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Chapter 8 Precambrian Earth and Life History— The Archean Eon • Archean Rocks The Beartooth Mountains on the Wyoming and Montana border some of the oldest rocks in the US. gneiss Precambrian Time Span The Precambrian lasted for more than 4 billion years! If Earth’s history were a 24 hour clock, the Precambrian would use 21 hours! • 88% of geologic time Precambrian • from Earth’s origin 4.6 billion years ago – to the beginning of the Phanerozoic Eon • 542 million years ago • all rocks older than the Cambrian system • No rocks are known for the first 600 million years of geologic time • The oldest known rocks on Earth • 4.0 billion years old Two eons for the Precambrian – Archean and Proterozoic • which are based on absolute ages from igneous and metamorphic rocks Eoarchean? – What we know: – Earth accreted from planetesimals – differentiated into a core and mantle • some crust was present – bombarded by meteorites – Volcanic activity was occurring globally – An atmosphere formed, quite different from today’s – Oceans began to accumulate Hot, Barren, Waterless Early Earth • Shortly after accretion, Earth was – – – – a rapidly rotating, hot, barren, waterless planet bombarded by meteorites and comets with no continents, intense cosmic radiation and widespread volcanism Eoarchean evidence shows: • Continental crust was present by 4.0 billion years ago – Evidence: Sedimentary rocks in Australia contain detrital zircons (ZrSiO4) dated at 4.4 billion years old • so source rocks at least that old existed • Eoarchean Earth probably rotated in as little as 10 hours – and the Earth was closer to the Moon • By 4.4 billion years ago, the Earth cooled sufficiently for surface waters to accumulate Eoarchean Crust – mafic and ultramafic magma: Temperatures > 1600C – and numerous subduction zones developed – Small island arcs • Eoarchean continental crust may have formed – by collisions between island arcs – as silica-rich materials were metamorphosed. – Larger groups of merged island arcs • protocontinents • grew faster by accretion along their margins Origin of Continental Crust • Intermediate • (Andesitic) island arcs – form by subduction – and partial melting of oceanic crust • The island arc collides with another Continental Foundations • Continents: composition similar to granite (same density as silica or quartz) • Continental crust is thicker • Ocean crust: Composition of basalt and gabbro (higher density ) Ocean Crust is thinner Cratons • Cratons have experienced little deformation – since the Precambrian • Precambrian shields are exposed ancient rocks on all continents • Covered by platforms – Sedimentary rocks that overlie the shield – Shield + Platform = Craton Distribution of Precambrian Rocks • The exposed craton in North America is the Canadian shield – northeastern Canada – large part of Greenland – parts of the Lake Superior region • in Minnesota, Wisconsin, and Michigan – and the Adirondack Mountains of New York Evolution of North America • North America evolved by the amalgamation of Archean cratons that served as a nucleus around which younger continental crust was added. Archean Rocks • granite-gneiss complexes – ultramafic igneous peridotite – sedimentary rocks had been metamorphosed • Greenstone belts are 10% of Archean rocks – Help unravel Archean tectonic events Archean Rocks • Outcrop of Archean gneiss cut by a granite dike from a granite-gneiss complex in Ontario, Canada Archean Rocks • Shell Creek in the Bighorn Mountains of Wyoming has cut a gorge into this 2.9 billion year old granite Greenstone Belts • A greenstone belt has distinct rock units – volcanic rocks are most common – Sedimentary – Intruded by granitic magma • Low-grade metamorphism – Makes igneous rocks green – chlorite, actinolite, and epidote Greenstone Belts and GraniteGneiss Complexes • Two adjacent greenstone belts showing synclinal structure • They are underlain by granite-gneiss complexes • and intruded by granite Greenstone Belt Volcanics • Pillow lavas in greenstone belts – indicate that much of the volcanism was – subaqueous Pillow lavas in Ispheming greenstone belt at Marquette, Michigan Ultramafic Lava Flows • Ultramafic magma (< 45% silica) – requires near surface magma temperatures of more than 1600°C – 250°C hotter than any recent flows • Why then, not now? Early Earth: – radiogenic heating was greater – and the mantle was as much as 300 °C hotter • Earth cooled: They are rare in rocks younger – than Archean and none occur now To summarize… Ultramafic Lava Flows • As Earth’s production – of radiogenic heat decreased, – the mantle cooled – and ultramafic flows no longer occurred Sedimentary Rocks of Greenstone Belts • Many of these rocks are successions of – graywacke • sandstone with abundant clay and rock fragments – and argillite = shale Sedimentary Rocks of Greenstone Belts • Small-scale cross-bedding and graded bedding – indicate an origin as turbidity current deposits Canadian Greenstone Belts • In North America, – most greenstone belts – (dark green) – occur in the Superior and Slave cratons – of the Canadian shield Evolution of Greenstone Belts • Greenstone belts formed in several tectonic settings • Models for the formation of greenstone belts – involve Archean plate movement • In one model, greenstone belts formed – in back-arc marginal basins Evolution of Greenstone Belts • According to this model, – There was an early stage of extension as the backarc marginal basin formed – volcanism and sediment deposition followed Evolution of Greenstone Belts • Then during closure, – the rocks were compressed, – metamorphosed, – and intruded by granitic magma • The Sea of Japan – is a modern example – of a back-arc basin Archean Plate Tectonics • Plates moved faster – heat from Earth’s origin – more radiogenic heat (radioactive decay), – Magma generated more rapidly • Therefore… – continents grew rapidly – By continental collision and accretion with other plates and islands Southern Superior Craton Evolution Geologic map • Plate tectonic model for evolution of the southern Superior craton • North-south cross section • Greenstone belts (dark green) • Granite-gneiss complexes (light green Atmosphere and Hydrosphere • Today’s atmosphere: – nitrogen (N2) 78% – free oxygen (O2) 21% • or oxygen in compounds (CO2) – water vapor (H2O) varies 0.1 – 04% – other gases, like ozone (O3) ~ < 2% • block most of the Sun’s ultraviolet radiation Earth’s Very Early Atmosphere – hydrogen and helium, • the most abundant gases in the universe • Earth’s gravity is insufficient to retain them • Earth had no magnetic field until its core formed (magnetosphere) • Without a magnetic field, – the solar wind would have swept gases away Outgassing • After magnetic field forms: – Atmosphere accumulated from outgassing • during volcanism • Water vapor – – – – – – common volcanic gas volcanoes also emit carbon dioxide sulfur dioxide Methane Nitrogen oxide Archean Atmosphere • Archean volcanoes – emitted the same gases, – atmosphere developed – ! lacking free oxygen and an ozone layer • Oxygen in compounds: CO2, ammonia (NH3) methane (CH4) Evidence for a lack of Free Oxygen Atmosphere • detrital deposits – contain minerals that oxidize rapidly – These minerals are NOT bound to typical abundances of oxygen • pyrite (FeS2) • uraninite (UO2) Introduction of Free Oxygen • Two processes account for 1. Photochemical dissociation • radiation breaks up water molecules upper atmosphere – releases their oxygen and hydrogen – 2% of present-day oxygen • with 2% oxygen, ozone forms, creating a barrier against ultraviolet radiation 2. More important were the activities of organisms that practiced photosynthesis Photosynthesis • Photosynthesis is a metabolic process – carbon dioxide and water make organic molecules – and oxygen is released as a waste product CO2 + H2O ==> organic compounds + O2 – probably no more than 1% of the free oxygen level – of today was present by the end of the Archean Oxygen Forming Processes • Photochemical dissociation and photosynthesis – added free oxygen to the atmosphere – Once free oxygen was present – an ozone layer formed – and blocked incoming ultraviolet radiation Earth’s Surface Waters • Volcanic Outgassing Meteorites and icy comets Rapid rate of accumulation of water – Most of hydrosphere in the oceans -- more than 97% • – Today: water vapor still emitted the rate of volcanism has decreased considerably – -- heat needed to generate magma has diminished Decreasing Heat • Ratio of radiogenic heat production in the past to the present • With less heat outgassing decreased • Heat production 4 billion years ago was 3 to 6 times as great as it is now First Organisms • We have fossils from Archean rocks 3.5 billion yrs – Only bacteria and archea are found in Archean rocks • Chemical evidence in rocks in Greenland – that are 3.8 billion years old – convince some investigators that organisms were present then What Is Life? • living organism must reproduce – and practice some kind of metabolism • The distinction between – living and nonliving things is not always easy • Are viruses living? – When in a host cell they behave like living organisms – but outside they neither reproduce nor metabolize What Is Life? • Carbon based molecules known as microspheres – form spontaneously – can even grow and divide in a somewhat organism-like fashion – but their processes are more like random chemical reactions, so they are not living How Did Life First Originate? – from non-living matter (abiogenesis), life must have passed through a prebiotic stages – it showed signs of living – but was not truly living • The origin of life has 2 requirements – source of appropriate elements for organic molecules – energy sources to promote chemical reactions Elements of Life • All organisms are composed mostly of – – – – carbon (C) hydrogen (H) nitrogen (N) oxygen (O) – SPONCH • all of which were present in Earth’s early atmosphere as – – – – – carbon dioxide (CO2) water vapor (H2O) nitrogen (N2) and possibly methane (CH4) and ammonia (NH3) Basic Building Blocks of Life • Energy from • Lightning, volcanism, • ultraviolet radiation – C, H, N, and O combined to form monomers • such as amino acids • Monomers are the basic building blocks – of more complex organic molecules Experiment on the Origin of Life • Is it plausible that monomers – originated in the manner postulated? – Experimental evidence indicates that it is • Late 1950s – Stanley Miller – synthesized several amino acids – by circulating gases approximating – the early atmosphere – in a closed glass vessel Experiment on the Origin of Life • This mixture was subjected to an electric spark – to simulate lightning • In a few days – it became cloudy • Produced – several amino acids – typical of organisms – had formed • Since then, – scientists have synthesized – all 20 amino acids – found in organisms Polymerization • The molecules of organisms are polymers • consisting of monomers linked together in a specific sequence • RNA (ribonucleic acid) and DNA (deoxyribonucleic acid) • Problem: • Water usually causes depolymerization, – however, researchers synthesized molecules – known as proteinoids when heating dehydrated concentrated amino acids Proteinoid Microspheres • Proteinoid microspheres produced in experiments • Proteinoids grow and divide much as bacteria do Protobionts • These proteinoid molecules can be referred to as protobionts – that are intermediate between – inorganic chemical compounds – and living organisms Monomer and Proteinoid Soup: Model for abiogenesis • Monomers likely formed continuously and by the billions – accumulated in the early oceans into a “hot, dilute soup” – The amino acids in the “soup” dried (might have washed up onto a beach or perhaps cinder cones) – they were polymerized by heat • The polymers then washed back into the ocean – where they reacted further Next Critical Step • The microspheres divide – and may represent a protoliving system – but in today’s cells, nucleic acids, • either RNA or DNA – are necessary for reproduction Dead End??? • The problem is that nucleic acids – – – – cannot replicate without protein enzymes, and the appropriate enzymes cannot be made without nucleic acids, or so it seemed until fairly recently Much Remains to Be Learned • Many researchers believe that – the earliest organic molecules were synthesized from atmospheric gases – but some scientist suggest that life arose instead – near hydrothermal vents on the seafloor Submarine Hydrothermal Vents • Seawater seeps into the crust near spreading ridges, becomes heated, rises and discharges hot waters • Black smokers • Mineral-rich fluids Submarine Hydrothermal Vents • Several minerals containing zinc, copper, and iron precipitate around them • Communities of organisms – previously unknown to science, are supported here. – Necessary elements, sulfur, and phosphorus are present in seawater – Polymerization can take place on surface of clay minerals – Protocells were deposited on the ocean floor Oldest Known Organisms • The first organisms were archaea and bacteria – both of which consist of prokaryotic cells, – cells that lack an internal, membrane-bounded nucleus and other structures Oldest Know Organisms • stromatolites, – not until 1954 were they shown – to be products of organic activity Present-day stromatolites (Shark Bay, Australia) Stromatolites • Different types of stromatolites include – irregular mats, columns, and columns linked by mats Stromatolites • Present-day stromatolites form and grow – as sediment grains are trapped – on sticky mats – of photosynthesizing cyanobacteria • The oldest known undisputed stromatolites – are found in rocks in South Africa – that are 3.0 billion years old Other Evidence of Early Life • The oldest known cyanobacteria – were photosynthesizing organisms: COMPLEX!! • A simpler type of metabolism – must have preceded it • No fossils are known of these earliest organisms Earliest Organisms • The earliest – tiny anaerobic bacteria – required no oxygen • totally depended on – external source of nutrients – Heterotrophic • They all had only prokaryotic cells • The earliest organisms, then, – were anaerobic, heterotrophic prokaryotes Fossil Prokaryotes • Photomicrographs from western Australia’s – 3.3- to 3.5-billion-year-old Warrawoona Group, – with schematic restoration shown at the right of each