made up of unique atoms and the atoms of an element are all the same. At that time, there were about 35 known ...
St. Xavier`s College – Autonomous Mumbai Syllabus for 3 Semester
St. Xavier`s College – Autonomous Mumbai Syllabus for 3 Semester

... UNIT II: Theories Of Chemical Bonding ...
Oxidative Alihatic Carbon-Carbon Bond Cleavage Reactions
Oxidative Alihatic Carbon-Carbon Bond Cleavage Reactions

... relevance to dioxygenase enzymes that oxidatively cleave aliphatic carbon-carbon bonds. The goal of this research was to elucidate mechanistic aspects of the activation of aliphatic carbon-carbon bonds towards cleavage by reaction with oxygen, and also investigate the regioselectivity of these react ...
Chapter 4 Chemical Reactions and Solution Stoichiometry 4.1
Chapter 4 Chemical Reactions and Solution Stoichiometry 4.1

... In a typical decomposition reaction (Interactive Figure 4.1.3), the number of products is greater than the number of reactants. The reaction is essentially the reverse of a combination reaction and usually results from the addition of thermal or electrical energy. For example, water is a very stable ...
ap chemistry 2005/2006
ap chemistry 2005/2006

... A typical week is organized to provide:  3-4 days of lecture focused on the key objectives listed in the syllabus, including teacher demonstrations  1-2 days of lab activity. Labs may exceed one 90 minute class, depending on the requirements of the specific lab activity. In addition, some sections ...
3.98 MB - KFUPM Resources v3
3.98 MB - KFUPM Resources v3

... Aqueous Reactions and Chemical Analysis Many aqueous reactions are very useful for determining how much of a particular substance is present in a sample. ...
+ OH - (aq) - Miss Gerges
+ OH - (aq) - Miss Gerges

... Aqueous Reactions and Chemical Analysis Many aqueous reactions are very useful for determining how much of a particular substance is present in a sample. ...
Follow Along Notes - Jackson County School System
Follow Along Notes - Jackson County School System

... Relationship Between Kp and Kc Relationship Between Kp and Kc Relationship Between Kp and Kc Relationship Between Kp and Kc ...
AP Chemistry: Total Notes Review
AP Chemistry: Total Notes Review

... 3: Fill the octets 4: use double and triple bonds as necessary o Formal charges: subtract the amount of electrons on the periodic table (for that element) from the electrons you drew in ~ 0 means right on ~ the negative charge should be on the most electronegative atom o Resonance: when one Lewis st ...
Molarity = M (Concentration of Solutions)
Molarity = M (Concentration of Solutions)

... Gas Law Stoichiometry - I - NH3 + HCl Problem: A slide separating two containers is removed, and the gases are allowed to mix and react. The first container with a volume of 2.79 L contains Ammonia gas at a pressure of 0.776 atm and a temperature of 18.7 oC. The second with a volume of 1.16 L conta ...
Basic Concepts
Basic Concepts

... • Chemical equilibrium exists when two opposing reactions occur simultaneously at the same rate. – A chemical equilibrium is a reversible reaction that the forward reaction rate is equal to the reverse reaction rate. • Chemical equilibria are dynamic equilibria. – Molecules are continually reacting, ...
Basic Concepts - Department of Chemistry
Basic Concepts - Department of Chemistry

... • Comparing the magnitudes of Q and K allows the determination of whether a reaction mixture is already at equilibrium and, if it is not, how to predict whether its composition will change with time (whether the reaction will proceed to the right or to the left) 1. If Q = K, the system is at equilib ...
Physical Chemistry Problems. ©Mike Lyons 2009
Physical Chemistry Problems. ©Mike Lyons 2009

... Write down an expression for the First Law of Thermodynamics which relates the change in internal energy of a system to the work done on the system and the heat absorbed by the system. Hence derive a relationship between the change in internal energy U and the change in enthalpy H of a system. b. ...
CHE 1031 Lab Manual
CHE 1031 Lab Manual

... ii. Read  through  the  lab  protocol.  Anything  that  you  are  asked  to  measure  or   observe  becomes  a  row  label.  The  row  label  should  include  units.  For   example:  “mass  of  marble  (g)”.   iii. You  like  to  crea ...
ism ismismismismismrapidrevisionquestionsismismismismismism
ism ismismismismismrapidrevisionquestionsismismismismismism

Chapter 2 Geochemical Reactions
Chapter 2 Geochemical Reactions

... In bonds between atoms with strongly contrasting electronegativities, the valence electrons orbit the atom with the strongest electronegativity, giving it a negative charge (the anion) and leaving the other atom stripped of its valence electrons and so carrying a positive charge (the cation). They b ...
ap chemistry 2005/2006
ap chemistry 2005/2006

... A typical week is organized to provide:  3-4 days of lecture focused on the key objectives listed in the syllabus, including teacher demonstrations  1-2 days of lab activity. Labs may exceed one 90 minute class, depending on the requirements of the specific lab activity. In addition, some sections ...
chemistry (9189)
chemistry (9189)

... bonding; covalent bonding; hydrogen bonding, other intermolecular interactions; metallic bonding) on the physical properties of substances ...
The Advanced Placement Examination in Chemistry Part I – Multiple
The Advanced Placement Examination in Chemistry Part I – Multiple

... (a) The vapor density of compound X at 27C and 750. mm Hg was determined to be 3.53 grams per liter. Calculate the molecular weight of compound X. (b) Determine the mass of element Q contained in 1.00 mole of each of the three compounds. (c) Calculate the most probable value of the atomic weight of ...
Chapter 6. Therrnochemistry
Chapter 6. Therrnochemistry

< 1 ... 53 54 55 56 57 58 59 60 61 ... 185 >

Lewis acid catalysis



In Lewis acid catalysis of organic reactions, a metal-based Lewis acid acts as an electron pair acceptor to increase the reactivity of a substrate. Common Lewis acid catalysts are based on main group metals such as aluminum, boron, silicon, and tin, as well as many early (titanium, zirconium) and late (iron, copper, zinc) d-block metals. The metal atom forms an adduct with a lone-pair bearing electronegative atom in the substrate, such as oxygen (both sp2 or sp3), nitrogen, sulfur, and halogens. The complexation has partial charge-transfer character and makes the lone-pair donor effectively more electronegative, activating the substrate toward nucleophilic attack, heterolytic bond cleavage, or cycloaddition with 1,3-dienes and 1,3-dipoles.Many classical reactions involving carbon–carbon or carbon–heteroatom bond formation can be catalyzed by Lewis acids. Examples include the Friedel-Crafts reaction, the aldol reaction, and various pericyclic processes that proceed slowly at room temperature, such as the Diels-Alder reaction and the ene reaction. In addition to accelerating the reactions, Lewis acid catalysts are able to impose regioselectivity and stereoselectivity in many cases.Early developments in Lewis acid reagents focused on easily available compounds such as TiCl4, BF3, SnCl4, and AlCl3. The relative strengths of these (and other) Lewis acids may be estimated from NMR spectroscopy by the Childs method or the Gutmann-Beckett method. Over the years, versatile catalysts bearing ligands designed for specific applications have facilitated improvement in both reactivity and selectivity of Lewis acid-catalyzed reactions. More recently, Lewis acid catalysts with chiral ligands have become an important class of tools for asymmetric catalysis.Challenges in the development of Lewis acid catalysis include inefficient catalyst turnover (caused by catalyst affinity for the product) and the frequent requirement of two-point binding for stereoselectivity, which often necessitates the use of auxiliary groups.
  • studyres.com © 2026
  • DMCA
  • Privacy
  • Terms
  • Report