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Basic Physical Chemistry Lecture 1

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... When dealing with a large quantum system, we need to take 2 averages, one over the inherent quantum uncertainties and one over the uninteresting microscopic details. Consider then an isolated system described, in the Schrodinger picture, by a complete set of orthonormal eigenstates  n  t  ...
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... in which case ρ = |ψ >< ψ| if the state vector is normalized to unity. In summary, by the term “state of a system” we will understand as state of a micro or macroscopic system defined by its complete density matrix. With that understanding, not all states are characterized by a state vector. Only pu ...
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... moment to have 2l + 1 eigenvalues. However, experimentally only two distinct traces where seen (although, nothing was seen due to very thin layer deposited until Stern’s breath full of sulfur from cheap cigars developed AgS which is ”jet” black ). The solution to this comes from the postulate by Gou ...
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... kind terms not as fulfilling a merely regulative demand in the Kantian sense (i.e., as if nature were ordered according to those taxonomic relationships), but rather as fixing an order of things in nature in the Aristotelian/neo-Platonic sense (i.e., nature is so ordered).’’ (italics in the original). ...
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Hydrogen atom



A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral atom contains a single positively charged proton and a single negatively charged electron bound to the nucleus by the Coulomb force. Atomic hydrogen constitutes about 75% of the elemental (baryonic) mass of the universe.In everyday life on Earth, isolated hydrogen atoms (usually called ""atomic hydrogen"" or, more precisely, ""monatomic hydrogen"") are extremely rare. Instead, hydrogen tends to combine with other atoms in compounds, or with itself to form ordinary (diatomic) hydrogen gas, H2. ""Atomic hydrogen"" and ""hydrogen atom"" in ordinary English use have overlapping, yet distinct, meanings. For example, a water molecule contains two hydrogen atoms, but does not contain atomic hydrogen (which would refer to isolated hydrogen atoms).
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