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WATER POLLUTION PART I NINE TYPES OF WATER POLLUTANTS • Disease Causing Agents • Sediment Pollution (suspended solids) • Inorganic Chemicals and Oxygen-Demanding Wastes • Organic Chemicals and Oxygen-Demanding Wastes • Water-Soluble Radioactive Isotopes • Thermal Pollution • Genetic Pollution (non-native species) DISEASE CAUSING AGENTS • Bacteria, viruses, protozoa, parasitic worms. • Waterborne Diseases – typhoid, cholera, bacterial dysentary, polio, and infectious hepatitis. • Cause of Typhoid fever: Salmonella typhi bacteria from food or water or if sewage contaminated with S. Typhi bacteria gets into the water you use for drinking or washing food. “Typhoid Mary” • Cause of Cholera: Feces exposure from poor hygiene and sanitation of food or water. A person may get cholera by drinking water or eating food contaminated with the cholera bacterium. • Common in developing nations. Threat following Katrina in USA! DISEASE CAUSING AGENTS • Pfiesteria piscida – “Cell from hell” • A microscopic organism that can behave as both a plant and animal cell. Flips from an algae eater into a fish-eating dinoflagellate. • Lacks suitable prey to keep population in check. • Releases neurotoxins that kill fish within 10 hours and the neurotoxins form an aerosol above the water and can harm humans. • Pfiesteria live in waters from Chesapeake Bay to Florida. • Scientific research show increased population growth of Pfiesteria associated with cultural eutrophication from hog farms. • Joanne Burkholder’s research was not well-received from law makers and big business. Her research indicates that farmers need to implement nutrient-loading management plans and that government needs to implement policy and regulations to limit Pfiesteria outbreaks to protect human health! SEDIMENT POLLUTION • “Sediment Kills Reefs” • Sediment releases into surface waters due to poor land management decreases water clarity, increases turbidity, buries organisms, decreases the availability of light for photosynthesizing organisms, and brings insoluble toxic pollutants including PCB’s and DDT. • 1.3 million pounds of PCB’s in Hudson River from GE Plant. Must dredge 2.6 million yards! Long residence time in environment. • DDT banned in the USA for application BUT we are the #1 producers of DDT for sales worldwide! Long residence time in environment. DDT (50years), DDE (200 years). INORGANIC CHEMICALS (water-soluble nutrients) • Heavy metals such as mercury (Hg) and lead (Pb) from industry, mines, irrigation runoff, oil drilling, and urban runoff from storm sewers. (point source and non-point source pollution) • Lead (Pb) – additives in gasoline (MTBE’s) contaminate the air. Lead gas banned in the USA (still available in other parts of the world). It is also present in incinerator ash. This is classified as “hazardous” waste and must be disposed of in a special landfill. It leaches into groundwater. Residues can also be found on food resources located downwind from incinerators. Lead paints – banned in USA, but can still be found in buildings. • Greatest risk for Pb poisoning are mid-aged men (high blood pressure), pregnant woman (miscarriage, premature births and stillbirths), and young children (mental/physical impairments – hearing loss, hyperactivity, ADD, low IQ, LD). INORGANIC CHEMICALS (water-soluble nutrients) • Mercury (Hg) – mostly from industrial processes (wastewater), also from batteries, paints and plastics burned in incinerators. Burning converts it to methyl mercury which readily enters food webs. • Bioaccumulation in muscle of tuna, shark, and swordfish. • Biomagnification since they are top predators. • Long residence time in environment – toxic to humans and causes mental retardation in children and kidney failure. BIOACCUMULATION AND BIOMAGNIFICATION Biomagnification • Nitrogen and phosphorous loading (cultural eutrophication causes and increase in algae (bloom) which causes a decrease in DO resulting in the death of aquatic organisms. Decomposing aerobic bacteria continue using DO (increase in BOD) in water until the conditions become Anoxic! SEPTIC TANKS Septic tanks are used in areas where there are no combined sewers. Septic tanks (cesspools) must be emptied each year. Old tanks can crack and leak coliform bacteria into surrounding soil, groundwater, and surface waters. Figure 9-28 Page 196 Septic tank with manhole (for cleanout) Household wastewater Non-perforated pipe Distribution box (optional) Gravel or crushed stone Drain field Vent pipe Perforated pipe SEWAGE TREATMENT • Sewage treatment means removing impurities so that the remaining waste water can be safely returned to the surface waters (river, bay, ocean) and become part of the natural water cycle again. • sewage treatment separates solids from liquids by physical processes and purifies the liquid by biological and chemical processes PRIMARY TREATMENT • solids like wood, paper, rags and plastic are removed by screens, washed, dried and taken away for safe disposal at a licensed waste tip. Grit and sand, which would damage pumps, are also removed by settling tanks and disposed of in a similar way. PRIMARY TREATMENT • the remaining solids are separated from the liquid by passing the sewage through large settlement tanks, where most of the solid material sinks to the bottom. About 70% of solids settle out at this stage and are referred to as sludge. The sludge is used on farms after further treatment called sludge treatment. SLUDGE TREATMENT • Sludge is an excellent soil conditioner and is used as a fertilizer on farmland. However, it needs additional treatment to make it suitable. This treatment is called anaerobic digestion and takes place in large, enclosed tanks. NYC sludge has too many heavy metals (Hg, Pb, Cd, Cu) and may not be used as a soil amendment for food resources in NY State. • The rate of digestion is increased by heating the sludge to a temperature where naturally occurring bacteria (microorganisms) respond to these comfortable conditions and feed on other bacteria. On cooling, the well-fed bacteria die off, and the sludge is suitable for use on agricultural land. • A by-product of the sludge digestion process is methane gas. This can be burned to produce electricity. The electricity can be used to heat more sludge or to provide heat and light for the treatment works. Sometimes more energy is produced than is required. The surplus is sold to local electric companies. SECONDARY TREATMENT • a biological process which relies on naturally occurring microorganisms acting to break down organic material and purify the liquid. • In a simple sewage treatment process, micro-organisms are encouraged to grow on stones over which the sewage is trickled. They feed on the bacteria in the sewage and purify the water. These treatment units are called percolating filters. SECONDARY TREATMENT • The rate of this process can be increased by pumping air into tanks of sewage where the aerobic digesters float freely and feed on the bacteria. These treatment units are called aeration tanks. • Following either form of secondary treatment, the waste water is settled in tanks to separate the biological sludge from the purified waste water. TERTIARY TREATMENT • Extra treatment is needed to give the waste water a final "polish". This is known as tertiary treatment. Various methods may be used, including sand filters, reed beds or grass plots (artificial treatment wetlands). Disinfection, using ultra violet light to kill bacteria, is another method, and is being used at a number of coastal sewage treatment plants. Secondary Primary Bar screen Grit chamber Settling tank Aeration tank Settling tank Chlorine disinfection tank To river, lake, or ocean Raw sewage from sewers (kills bacteria) Sludge Activated sludge Air pump Sludge digester Sludge drying bed Disposed of in landfill or ocean or applied to cropland, pasture, or rangeland (Sludge cake or pellets) IMPACTS FROM ORGANIC WASTE 8 ppm 8 ppm (mg/L) WAYS TO REDUCE CULTURAL EUTROPHICATION • Advanced waste treatment (sewage and industrial) • Regulate detergents cleaning products for phosphates. They have been regulated since the 1970’s on Long Island! • Promote soil conservation and preservation of wetlands to capture and filter pollutants before they enter surface waters. • Regulate fertilizer, pesticide, agricultural and livestock runoff to control Nitrogen, phosphate, and PAH’s. • Create policies and economic incentives for doing these things! ORGANIC CHEMICALS (Synthetic) • Pesticides, solvents, industrial chemicals, and plastics, oil, gasoline, and MTBE’s. • Many are hydrocarbons (PAH’s) and leach into soil and groundwater. All of these are toxic to aquatic organisms. • Standards: benzene (1ppb) (DDT) • MTBE (5 ppb) • As soon as Clean Air Act Ammendments of 1990 went into effect, childhood asthma increased as well as bronchitis, depression, and nuerological disorders. • Senator Marcellino wants to remove the mandate for MTBE’s. New Hampshire is the only state that has outlawed MTBE’s. • Problematic due to NAFTA – violates Article 11 • Oil Spills – Exxon Valdez EXXON VALDEZ OIL SPIILL • On March 24, 1989, shortly after midnight, the oil tanker Exxon Valdez struck Bligh Reef in Prince William Sound, Alaska, spilling more than 11 million gallons of crude oil. The spill was the largest in U.S. history. Capt. Joe Hazelwood, who later admitted to having had several alcoholic drinks that day, (From Huntington, Long Island). In jail NOW! • The spill posed threats to the delicate food chain that supports Prince William Sound's commercial fishing industry. Also in danger were ten million migratory shore birds and waterfowl, hundreds of sea otters, dozens of other species, such as harbor porpoises and sea lions, and several varieties of whales. • In the aftermath of the Exxon Valdez incident, Congress passed the Oil Pollution Act of 1990, which required the Coast Guard to strengthen its regulations on oil tank vessels and oil tank owners and operators. Today, tank hulls provide better protection against spills resulting from a similar accident, and communications between vessel captains and vessel traffic centers have improved to make for safer sailing. OIL SPILLS • Spills occur at offshore oil drilling rigs during natural disasters (Katrina) and due to human error. They are called “blowouts” • Spills occur from tanker accidents. • Damage to environment from oil spills is dependent on type of oil (crude oil most toxic due to benzene and toluene), weather conditions, season, and type of organisms in the area. • Oils spill cleanup is difficult and EXPENSIVE. It is very difficult to save animals who have ingested the hydrocarbons into their digestive tracts, especially aquatic birds who preen to insulate themselves.