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Changes to the Earth’s rocks and atmosphere Course Notes Chemistry C1 Section 6 2013-15 Inside the Earth The Earth has a layered structure. Large-scale movements of the Earth’s crust can cause changes in the surface rocks. The Earth consists of an inner and outer core, then a mantle and finally a thin crust. The Earth’s crust and the upper part of the mantle are cracked into a number of large pieces called tectonic plates. Convection currents within the Earth’s mantle, driven by heat released by natural radioactive processes there, cause these plates to move at speeds of a few centimetres per year. Earthquakes and volcanoes and occur at the boundaries between tectonic plates. These movements can be sudden and disastrous. Old ideas - bad science Scientists once thought features of the Earth’s surface happened because the crust was shrinking as the Earth cooled down. Evolved atmosphere Start here The Earth forms from dust and gas spiralling inwards. Planet is rocky & rather small First single-celled plant-like organisms live in deepish water to avoid ultra-violet rays - photosynthesis begins! Huge quantities of CO2 are turned into oxygen, O2 gas. Plant-like organisms are the first polluters! First simple animals evolve in water feeding on simple plants - dead organisms move carbon from air to rocks Hydrogen and helium gases escape because Earth is not massive enough (lower gravity than a gas giant planet) Atmospheric oxygen builds up. Ozone, O3, forms in the stratosphere. Ozone shields land from UV rays. With an ozone shield, life can survive on land!! 1 Carbon dioxide and gases blown out of volcanoes form the first atmosphere Steam, methane, ammonia join CO2 - comets bring more water to the Earth as the molten surface solidifies. Oceans form. Steady state - atmosphere in balance Atmosphere reaches a steady state thanks to plants and animals. Most of the high levels of the early carbon dioxide atmosphere is now locked up in rocks (limestone; chalk; fossil fuels … ). Plants turn water and carbon dioxide into sugar and oxygen. Life is a powerful force controlling the composition of the Earth’s atmosphere, which in turn exerts a powerful control on our planet’s climate! Plate tectonics and sea-floor spreading Alfred Wegener He proposed an idea that the Earth’s continents were once joined together. Over a few hundred million years, forces made this supercontinent break up and drift apart. This was his continental drift theory. He offered this evidence: the shapes of Africa and South America look as though they once joined together African and South American rocks which are 200 million years old contain identical fossils and sequences of fossils rocks on the edges of these continents are similar where they might once have joined. New evidence supports Wegener’s theory New evidence from exploring the ocean floor rocks, including the magnetic striping patterns of the mid-ocean rocks, gives us the idea that it is the radioactivity from uranium and thorium that provides the enormous heat source that creates the convection currents that drive the tectonic plates apart. Under the Atlantic ocean, tectonic activity along the mid-Atlantic ridge drives the plates apart. This is called sea-floor spreading. The new evidence proved that Alfred Wegener was correct. The mechanism for Wegener’s theory of crustal movement (continental drift) is now generally accepted. Continents drift because of sea-floor spreading. Scientists cannot accurately predict when earthquakes and volcanic eruptions will occur, because Earthquakes are caused by sudden movements of tectonic plates and volcanic eruptions require sudden changes in pressure deep underground. 2 If recent Earthquakes and volcanic eruptions are plotted on a World map, then a striking pattern emerges. The pattern exposes the positions of the plate boundaries. These are parts of the World where Earthquakes and volcanic activity have happened in the past , but we can only wonder where the next ‘quake will happen. The Earth’s evolving atmosphere For 200 million years, the proportions of different gases in the atmosphere have been much the same as they are today: about four-fifths (78%) nitrogen; about one-fifth (21%) oxygen. small proportions of various other gases, including carbon dioxide, water vapour and noble gases. During the first billion years of the Earth’s existence there was intense volcanic activity. This activity released the gases (called outgassing) that formed the early atmosphere and water vapour that condensed to form the oceans. There are several theories about how the atmosphere was formed. One theory suggests that during this period the Earth’s atmosphere was mainly carbon dioxide and there would have been little or no oxygen gas (like the atmospheres of Mars and Venus today). There may also have been water vapour and small proportions of methane and ammonia. There are many theories as to how life was formed billions of years ago. One theory as to how life was formed involves the interaction between hydrocarbons, ammonia and lightning (the primordial soup theory). This theory is supported by laboratory experiments done by Miller and Urey. Plants and algae produced the oxygen that is now in the atmosphere (photosynthesis). This process takes out carbon dioxide from the atmosphere. Respiration and decay of organic material releases carbon dioxide into the atmosphere. Most of the carbon from the carbon dioxide in the air gradually became locked up in sedimentary rocks as carbonates and fossil fuels. The oceans also act as a reservoir for carbon dioxide but increased amounts of carbon dioxide absorbed by the oceans has an impact on the marine environment. Nowadays the release of carbon dioxide by burning fossil fuels increases the level of carbon dioxide in the atmosphere. Carbon dioxide is a greenhouse gas. Air is a mixture of gases with different boiling points and can be fractionally distilled to provide a source of raw materials used in a variety of industrial processes. Remember oxygen has a higher boiling point (–183℃) than nitrogen (–196℃) because the more negative the number, the lower is the boiling point. 3