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METAMORPHISM: Modification of Rocks by Temperature and Pressure Chapter 6 Continental lithosphere Oceanic crust Continental crust Mantle lithosphere Asthenosphere Pressure (kilobars) Depth Volcanic arc (subduction zone) Zone of continental plate extension 0 0 km 30 30 Ancient stable continental lithosphere 0 1300°C 50 50 50 1300°C isotherm 150 Pressure increases with depth at about the same rate everywhere,... ...but temperature increases at different rates in different regions. Pressure (kilobars) Depth Volcanic arc (subduction zone) Zone of continental plate extension 0 0 km 30 30 Ancient stable continental lithosphere 0 1300°C 50 50 50 1300°C isotherm 150 Regional Shock metamorphism metamorphism Depth, km 0 Regional high-pressure metamorphism Regional metamorphism Oceanic crust 35 75 Oceanic lithosphere Regional Shock metamorphism metamorphism Depth, km 0 Regional high-pressure metamorphism Contact metamorphism Regional metamorphism Oceanic crust 35 Oceanic lithosphere 75 Water Burial metamorphism Seafloor metamorphism Metamorphism of sedimentary rocks —shales undergo the most spectacular metamorphosis of all the rocks. The reason is that the clay minerals form at Earth surface temperature (T) (030 C) and pressure (P) (1 bar) by weathering of pre-existing rocks. Thus, clay minerals are grossly out of equilibrium with the high temperature and pressure conditions found at depth in the Earth’s crust. When shale is buried to deeper crustal levels beneath, for example, mountain belts, the original clay is transformed to chlorite, and then to biotite/muscovite, with increasing T and P. These micaceous minerals are platy; they grow large and become aligned in the metamorphic stress field, giving the rock a foliated appearance. slate (phyllite) schist gneiss slate - phyllite schist gneiss Increasing intensity of metamorphism Low grade Intermediate grade Increasing crystal size Increasing coarseness of foliation High grade Foliation is the result of compressive forces. Mineral crystals elongate perpendicular to the compressive force. Feldspar Quartz Mica Pyrite Staurolite Staurolite crystal Mica Foliated rocks are classified by the degree of cleavage, schistosity, and banding. Diagenesis Slate Slaty cleavage Low grade Intermediate grade Phyllite High grade Schist (abundant micaceous minerals) Gneiss (fewer micaceous minerals) Migmatite Schistosity Banding Banding Rocks without clay minerals do not form micaceous minerals during metamorphism and, thus, tend not to be foliated. Examples are limestone and sandstone, which form marble and quartzite, respectively. In the limestone, the pre-existing grains of calcite and skeletal fossils (bioclasts) are obliterated and new larger crystals of calcite form in the high P and T conditions. In the sandstone, the quartz grains become welded together by quartz cements. Granoblastic texture results. Schists have the tendency to grow one mineral much larger than the others. The large mineral is called a porphyroblast. The mineralogy of the porphyroblast changes with increasing T and P. A common porphyroblast is garnet. A series of porphyroblast polymorphs denoting increasing temperature is staurolite, kyanite, silliminite. The fact that certain minerals will grow only within a restricted range of temperatures and pressures gives way to the concept of using mineral assemblages to determine metamorphic conditions–--the minerals behave as paleothermometers and paleobarometers. Degree of metamorphism Diagenesis Low Greenschists Intermediate High Amphibolites Granulites Chlorite White mica (mainly muscovite) Biotite Garnet Staurolite Kyanite Sillimanite Albite (sodium plagioclase) With increasing metamorphic Mineral suites define grade, mineral composition metamorphic facies. changes. A metamorphic facies is a set of metamorphic mineral assemblages that were formed under similar pressures and temperatures.[1] The assemblage is typical of what is formed in conditions corresponding to an area on the two dimensional graph of temperature vs. pressure (See diagram at right).[1] Rocks which contain certain minerals can therefore be linked to certain tectonic settings, times and places in geological history of the area.[1] The boundaries between facies (and corresponding areas on the temperature v. pressure graph), are wide, because they are gradational and approximate.[1] The area on the graph corresponding to rock formation at the lowest values of temperature and pressure, is the range of formation of sedimentary rocks, as opposed to metamorphic rocks, in a process called diagenesis.[1] Low Grade Intermediate Grade Phyllite High Grade Schist Blueschist Gneiss Migmatite Temperature (°C) Depth (km) Pressure (kilobars) Slate 0 0 Hornfels 20 0 15 20 25 13.5 Depth (km) 10 Granulite 10 15 Amphibolite 5 Greenschist Pressure (kilobars) 5 30 200 Eclogite 35 600 40 1000 400 800 Temperature (°C) Metamorphic facies correspond to particular combinations of pressure and temperature... … and can be used to indicate specific tectonic environments. Index minerals define metamorphic zones. Isograds can be used to plot the degree of metamorphism. Canada ME NY Isograds VT NH Key: MA CT RI Low grade Medium grade High grade Not metamorphosed Chlorite zone Biotite zone Garnet zone Staurolite zone Sillimanite zone Tectonic transport moves rocks through different pressure-temperature zones, … Low P, Low T High P, High T …and then transports them back to the shallow crust or the surface. Intermediate Grade Depth (km) Pressure (kilobars) Low Grade High Grade Temperature (°C) Pressure-Temperature Paths Click here to view the Flash animation in your web browser