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Transcript

Arrangement of Electrons in Atoms Chapter 4 The New Atomic Model Investigations relationship between light and atom’s electrons How are electrons arranged? Why don’t they fall into the nucleus? Light a wave or particle? Wave Description: Electromagnetic Radiation: energy that acts like a wave in space All forms create Electromagnetic Spectrum Electromagnetic Spectrum Electromagnetic Spectrum All forms move at speed of light, c, 3.00x108 m/s Forms identified by: wavelength, , the distance b/ corresponding points on adjacent waves. Units: nm, cm, or m Frequency, , # of waves that pass a given point in a specific time, 1 sec. Unit: 1/s = Hertz, Hz Wavelength and Frequency Wavelength and Frequency c = speed of light, m/s wavelength, m Inverse proportion equation!! Frequency, 1/s Calculation Calculate the wavelength of a radio wave with a frequency of 102.7 x 106s-1 Determine the frequency of light whose wavelength is 5.267 nm. Particle Nature of Light Photoelectric Effect: emission of electrons from a metal when light shines on the metal Photoelectric Effect Light had to be certain frequency to knock e- loose Wave theory any frequency should work (just might take a while) Light must also be a particle! Max Planck(1900) explanation: objects emit energy in small packets called quanta Video - 16 Max Planck Quantum of energy is the smallest amount of energy that can be lost or gained by an atom E = h Energy of quantum, in joules, J Planck’s constant, 6.626x10-34 Js Frequency, s-1 Energy Calculation What is the energy of green light, with a wavelength of 500. nm? Albert Einstein Light is both wave and particle! Particle of light = photon, having zero mass and a quantum of energy Photons hit metal and knock e- out, but photon has to have enough energy H-atom Emission Spectrum Pass a current through gas at low pressure it excites the atoms Ground state: lowest energy state of an atom Excited state: atom has higher potential energy than it has in ground state H – Atom Spectrum When atom jumps from excited state to ground state it gives off energy LIGHT! E2 Ephoton = E2 – E1 = hv E1 Bohr Model of H-atom H-atom Line Emission Spectrum Element Emission Spectras Helium – 23 lines Neon – 75 lines Argon - 159 lines Xenon – 139 lines Mercury – 40 lines H-atom Line Emission Spectrum More lines in UV (Lyman series) and IR(Paschen series) Why did H-atom only emit certain colors of light? Explanation led to new atomic theory Quantum Theory Bohr Model of H-atom 1913 – Niels Bohr e- circles nucleus in certain paths, orbits or atomic energy levels e- is higher in energy the farther away from nucleus e- cannot be between orbits Video - 23 Bohr Model of H-atom Bohr Model of H-atom From wavelengths of emission spectrum Bohr calculated energy levels of H-atom Model worked ONLY for H-atom Quantum Model of Atom Can e- behave as a wave? Yes! To find e- use a photon, but photon will knock the e- off course Heisenberg Uncertainty Principle: impossible to determine position and velocity of a particle at the same time. Schrödinger Wave Equation 1926 – developed equation and only ewaves of certain frequencies were solutions Quantization of e- probability of finding e- in atom No neat orbits probability clouds or orbitals Electron Configurations Atomic Orbitals Def: 3-D region around nucleus that indicates the probable location of an electron Energy levels or shells: Numbered 1-7 Smaller number = closer to nucleus, lower energy Sublevels Each shell has sublevels s p 1 – s orbital 3 – p orbitals d 5 – d orbitals 7 – f orbitals f Shells and Sublevels Shells and sublevels together: 1s 2s, 2p 3s, 3p, 3d 4s, 4p, 4d, 4f, etc. s is the lowest energy and f is the highest Orbitals Each orbital in a sublevel can hold a maximum of 2 e 1 – s 2 e- max. 3 – p orbitals 6 e- max. 5 – d orbitals 10 e- max. 7 – f orbitals 14 e- max. Electron Configurations Arrangement of e- in atom Orbital Notation: H has 1eRules: 1. Aufbau Principle: electron occupies lowest energy level that can receive it Electron Configurations 2. Pauli Exclusion Principle: no two e- in an sublevel orbital can have the same spin 3. Hund’s Rule: orbitals of equal energy are occupied by one e- before pairing up e-. All single occupied orbitals must have same spin. He – 2e- Energy of sublevels Electron Configurations N S Ti I Electron Configuration Notation B Ni Hg Noble Gas Notation Use noble gas from previous row Al Pb Special Cases d sublevel more stable with half-filled or completely filled sublevel Cr Cu