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TE 802 Group Unit Plan ------------------------------------------------------------------Names of Group Members AND their contributions: 1. Travis (c 4.8A, c 4.8B, c 4.8C) 2. Stephen (4.8 d, 4.8 g) 3. Kyle (4.8 e, 4.8 f) 4. Liz (4.8h, 4.8 i) (also did a stellar job helping out with the OPM table!) 5. Caitlin (4.9a, 4.9b, 4.9 c) Topic: Periodic Table Abstract This unit addresses the periodic table and how it can be used to determine the subatomic particles present in the atoms of each element, and what the properties of those particles are. Additionally students will learn to use the periodic table to determine the oxidation states, electron configuration, and electron orbitals for elements. Students should already have completed units on the history of the atom and atomic theory. They should be able to identify the major experiments that have led to the development of the current model of the atom from its modest beginnings as a single indivisible piece of matter. The units following this will cover chemical bonding and formula writing. CLARIFYING YOUR GOALS A. School Science Approach Facts -Protons and neutrons make up the nucleus of an atom, and it is surrounded by electrons. -Periodic table groups elements based on chemical and physical properties, with certain atomic trends appearing as you travel across a period or down a group: -Atoms are mostly empty space; there is a small, dense nucleus at the center, then a large amount of space that electrons “live” in. -Electrons are located in clouds around the nucleus, and that “cloud” represents an area of very high probability where they may be found. Nodes represent areas where electrons have a 0% chance of being found; as you increase the principle quantum number, so too do you increase the number of nodes found in any single orbital. Vocabulary Words Orbitals: Each of the actual or potential patterns of electron density that may be formed in an atom or molecule by one or more electrons and that can be represented as a wave function Protons: positively charged particles in the nucleus of the atom; characteristic particle of the element Neutrons: neutrally charged particles in the nucleus of the atom; isotopes of the same element have a different number of neutrons Electrons: electrically charged particles surrounding the nucleus of the atom; ions of the same element have a different number of electrons Nucleus: The positive center of an atom that contains the majority of its mass Periodic Table: A table of all known chemical elements arranged by mass, atomic properties, and electron configuration. Ionization Energy: Energy required to completely remove an electron from an atom Physical change: Bonds remain unchanged, while the state or some other physical property (color, size, and temperature) may change Chemical change: Bonds are broken and formed between new atoms, changing the chemical composition Metal: ● good conductors of heat and electricity ● high densities ● high melting points and boiling points ● generally form cations as they lose electrons ● located in the middle and far left of the periodic table Metalloid: Generally share properties with metals and nonmetals without being classified one way or the other. These include boron, silicon, germanium, arsenic, antimony, and tellurium, with some lists occasionally including aluminum, carbon, selenium, polonium, and astanine. Nonmetal: ● ● ● poor conductors of heat and electricity in solid form, they are dull and brittle they have significantly lower melting points and boiling points ● non-metals have high electronegativity ● generally form anions as they gain electrons ● located on the far right of the periodic table [with the exception of hydrogen] Electronegativity: The tendency of an atom to draw electrons in towards itself Hund’s Rule: Every degenerate orbital must be filled with one electron before any orbital gets two; and each electron in singly-occupied orbitals has the same spin. Aufbau Principle: Electrons fill the lowest energy orbitals before moving to higher energy orbitals Pauli Exclusion Principle: No electrons with the same spin may occupy an orbital at the same time. Valence electrons: Electrons located in the highest energy orbital Ions: Elements with differing charges; the different charge comes from gaining or losing electrons. Isotopes: Elements with differing masses but identical protons/electrons; the extra mass comes from extra neutrons in the nucleus. Diagrams or standard representations Thomson Model Bohr Model D Orbitals Orbitals! Lewis Dot Structure Periodic Table Formulas or problem-solving skills Formal charge of an atom: Number of valence electrons - number of non-bonding electrons - [number of bonded electrons / 2] General understanding of atomic trends: It is important for students to understand the WHYs behind atomic trends. ● Atomic radius increases going down a group because more orbitals are being added on; it decreases going across a period because the attraction between the positive nucleus and the electrons increase as the number of valence electrons increase ● Electronegativity increases going across a period because atoms need fewer electrons to reach a full, stable octet; it decreases going down a group because more orbitals are being added on, and they are shielding the positive charge of the nucleus ● Ionization energy increases going across a period because the atoms need fewer electrons to reach a full, stable octet so they are less inclined to give up electrons; it decreases going down a group because more orbitals are being added on, so they shield the positive charge of the nucleus, allowing the electrons in the valence shell to pull away more easily. B. Standards and Benchmarks Benchmarks for Science Literacy 1. History often involves scientific and technological developments. 1C/H3b 2. From time to time, major shifts occur in the scientific view of how things work. More often, however, the changes that take place in the body of scientific knowledge are small modifications of prior knowledge. Continuity and change are persistent features of science. 1A/H2* 3. No matter how well one theory fits observations, a new theory might fit them just as well or better, or might fit a wider range of observations. 1A/H3a National Science Education Standards http://www.nap.edu/openbook.php?record_id=4962&page=111 Michigan Content Expectations C4.8A- Identify the location, relative mass, and charge for electrons, protons, and neutrons. C4.8B- Describe the atom as mostly empty space with an extremely small, dense nucleus consisting of the protons and neutrons and an electron cloud surrounding the nucleus. C4.8C- Recognize that protons repel each other and that a strong force needs to be present to keep the nucleus intact. C4.8D- Give the number of electrons and protons present if the fluoride ion has a -1 charge. C4.8e- Write the complete electron configuration of elements in the first four rows of the periodic table. C4.8f- Write kernel structures for main group elements. C4.8g- Predict oxidation states and bonding capacity for main group elements using their electron structure. C4.8h- Describe the shape and orientation of s and p orbitals. C4.8i- Describe the fact that the electron location cannot be exactly determined at any given time. C4.9A- Identify elements with similar chemical and physical properties using the periodic table. C4.9b- Identify metals, non-metals, and metalloids using the periodic table. C4.9c- Predict general trends in atomic radius, first ionization energy, and electonegativity of the elements using the periodic table. Synthesized Objectives Students will be able to identify ions and use oxidation numbers in order to determine how elements bond to one another. Students will also be able to appropriately determine how the bonding in a compound changes as the oxidation numbers in the compound change. (C1.1f, C4.8D, C4.8g) Students will be able to group elements in the periodic table using chemical and physical properties into metals, non-metals, and metalloids, and be able to predict the general trends of the elements in the periodic table using data and empirical evidence. (C4.9A, C4.9b, C4.9c, C1.1D, C1.1g) Explain the structure of the atom, including the location and properties of its subatomic particles. (4.8A, 4.8B, 4.8C) Compare and contrast new and old atomic models using orbitals and probability. (4.8h, 4.8 i) Write electron configurations for various elements and identify patterns of electron configuration using the Periodic Table. (4.8 e, 4.8 f, C1.1d) C. Big Ideas Atoms are elementary particles that are the building blocks of everything around us. Their structure is surprisingly simple. They are mostly empty space, with a tiny, extremely dense nucleus. Within this dense nucleus are the important parts of the atom, the protons, and neutrons. Protons have a mass of 1.67262158 E-27 kg, and a positive charge therefore they repel each other very strongly so it is necessary for a very strong force to be present to keep the nucleus intact. Neutrons have a mass of 1.674927 E-27 kg, and carry no charge. Surrounding the nucleus there is a ‘cloud’ of electrons. Which is referred to as a cloud because the exact location of an electron cannot ever be pinpointed exactly. This is because electrons move around in order to help atoms of differing elements to bond with one another, also due to its extremely small mass (9.10938188 E-31 kg). Electrons organize themselves into what are commonly referred to as orbitals. Be careful with the word orbital they are not like planets that orbit; they are energy levels that electrons occupy depending on their state of excitement. These orbitals come in several different shapes, the most common shapes for lower energy elements are s and p orbitals. An s orbital is sphere around the nucleus. A p orbital is shaped like an oblong 8 with the nucleus at the center of the 8 where the two ovals intersect. The orbitals are filled based off of several rules, first of which is the Aufbau principle which says electrons want to occupy the lowest state of energy so they fill from the lowest up. An electron will not enter a higher state of energy unless all the lower orbitals are filled. An orbital is considered full when it contains two electrons of opposite and equal spin. (Pauli Exclusion Principle) Electrons don’t like to be paired up if they can avoid it though and Hund’s Rule states that electrons will try for the maximum amount of unpaired occupied orbitals. So all orbitals in a given energy level fill with one electron before cycling back through adding the second electron then if more electrons remain they start to fill the next energy level. What is an important thing to look for in this process is a special type of electron called valence electrons, which means the outermost or highest energy electrons. These electrons because of their high energy are the ones that will be the biggest factor in chemical reactions. The Lewis dot structure is how you represent the number of valence electrons for an atom. The Lewis dot structure is the elemental symbol surrounded by the number of valence electrons. The number of valence electrons is determined by how many electrons reside in the highest energy level (not sublevel so it would be all the electrons in for instance 6s and 6p not just 6p is 6 was the highest energy level represented). The periodic table is a table with all the known elements in it. They are not just thrown on there, they are organized very specifically. They are organized so all the elements with similar chemical and physical properties are near one another. There are many ‘groups’ on the periodic table such as metals, non-metals, metalloids, and gases. The elements are ordered by increasing atomic number. There are many trends in the periodic table because of the way they are grouped. Atomic radius of an element increases as you go down the periodic table and from right to left. Ionization energy increases as you go up the periodic table and as you go left to right across it. And electronegativity increases as you go up the periodic table and from left to right. D. Observations, Patterns, and Models Observations or experiences (examples, phenomena, data) WHAT Patterns (laws, generalizations, graphs, tables, categories) HOW Models (explanations, theories) -Protons have mass of 1.67262158 × 10-27 kg -Neutrons have mass of 1.6749 x 10-27 kg -Electrons have mass of 9.10938188 × 10-31 kg -Carbon has a mass of 12.001 amu -Hydrogen has a mass of 1.01 amu -Oxygen has a mass of 15.999 amu -Rutherford Gold Foil Experiment: Dense nucleus, protons inside the nucleus and electrons outside the nucleus. -Electron only found in certain areas surrounding the nucleus (s orbital, p orbital, d orbital, nodes) -Different models of atom (Dalton, Thomson, Bohr, Quantum) -Atoms have mass -Protons and neutrons have more mass than electrons -Nucleus is the most dense part of the atom -Generally, the higher the atom is on the periodic table, the more mass it has. -The atomic number correlates to the number of protons in an atom. -Atoms have a specific structure Atomic models: Each atom has a characteristic number of protons in a dense nucleus with a corresponding number of electrons to keep it neutral. Atoms also have neutrons that exist with the protons inside the nucleus. -Electrons fill orbitals in a certain order. -Each element has its own electron configuration -Electrons occupy space in the electron cloud known as orbitals which surround the nucleus. -Aufbau Principle: Electrons fill the lowest energy orbitals before moving to higher energy orbitals -Pauli Exclusion Principle: No electrons with the same spin may occupy an orbital at the same time. -Hund’s Rule: Every degenerate orbital must be filled with one electron before any orbital gets two; and each electron in singly-occupied orbitals has the same spin. Electron configuration: Every electron in an atom must have a different quantum number as no two may exist in the same exact place at the same exact time. Because of this, electrons end up existing in orbitals surrounding the nucleus. The more electrons, the more orbitals that are filled. -Atoms that share chemical/physical properties are placed in the same groups -Atoms are classified by properties and periodic table location -Atomic radius decreases as you go across a period, increases down a group -Electronegativity increases as you go across a period, decreases as you go down a group -Ionization energy increases as you go across a period, Periodic Table: - Atomic radius: decreases down a period due to a stronger pull by the nucleus on the electrons and increases down a group due to an increase in orbital shells -Sodium reacts more violently than lithium in water -Potassium reacts more violently than sodium in water -Bromine and mercury are liquid at room temperature -Oxygen, nitrogen, hydrogen, helium, etc are gases at room temperature -Copper, carbon, magnesium, sodium, lithium, etc are solids at room temperature -Alkali metals are in group 1 -Alkaline earth metals are in group 2 -Chalcogens are in group 16 -Halogens are in group 17 WHY Electrons must be in the lowest energy configuration for maximum stability. -Ionization energy: increases down a period due to atoms requiring fewer electrons to reach an octet and decreases down a group due to adding more orbital shells which increases shielding -Noble gases are in group 18 -Atoms on the left side of the periodic table are called metals -Atoms on the right side of the table are called nonmetals -Atoms in between nonmetals and metals are called metalloids -Alkali metals/alkaline earth metals react with halogens/chalcogens -Fluorine is more electronegative than oxygen -Fluorine is more electronegative than chlorine -Fluorine has a higher ionization energy than chlorine -Fluorine has a higher ionization energy than carbon -Fluorine has a smaller radius than oxygen -Fluorine has a smaller radius than chlorine decreases as you go down a group -Electrons can be added or removed -Pure elements have an oxidation number (or formal charge) of 0, for example, O(2), H(2), Mg(s). These also have a neutral charge. -Elements that lose electrons are positive ions (cations): ● Mg2+ lost 2 electrons ● Na1+ lost 1 electron ● Al3+ lost 3 electrons -Elements that gain electrons are negative ions (anions): ● Cl1- gained 1 electron ● O2- gained 2 electrons ● F1- gained 1 electron -Na radius is 180 pm -Na1+ radius is 116 pm -F radius is 50 pm -F1- radius is 119 pm -Mg radius is 150 pm -Mg2+ radius is 86 pm -O radius is 66pm -O2- radius is 126 pm -The more electrons an atom gains, the more negative it becomes -The more electrons an atom loses the more positive it becomes. -Cations are generally smaller than neutral atoms -Anions are generally larger than neutral atoms -Electronegativity: increases down a period due to atoms requiring fewer electrons to reach a full octet and decreases down a group due to adding more orbital shells which increases shielding and decreases attraction The table as we have it today has been organized by Mendeleev. The table organizes atoms in rows determined by the number of protons and increasing number of valence electrons, as well as in columns determined by the properties exhibited by the elements. With the way these elements are arranged, it allows for observable trends to be noticed along the table. Ions and Valence Electrons: Ions are when the number of electrons in an atom does not equal the number of protons. This phenomenon gives atoms either a positive or negative charge. A certain amount of energy is required to detach an electron from an atom and so until that energy is supplied (such as in a chemical reaction) electrons generally remain as a valence electron found on an atom. Atoms are most stable with 8 electrons in their valence shell, so they either lose electrons if they have less than 4 (metals/cations) or gain electrons if they have more than 4 (nonmetals/anions) to do this. Adding electrons increases the pull exerted by the nucleus which decreases atomic radius, and removing decreases the pull which increases atomic radius Oxidation numbers involve the transfer of electrons during reactions. Free elements maintain an oxidation number of zero, but compounds contain oxidation numbers that result in an overall oxidation number of zero (unless the compound itself has a charge than the net number will match the charge) E. Students’ Prior Knowledge A. Accurate examples or ideas you can build on - Know that protons, neutrons, and electrons are in atoms. - Protons have a positive charge; electrons have a negative charge; neutrons are neutral. - Protons and neutrons are in the nucleus; electrons orbit nucleus. - Atoms can have a positive, negative, or neutral charge, depending on the number of protons, electrons, and neutrons. - Students are aware of elements, like Hydrogen, Carbon, Nitrogen, etc., but may not understand what they are composed. - Understand what atoms, molecules and compounds are. B. Common misconceptions - The size of the proton, neutron and electron have the same mass. - Neutrons contain a negative charge because neutron “sounds” negative. - The atom is not mostly empty space, but rather it is solid. - You can see the atom. - Electrons are in the nucleus. - Fill the electrons according to number and not by energy level. - Confuse atomic number with valence number. - The Periodic Table is just a table with no rhyme or reason for the placement of the elements. ASSESSMENT AND ACTIVITIES Synthesized Unit Objectives Summative Assessment Formative Assessment Major Activity Compare and contrast new and old atomic models using orbitals and probability. (4.8h, -Test questions. 1. Draw each of the following: (a) 2) 1s (b) 2px (c) 3dxy 2. Draw a picture of - Exit pass/bell work. Have students draw Bohr models for different atoms, or -Poster project. Students will gather into groups of four and draw atomic models throughout the years [Thomson --> Bohr --> 4.8 i) Bohr’s model of the oxygen atom and make sure to label (a) protons (b) neutrons (c) electrons. 3. What is the majority of the atom and which experiment proved this? have them draw different orbitals when given the specific four quantum numbers— although that could also be done just by saying “draw the 3pz orbital,” if that is better for the students. Identify ions and use oxidation numbers to determine how elements bond. Also appropriately determine how the bonding in a compound changes as the oxidation numbers in the compound change. Test / Quiz 1. List the number of protons and electrons found in each listed ion: a. H+ b. Li+ c. Zn2+ d. Al3+ e. NH(4)+ Bell Work What are valence electrons and what happens to an atom as electrons are either added to or taken away from that atom. 2. Write about the differences between MgCl(4) and MgCl(2). Make sure to list the oxidation numbers. It may be helpful to draw the Lewis dot structures 3. What are oxidation numbers? Current orbital model]. They will need to say who discovered the model, make sure everything is labeled properly, and explain in 2-4 sentences why the scientist thought that was the proper model, i.e. Rutherford’s gold foil experiment. Hopefully this will reach a variety of kids, since it involves writing and drawing, and it will help them see how the model evolved over the years, since it’s not a direct lecture. After students finish the bell work, hold a class discussion taking in ideas on what students think happen to an atom as electrons are either added to or taken away from it. Ask students what they think an ion is giving the hint that it Ticket to leave has to do with the number of Label the oxidation electrons on an atom. Guide numbers in the reaction discussion to the idea that ions CO(2) + H(2) -> CO + are atoms where electrons do H2O. Mention how we not equal the number of will be visiting these protons on an atom. types of reactions later more in depth Break up students into groups and ask them to write up ways to organize ions. Take volunteers from groups to share what they’ve come up with. Afterwards, show them how scientists describe and label ions. For example: Cl-, Ag+, Mg2+, Mg4+. Hand out flashcards to the groups that contain matching scenarios such as the following: “I have 18 electrons but I have a net charge of negative 1... What ion am I?” ( Cl-1) or “How many electrons total does Mn+4 have?” Have groups cycle through these flash cards with a periodic table to help them not only become familiar with ions but also with the table itself Write electron configurations for various elements and identify patterns of electron configuration using the Periodic Table Test / Quiz 1. Write the electron configuration for the following elements. a. C b. Cl c. V d. Se e. Na 2. Write the electron configuration using noble gas configuration. a. Al b. Ni c. Br d. Be e. Nb 3. How are the electron configuration for nitrogen and phosphorous similar? 4. What is Hund’s Rule? While during lecture and homework students will be asked questions that have them writing the various electron configurations for different elements. Furthermore, the teacher will use cold call to ask students to recite the electron configuration of elements with a low number of electrons. Students will be asked to explain the Aufbau Principle, Pauli Exclusion Principle and Hund’s Rule. Students will partake in an activity that makes them fill an apartment complex that follows the rules of filling electrons while writing electron configurations. Students will be told they are an owner of a special apartment building that has special rules for filling its occupants. The rules are as follows: 1) The lowest floor must be completely filled before the next floor can be occupied. (Aufbau Principle) 2) Nobody can have a roommate until every room on the floor has an occupant (Pauli Exclusion Principle) 3) There can only be 2 people per room. 4) There can be no male-male or female-female roommates, only male-female. (Hund’s Rule) After being told these rules they will have to fill the apartment by the rules. After going over this, we will discuss how filling the apartment is like filling orbital diagrams. Then after the activity we will go over how to do electron configuration and how it relates to orbital notation. Once we have completed that we will do several, and I mean several, practice problems to get them used to writing the elements in electron configuration. Students will be able to group elements in the periodic table using chemical and physical properties into metals, nonmetals, and metalloids, and be able to predict the general trends of the elements in the periodic table using data and empirical evidence. (C4.9A, C4.9b, C4.9c, C1.1D, C1.1g) (questions modified from Holt Chemistry) The difference between the atomic number of an element in Period 2 and the atomic number of the element in Period 3 directly below it is? The elements of a group on the periodic table have similar what? The alkali metals are found in which group of the periodic table? The elements in Group 18 are called? ____________ is a chemical property of alkali metals Which groups consists of metals that typically form ions with a 2+ charge? The energy required to remove the first electron from a neutral atom is called ____________ and generally ____________ in successive atoms down through a group. From top to bottom in most groups of elements, atomic radii tend to? Not including the noble During lecture teach will use cold call to review the concepts just covered throughout lecture and to review when lecture moves on to multiple days. (borrowed/modified from Holt Chemistry) Have students observe reactions of halide ions with different reagents and analyze data to determine characteristics reactions of each halide ion Have students use references to research the properties different groups of elements. Mix up the properties and have students match them with the different groups. Make up some elements and list some properties physical and chemical and have the students place them with the group they would belong to. gases, the elements with the highest electronegativities are located in the ____________ of the periodic table. Explain the structure of the atom, including the location and properties of its subatomic particles. (4.8A, 4.8B, 4.8C) Test Sample questions: 1.) According to the law of conservation of mass, if Element A has an atomic mass of 2 mass units, and element B has an atomic mass of 3 mass units, what is the mass of compound AB? 2.) What number uniquely identifies an atom? 3.) What was Rutherford able to determine about the structure of the atom with his gold foil experiment? 4.) Which two particles are found in the nucleus of all atoms but Hydrogen1? 5.) What is the definition of an atom? Group presentation on the important experiments and revisions of the atomic theory. Constructing a Model activity adapted from Modern Chemistry by Davis, Frey, Sarquis, Sarquis. Objective: The goal of this For this activity, activity is to have students separate the class into construct a model of an groups. Each group unknown object by making will be assigned inferences about an object a notable scientist that is in a closed container who helped advance without touching or seeing the atomic theory. that object. Examples include Lavoisier Procedure: (conservation of mass), Proust 1. Separate the class into (definite groups of 4-5 students. Each proportions), member of the group is Rutherford (Gold required to record the data foil experiment), etc. they collect and the In class give each inferences they made from group time to that data research what the 2. Provide each group with a scientist sealed box filled with objects did, and what of different size, inferences they drew mass, and shape. from their 3. Without opening the box, observations. Each students must manipulate group will then the box in an attempt to get 35-5 minutes to determine which objects are report their findings in the box. to the class. Have the 4. Record observations you groups present on made, such as weight, number of objects, sound of their scientist in chronological order, and after each presentation discuss how their observations added to the previous understanding of the atom. objects, etc. 5. From those observations try to determine what objects are inside the box. 6. Open up the box and compare your guesses to the actual objects, which did you get right, what did you miss. Discuss: 1. Real scientists use more than one method to gather data, how is this illustrated by this activity? 2. Of the observations you made, which were qualitative and which were quantitative? 3. What parallels can be drawn between this activity, and the experiments conducted in order to determine the structure of the atom?