Download 索书号：O62 /C713p (MIT) Principles and Applications Of

索书号：O62 /C713p (MIT)
Principles and Applications Of Organotransition Metal Chemistry
Contents
1 A Perspective
Part I Basic and Bonding
2 Structure and Bonding: Electronic Bookkeeping
3 Survey of Organotransition-Metal Complexes According to Ligand
4 Ligand Substitution processes
5 Oxidative-Addition and Reductive-Elimination
6 Intramolecular Insertion Reactions
7 Nucleophilic Attack on Ligands Coordinated to Transition Metals
8 Electrophiliic attack on Coordinated Ligands
9 Metallacycle
Part II Catalytic Processes
10 Homogeneous Catalytic Hydrogenation, Hydrosilation and Hydrocyanation
11 Catalytic Polymerization of Olefins and Acetylenes
12 Catalytic Reactions Involving Carbon Monoxide
Part III Applications to Organic Synthesis
13 Synthetic Applications of Transition-Metal Hydrides
14 Synthetic Applications of Complexes Containing Metal-Carbon σBonds
15 Synthetic Applications of Transition-Metal Carbonyl Compounds
16 Synthetic Applications of Transition-Metal Carbenes and Metallacycles
17 Synthetic Applications of Transition-Metal Alkene, Diene and Dienyl
18 Synthetic Applications of Transition-Metal Alkyne Complexes
19 Synthetic Applications of η³-Allyl Transition-Metal Complexes
20 Synthetic Applications of Arene Transition-Metal Complexes
Index
Abstract
This textbook is intended to introduce both students and experienced chemists to an exiting rapidly growing
interdisciplinary subject: organotransition-metal chemistry. This book represents a thorough revision of the first
edition which has become dated within only six years. During this time the chemistry of organotransition-matal
complexes has continued to experience explosive growth in novel substances, new reactions, surprising
mechanisms, and further applications to both organic synthesis and industrial processes.