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What is Chemistry? Chemistry is______________________________________________, especially its properties, structure, composition, behavior, reactions, interactions and the changes it undergoes Chemistry is sometimes referred to as “the central science” because it connects ____________________with other natural sciences such as ________________________________________________________ When was the beginning of chemistry? Aristotle o All matter was composed of varying combinations of the _________________________________________________________________ o Earth,________________________________________________________,Fire Dalton – 1803 o All matter is made of _______________________. o Dalton envisioned atoms as tiny spheres with hooks on them. o With these hooks, one atom could combine with other atoms in ___________________________________________. J.J. Thompson - 1898 o Thomson proposed a model, sometimes called the ________________________________________________________________________________ _________, in which thousands of tiny, negatively charged corpuscles swarm inside a sort of cloud of massless positive charge. Rutherford – 1911 o Rutherford suggested that the atom might resemble a tiny ____________________________________, o with a massive, positively charged ______________________________________ circled by only a few electrons. Bohr – 1923 o Proposed that electrons exist in ____________________________ What does modern chemistry look like? The Atom o The atom is the smallest particle of an element that retains all of the _____________________________________________________. o The atom has three subatomic particles: the _____________________, the ____________________, and the __________________________. Subatomic Particles o A proton is a ____________________________________ found in the nucleus. It is partly responsible for the mass of an atom. o A neutron is a particle ___________________________________________ found in the nucleus of an atom. It is partly responsible for the mass of an atom. o An electron is a __________________________________________ found outside the nucleus. Electrons are very small and do not add much to the mass of an atom. 1 Elements o Elements are given chemical symbols to represent them. o The first letter (or only letter) is ______________________________. o The second letter (if there is one) is _____________________________. o H is __________________________ o O is Oxygen o Be is Beryllium o Ni is ___________________________ Pure Substances o A pure substance is either an ___________________________________. o An element is a type of matter that is made up only of __________________________________________________. o A compound is two or more elements chemically ______________________________________________. Mendeleev o In 1869, Dmitri Ivanovitch Mendeléev created the first accepted version of the ____________________________________. o He grouped elements according to their __________________________, and as he did, he found that the families had similar ___________________________. o Blank spaces were left open to add the new elements he predicted would occur. The Current Periodic Table Mendeleev wasn’t too far off. Now the elements are put in rows by increasing ___________________________________________ The horizontal rows are called ______________ and are labeled from _____________________. The vertical columns are called ___________________ or families and are labeled from _____________________. Elements o Science has come a long way since Aristotle’s theory of Air, Water, Fire, and Earth. o Scientists have identified ____________________________________________, and created about 28 others. Elements o The elements, alone or in combinations, make up our bodies, our world, our sun, and in fact, the entire universe. o Almost all elements are made up of 3 sub atomic particles. ______________________________________________ o The most abundant element in the Earth’s crust is oxygen. Periodic Table The periodic table organizes the elements in a particular way. A great deal of information about an element can be gathered from its ____________________________________________. 2 For example, you can predict with reasonably good accuracy the ________________________________________ properties of the element. You can also predict what other elements a particular element will react with chemically. Understanding the organization and plan of the periodic table will help you obtain basic information about each of the ____________________________________. What’s in a square? o Different periodic tables can include various bits of information, but usually: o ___________________________________ o ____________________________________ o ___________________________________ Key to the Periodic Table o Elements are organized on the table according _____________________________________________________, usually found near the top of the square. o The atomic number refers to how many _____________________________________________ atom of that element has. o For instance, hydrogen has 1 proton, so it’s atomic number is 1. o The atomic number is ___________________________________. No two elements have the same atomic number. Symbols o All elements have their own _____________________________. o It can consist of a single capital letter, or a _____________________ and one or two ______________________. o Elements have their name for a variety of reasons. Some are named after mythology, countries, scientists or in Latin or Greek. Atomic Number o This refers to how many ________________________________ an atom of that element has. o No two elements, have the same number of protons. Atomic Mass o Atomic Mass refers to the “weight” of the atom. o It is derived at by ________________________________________________________________________ ________________. Atomic Mass Unit (AMU) o The unit of measurement for an atom is an AMU. It stands for atomic mass unit. o One AMU is equal to ______________________________________. 3 o There are o 6 X 1023 or 600,000,000,000,000,000,000,000 amus in one gram. o (Remember that electrons are __________________________ smaller than one amu). Atomic Mass and Isotopes o While most atoms have the same number of protons and neutrons, some don’t. o Some atoms have more or less ___________________________________. These are called isotopes. o An atomic mass number with a decimal is the total of the number of protons plus the _______________________________________________. o We write isotopes like this: o Uranium has 2 isotopes: Uranium – 238 & Uranium - 239 Isotopes o Two atoms of the same element must have the same number of protons, but they do not necessarily have to have ________________________________________________. o NOTE: protons never change (except in nuclear reactions) o Same # of protons and different # of neutrons means you have __________________________________________. o Example: o Carbon most commonly has a mass of 12 6 p + 6n = 12 o Carbon 14 has a mass of 14 6 p + 8n = 14 Isotope Examples o List the protons, neutrons, electrons and the symbol o Carbon – 12 o Carbon – 13 o Carbon – 14 o Note: o The # of neutrons may vary. o Isotopes have different mass numbers. o Isotopes of the same element are still chemically alike because they have the same number of protons and electrons. Symbolizing Isotopes o Write the ____________________________________ o Write the number of protons the element has on the bottom _____________________________________. o Write the mass number on the __________________________. 4 Properties of Metals o Metals are good conductors of ________________________________. o Metals are shiny. o Metals are ductile (can be stretched into thin wires). o Metals are malleable (can be pounded into thin sheets). o A chemical property of metal is its reaction with water which results in ______________________. Properties of Non-Metals o Non-metals are poor conductors of ______________________________. o Non-metals are not ductile or malleable. o Solid non-metals are brittle and break easily. o They are dull (not shiny). o Many non-metals are ____________________. Properties of Metalloids o Metalloids (metal-like) have properties of both __________________________________________. o They are solids that can be shiny or dull. o They conduct heat and electricity better than non-metals but not as well as metals. o They are _________________________________________. Groups or Families o Columns of elements are called ______________________________. o Elements in each family have similar but not identical properties. o For example, lithium (Li), sodium (Na), potassium (K), and other members of family IA are all soft, white, shiny metals. o All elements in a family have the same ______________________________________________________. Periods o Each horizontal row of elements is _____________________________. o The elements in a period are ______________________________ properties. o In fact, the properties change greatly across even given row. o The first element in a period is always an extremely active solid. The last element in a period, is always an inactive gas. o The period tells us how many ____________________ the element has. Group 1: Alkali Metals o A.K.A. the ________________________________ o Very reactive o Metallic o Francium is the most reactive o Six elements (Li, Na, K, Rb, Cs, and Fr) 5 Group 2: Alkaline Earth Metals o A.K.A. ________________________________________ o Six elements (Be, Mg, Ca, Sr, Ba and Ra) o Reactive metals o Radium is most reactive Group 3 and 4 o Vary from metallic and non metallic o Very _______________________________________________. Group 5: Nitrogen Family o Nitrogen and Phosphorous are non-metallic o Bismuth is metallic o Antimony (Sb) and Arsenic (As) exhibit properties of both _______________________________________. Group 6: Oxygen Family o ________________________ on the top and ___________________ on the bottom. Group 7: Halogen Family o Very active non-metals o _______________________ is the most reactive Group 8: Noble Gas Family o Outer shell of ___________________________________ o Very stable elements Transition Elements o Fill in the d shells o Metallic o Number of electrons vary in _________________________________ Rare Earth Elements o Fill in the f shells o Separated into series: o Elements 58-71 are the ____________________________________ o Elements 90-103 are the ____________________________________ Zigzag Line o Line that separates metals from non-metals o Elements that touch the line are called ___________________________ o Metalloids are elements that have both properties of ______________________________________________ Valence Electrons The number of valence electrons an atom has may also appear in a square. Valence electrons are the electrons in the ______________________________________________________________. These are the electrons that are transferred or shared when atoms _______________________________________. 6 What does it mean to be reactive? o We will be describing elements according to their ________________________. o Elements that are reactive bond easily with other elements to make _____________________________. o Some elements are only found in nature bonded with other elements. o What makes an element reactive? o An incomplete __________________________________________. o All atoms (except hydrogen) want to have 8 electrons in their very outermost energy level (This is called the octet rule.) o Atoms bond until this level is complete. Atoms with less than 4 valence electrons lose them during bonding. Atoms with 5, 6, or 7 valence electrons gain electrons during bonding. Elements that have either gained or lost electrons are called ions. o Positively charged: _______________________ o Any atom that loses electrons to form compounds are called cations. Cations have a positive charge. o Naming cations: Use the element name followed by the word “ion”. Some Cations have more than one charged form. o Alkali metals (group 1) have 1 valence electron and are highly reactive because they tend to lose their valence electron E.g. Li+, Na+, K+ o Alkaline Earth Metals (group 2) have 2 valence electrons and therefore must give up 2 electrons E.g. Ca2+, Mg2+, Ba2+ o These are ____________________________ than group 1 Elements that have either gained or lost electrons are called ions. o Negatively charged: _______________________________ o Atoms that gain electrons to form compounds are called anions. Anions have a _________________________________. o Naming Anions: Drop the last few letters of the element name and add “ide”. o E.g. Group 17 (Halogens) gain electrons easily and release lots of energy in the process highly reactive How can we determine the charge of an ion? o For some of the elements it is very easy. Elements in groups 1, 2, 13, 14, 15, 16, & 17 will lose or gain electrons so they have the same # as the nearest _________________________________________ o The _______________________________________________ cannot have their charges predicted in this way due to many of them having isotopes. Their charges must be predicted in other ways. Noble Gases o Noble Gases are colorless gases that are extremely ___________________________. 7 o One important property of the noble gases is their inactivity. They are inactive because their ___________________________________ level is full. o Because they do not readily combine with other elements to form compounds, the ______________________________________. o The family of noble gases includes helium, neon, argon, krypton, xenon, and radon. o All the noble gases are found in small amounts in the earth's atmosphere. Bohr’s Model of the Atom Electrons orbit the nucleus at a ______________________________. Each orbit is associated with a definite ___________________________. Energy levels are quantized o Electrons travel in orbits _______________________________________ o The farther the electron is from the nucleus the more ______________________________________ Bohr Diagrams o These are simple diagrams that show the _____________________________ in each orbital of an element. o The symbol of the element is placed in the nucleus, and electrons are then placed in each orbital. o Let’s do a couple of examples. Bohr-Rutherford Diagrams o These diagrams are a combination of a Bohr Diagram and a Rutherford Diagram. o The main difference between this diagram and the Bohr diagram is the inclusion of the ___________________________________________________________________ How To Draw Bohr-Rutherford Diagrams: o Draw the nucleus as a solid circle. o Put the number of protons (atomic number) in the nucleus with the number of neutrons (atomic mass – atomic number) under it. o Place the number of electrons (same as protons) in orbits around the nucleus by ______________________________________________. Remember, 1st shell – 2 electrons, 2nd shell – 8 electrons, 3rd shell – 8 electrons, 4th shell – 18 electrons. Electron Dot Diagrams If you want to see how atoms of one element will react, it is handy to have an easier way to represent the atoms and the _________________________________________________ You can do this with electron dot diagrams. An electron dot diagram is the symbol for the element surrounded by as many dots as there are _______________________________________________. 8 How to Write Them o The dots are written in pairs on __________________________________________________________________ o Start by writing one dot on the top of the element symbol, then work your way around adding dots to the right, bottom, and left. o Add a fifth dot to the top to make a pair. Continue in this manner until you reach the number of valence electrons the element has or until there are ___________________________________________________________ Finding Valence Electrons o You can do this by using the ______________________ for the element. Eg. N, K (do on board) o You can also find it by using the period # to find # of orbitals (shells). (use previous examples). Hint to make finding valence electrons easier: o When drawing dot diagrams for an element, if the element’s ion form has a positive charge, that # on the charge is the number of valence electrons. o If the ion form has a negative charge, that # on the charge is the # of electrons required to fill the outer orbital to a total of 8 electrons. Forming Compounds Sodium is an element. Chlorine is an element. When sodium and chlorine bond they make the compound _______________________________________, commonly known as table salt. A _____________________________ is formed when valence electrons of atoms interact and become stable. Ionic Compounds – substances composed of cations and anions forming ionic bonds. Certain combinations of elements form ionic bonds (__________________________ with group 16 & 17 nonmetals). Eg. ____________________________ Covalent bond – A bond formed when atoms share ________________________________________________. A neutral particle that is composed of atoms joined together by covalent bonds is called a _________________________________. Eg. Diatomic molecules o Molecules that contain two (“di”) atoms. o “The Magic 7” + Hydrogen – These elements are _____________________________________________________________, they are always in pairs. Mark them on your periodic table. o H, N, O, F, Cl, Br, I, At o These start at the element #7 9 o They form the shape of a 7 Crossing Over Method o Take down the examples!! Polyatomic Ions o Consists of ____________________________________________ like ammonium (NH4 = Nitrogen and 4 Hydrogen). See list on page 159. o Eg. NH4+ + OHNH4OH = Ammonium hydroxide o _________________________________ may be needed for polyatomic ions. o Fe3+ + OHFe(OH)3 = Iron (III) hydroxide Things to look for o If cations have ( ), the number inside the ( ) is ________________________. Not how many molecules of the element. o If anions end in -ide they are probably off the periodic table (Monoatomic) o If anion ends in -ate or -ite it is _____________________________________. o The positive piece always gets written first. o Hydrogen- it depends on where it’s at o If it is first, it is a metal – _____________________________________ o If it is second, it’s a nonmetal - ________________________________ Writing Chemical Equations ______________________________: are the chemicals that are made or produced in the reaction. ______________________________: are the chemicals that begin or go into the reaction before it takes place. Chemical reaction: when the chemicals that go into the reaction (___________________________) change and new chemicals (______________________) are formed. When we write these “skeleton equations”, we must be sure that each _____________________________________________. We will learn how to balance these equations later. Symbols in an equation o “+” tells us that 2 compounds are combining. Key words that tell us this are: _______________________________. o ----------- acts like an equal sign to separate the _____________________________________. Key words: to form, to produce, to make, synthesizes, decomposes, etc. Balancing Equations o _________________________________________ – a theory to explain the nature of all matter: all matter is made up of small particle called atoms, which can neither be created or destroyed. o _________________________________________ – in a chemical equation, the total mass of the products is always the same as the total mass of the reactants. o These 2 laws demand that the products and reactants have to have the _______________________________________. 10 o 5 sodium atoms + 5 Chlorine atoms = 10 atoms of table salt. o Chemists use symbols instead of words to describe a chemical equation. o We always start with the _____________________________ for the reaction. o After the skeleton equation you must balance the equation to satisfy the conservation of mass law and Dalton’s theory. o o We balance the equation by adding numbers (coefficients) to the ___________________________________________ in the reaction. o We have to count the number of atoms on each side of the reaction and make them all equal. We will do this for this reaction on the board. o WRITE THE EXAMPLE IN YOUR NOTES Steps to balancing equations: 1. Write a skeleton equation from the word equation. 2. ____________________________ on each side of the equation. 3. Add appropriate numbers to the front of the compound or element until the equation is balanced. NOTE: Always balance oxygen (O) second last and hydrogen (H) last. Balancing Equations Examples: (WRITE THE EXAMPLES OUT) 11 12