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ENERGY Energy •Ability to do work Kinetic Energy •Energy of motion Temperature •Measure of the Average Kinetic Energy of the particles of a sample vs. Heat •Kinetic energy of the particles (always flows from hot to cold) Potential Energy •Stored energy Temperature Scales in Science • Celsius : – The lowest point on the scale is -273.15 °C • Absolute Zero • Kelvin: – The lowest point on the scale is 0K • Absolute Zero NEVER, EVER USE FAHRENHEIT IN SCIENCE!!!!! IT IS THE “F” WORD!!! What is Absolute Zero? • The point at which no more heat can be removed from a system • Almost no movement of molecules • Theoretical temperature Temperature Conversions Table T K= °C + 273 °C = K-273 (this is not on the table) Energy Changes In a chemical or physical change there may be a transfer of energy (heat) Exothermic process: there is a release of energy (heat) Endothermic process: there is absorption of energy (heat) Energy changes Exothermic Reactions will feel “hot” Endothermic Reactions will feel “cold” What is heat? • Bill Nye The Science Guy on Heat Heating and Cooling Curves • Shows the heating or the cooling of a specific substance • Heat is added at a constant rate • When a substance is undergoing a phase change THE TEMPERATURE DOES NOT CHANGE until the phase change is complete Phase changes (Vocabulary) • • • • • • Melting (Fusion) Vaporization (l-g) Sublimation (solidgas) Deposition (gas solid) Freezing (fusion) Condensation (g-l) GAS T e m p er at ur e (◦ C ) Endothermic Boiling Point LIQUID Melting Point SOLID Time (minutes) GAS T e m p e r a t u re Exothermic LIQUID Freezing Point (◦C) SOLID Time (minutes) Condensation Point T e m p er at ur e (◦ C ) Δ Kinetic Energy Kinetic Energy is constant Δ Kinetic Energy Kinetic Energy is constant Δ Kinetic Energy Time (minutes) Potential Energy is constant T e m p er at ur e (◦ C ) Potential Energy is constant Δ Potential Energy Potential Energy is constant Time (minutes) Δ Potential Energy T e m p er at ur e (◦ C ) q = mCΔT q = mHv q = mCΔT q = mHf q = mCΔT Time (minutes) Law of Conservation of Energy In any chemical or physical process, energy is neither created nor destroyed, it is merely transferred. How is heat measured? • Calorimetry – The precise measurement of heat flow into or out of a system. – The heat released by a system is equal to the heat absorbed by its surroundings – The heat absorbed by a system is equal to the heat released by the surroundings – A calorimeter is an insulated device used to measure the absorption or release of heat Constant Pressure Calorimeter • Most changes in the lab occur at constant pressure • The heat of a system is it’s enthalpy (H) • The heat released or absorbed by a system at constant pressure is equal to the system’s change in enthalpy (ΔH ) • ΔH = q • q= mC ΔT Heat mass Change in temperature (Final Temperature – Initial Temperature) Specific heat ΔH Process Heat Positive (Final Temperature is higher than the initial temperature) Endothermic Absorbed Negative(Final Temperature is lower than the initial temperature) Exothermic Released • Calorimetry