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Registration form Chemical Contaminants 201 CEU Training Course $150.00 48 HOUR RUSH ORDER PROCESSING FEE ADDITIONAL $50.00 Start and finish dates: _____________________________________ You will have 90 days from this date in order to complete this course List number of hours worked on assignment must match State requirement. ________ Name________________________________Signature_______________________________ I have read and understood the disclaimer notice on page 2. Digitally sign XXX Address: ______________________________________________________________ City_________________________________State_________________Zip________________ Email____________________________________ Fax (____) _______________________ Phone: Home (____) _______________________ Work (____) ___________________________ Operator ID #____________________________________Exp. Date______________ Please circle/check which certification you are applying the course CEU’s/PDH’s. Wastewater Collection____ Wastewater Treatment____ Distribution ____ Water Treatment ______ Other ____________________ Your certificate will be e-mailed to you in about two weeks. Technical Learning College TLC PO Box 3060, Chino Valley, AZ 86323 Toll Free (866) 557-1746 Fax (928) 272-0747 [email protected] If you’ve paid on the Internet, please write your Customer#_________________ Please invoice me, my PO#__________________________________________ Please pay with your credit card on our website under Bookstore or Buy Now. Or call us and provide your credit card information. We will stop mailing the certificate of completion so we need either your fax number or e-mail address. We will e-mail the certificate to you, if no e-mail address; we will fax it to you. 1 DISCLAIMER NOTICE I understand that it is my responsibility to ensure that this CEU course is either approved or accepted in my State for CEU credit. I understand State laws and rules change on a frequent basis and I believe this course is currently accepted in my State for CEU or contact hour credit, if it is not, I will not hold Technical Learning College responsible. I fully understand that this type of study program deals with dangerous, changing conditions and various laws and that I will not hold Technical Learning College, Technical Learning Consultants, Inc. (TLC) liable in any fashion for any errors, omissions, advice, suggestions or neglect contained in this CEU education training course or for any violation or injury, death, neglect, damage or loss of your license or certification caused in any fashion by this CEU education training or course material suggestion or error or my lack of submitting paperwork. It is my responsibility to call or contact TLC if I need help or assistance and double-check to ensure my registration page and assignment has been received and graded. It is my responsibility to ensure all information is correct and to abide with all rules and regulations. State Approval Listing Link, check to see if your State accepts or has pre-approved this course. Not all States are listed. Not all courses are listed. If the course is not accepted for CEU credit, we will give you the course free if you ask your State to accept it for credit. Professional Engineers; Most states will accept our courses for credit but we do not officially list the States or Agencies. Please check your State for approval. State Approval Listing URL… http://www.tlch2o.com/PDF/CEU%20State%20Approvals.pdf You can obtain a printed version of the course manual from TLC for an additional $69.95 plus shipping charges. AFFIDAVIT OF EXAM COMPLETION I affirm that I personally completed the entire text of the course. I also affirm that I completed the exam without assistance from any outside source. I understand that it is my responsibility to file or maintain my certificate of completion as required by the state or by the designation organization. Grading Information In order to maintain the integrity of our courses we do not distribute test scores, percentages or questions missed. Our exams are based upon pass/fail criteria with the benchmark for successful completion set at 70%. Once you pass the exam, your record will reflect a successful completion and a certificate will be issued to you. Rush Grading Service If you need this assignment graded and the results mailed to you within a 48-hour period, prepare to pay an additional rush service handling fee of $50.00. This fee may not cover postage costs. If you need this service, simply write RUSH on the top of your Registration Form. We will place you in the front of the grading and processing line. 2 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 Chemical Contaminants 201Answer Key Name_____________________ Phone# ___________________________ You can also type your own answer key Did you check with your State agency to ensure this course is accepted for credit? Method of Course acceptance confirmation. Please fill this section Website __ Telephone Call___ Email____ Spoke to___________________ Did you receive the approval number if Applicable? ________________ What is the approval number if Applicable? ____________________ You are responsible to ensure that TLC receives the Assignment and Registration Key. Please call us to ensure that we received it. Please circle, underline, bold or X only one correct answer 1. A B C D E F 18. A B C D E F 35. A B C D E F 2. A B C D E F 19. A B C D E F 36. A B C D E F 3. A B C D E F 20. A B C D E F 37. A B C D E F 4. A B C D E F 21. A B C D E F 38. A B C D E F 5. A B C D E F 22. A B C D E F 39. A B C D E F 6. A B C D E F 23. A B C D E F 40. A B C D E F 7. A B C D E F 24. A B C D E F 41. A B C D E F 8. A B C D E F 25. A B C D E F 42. A B C D E F 9. A B C D E F 26. A B C D E F 43. A B C D E F 10. A B C D E F 27. A B C D E F 44. A B C D E F 11. A B C D E F 28. A B C D E F 45. A B C D E F 12. A B C D E F 29. A B C D E F 46. A B C D E F 13. A B C D E F 30. A B C D E F 47. A B C D E F 14. A B C D E F 31. A B C D E F 48. A B C D E F 15. A B C D E F 32. A B C D E F 49. A B C D E F 16. A B C D E F 33. A B C D E F 50. A B C D E F 17. A B C D E F 34. A B C D E F 51. A B C D E F 3 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 52. A B C D E F 84. A B C D E F 116. A B C D E F 53. A B C D E F 85. A B C D E F 117. A B C D E F 54. A B C D E F 86. A B C D E F 118. A B C D E F 55. A B C D E F 87. A B C D E F 119. A B C D E F 56. A B C D E F 88. A B C D E F 120. A B C D E F 57. A B C D E F 89. A B C D E F 121. A B C D E F 58. A B C D E F 90. A B C D E F 122. A B C D E F 59. A B C D E F 91. A B C D E F 123. A B C D E F 60. A B C D E F 92. A B C D E F 124. A B C D E F 61. A B C D E F 93. A B C D E F 125. A B C D E F 62. A B C D E F 94. A B C D E F 126. A B C D E F 63. A B C D E F 95. A B C D E F 127. A B C D E F 64. A B C D E F 96. A B C D E F 128. A B C D E F 65. A B C D E F 97. A B C D E F 129. A B C D E F 66. A B C D E F 98. A B C D E F 130. A B C D E F 67. A B C D E F 99. A B C D E F 131. A B C D E F 68. A B C D E F 100. A B C D E F 132. A B C D E F 69. A B C D E F 101. A B C D E F 133. A B C D E F 70. A B C D E F 102. A B C D E F 134. A B C D E F 71. A B C D E F 103. A B C D E F 135. A B C D E F 72. A B C D E F 104. A B C D E F 136. A B C D E F 73. A B C D E F 105. A B C D E F 137. A B C D E F 74. A B C D E F 106. A B C D E F 138. A B C D E F 75. A B C D E F 107. A B C D E F 139. A B C D E F 76. A B C D E F 108. A B C D E F 140. A B C D E F 77. A B C D E F 109. A B C D E F 141. A B C D E F 78. A B C D E F 110. A B C D E F 142. A B C D E F 79. A B C D E F 111. A B C D E F 143. A B C D E F 80. A B C D E F 112. A B C D E F 144. A B C D E F 81. A B C D E F 113. A B C D E F 145. A B C D E F 82. A B C D E F 114. A B C D E F 146. A B C D E F 83. A B C D E F 115. A B C D E F 147. A B C D E F 4 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 148. A B C D E F 180. A B C D E F 212. A B C D E F 149. A B C D E F 181. A B C D E F 213. A B C D E F 150. A B C D E F 182. A B C D E F 214. A B C D E F 151. A B C D E F 183. A B C D E F 215. A B C D E F 152. A B C D E F 184. A B C D E F 216. A B C D E F 153. A B C D E F 185. A B C D E F 217. A B C D E F 154. A B C D E F 186. A B C D E F 218. A B C D E F 155. A B C D E F 187. A B C D E F 219. A B C D E F 156. A B C D E F 188. A B C D E F 220. A B C D E F 157. A B C D E F 189. A B C D E F 221. A B C D E F 158. A B C D E F 190. A B C D E F 222. A B C D E F 159. A B C D E F 191. A B C D E F 223. A B C D E F 160. A B C D E F 192. A B C D E F 224. A B C D E F 161. A B C D E F 193. A B C D E F 225. A B C D E F 162. A B C D E F 194. A B C D E F 226. A B C D E F 163. A B C D E F 195. A B C D E F 227. A B C D E F 164. A B C D E F 196. A B C D E F 228. A B C D E F 165. A B C D E F 197. A B C D E F 229. A B C D E F 166. A B C D E F 198. A B C D E F 230. A B C D E F 167. A B C D E F 199. A B C D E F 231. A B C D E F 168. A B C D E F 200. A B C D E F 232. A B C D E F 169. A B C D E F 201. A B C D E F 233. A B C D E F 170. A B C D E F 202. A B C D E F 234. A B C D E F 171. A B C D E F 203. A B C D E F 235. A B C D E F 172. A B C D E F 204. A B C D E F 236. A B C D E F 173. A B C D E F 205. A B C D E F 237. A B C D E F 174. A B C D E F 206. A B C D E F 238. A B C D E F 175. A B C D E F 207. A B C D E F 239. A B C D E F 176. A B C D E F 208. A B C D E F 240. A B C D E F 177. A B C D E F 209. A B C D E F 241. A B C D E F 178. A B C D E F 210. A B C D E F 242. A B C D E F 179. A B C D E F 211. A B C D E F 243. A B C D E F 5 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 244. A B C D E F 276. A B C D E F 308. A B C D E F 245. A B C D E F 277. A B C D E F 309. A B C D E F 246. A B C D E F 278. A B C D E F 310. A B C D E F 247. A B C D E F 279. A B C D E F 311. A B C D E F 248. A B C D E F 280. A B C D E F 312. A B C D E F 249. A B C D E F 281. A B C D E F 313. A B C D E F 250. A B C D E F 282. A B C D E F 314. A B C D E F 251. A B C D E F 283. A B C D E F 315. A B C D E F 252. A B C D E F 284. A B C D E F 316. A B C D E F 253. A B C D E F 285. A B C D E F 317. A B C D E F 254. A B C D E F 286. A B C D E F 318. A B C D E F 255. A B C D E F 287. A B C D E F 319. A B C D E F 256. A B C D E F 288. A B C D E F 320. A B C D E F 257. A B C D E F 289. A B C D E F 321. A B C D E F 258. A B C D E F 290. A B C D E F 322. A B C D E F 259. A B C D E F 291. A B C D E F 323. A B C D E F 260. A B C D E F 292. A B C D E F 324. A B C D E F 261. A B C D E F 293. A B C D E F 325. A B C D E F 262. A B C D E F 294. A B C D E F 326. A B C D E F 263. A B C D E F 295. A B C D E F 327. A B C D E F 264. A B C D E F 296. A B C D E F 328. A B C D E F 265. A B C D E F 297. A B C D E F 329. A B C D E F 266. A B C D E F 298. A B C D E F 330. A B C D E F 267. A B C D E F 299. A B C D E F 331. A B C D E F 268. A B C D E F 300. A B C D E F 332. A B C D E F 269. A B C D E F 301. A B C D E F 333. A B C D E F 270. A B C D E F 302. A B C D E F 334. A B C D E F 271. A B C D E F 303. A B C D E F 335. A B C D E F 272. A B C D E F 304. A B C D E F 336. A B C D E F 273. A B C D E F 305. A B C D E F 337. A B C D E F 274. A B C D E F 306. A B C D E F 338. A B C D E F 275. A B C D E F 307. A B C D E F 339. A B C D E F 6 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 340. A B C D E F 361. A B C D E F 382. A B C D E F 341. A B C D E F 362. A B C D E F 383. A B C D E F 342. A B C D E F 363. A B C D E F 384. A B C D E F 343. A B C D E F 364. A B C D E F 385. A B C D E F 344. A B C D E F 365. A B C D E F 386. A B C D E F 345. A B C D E F 366. A B C D E F 387. A B C D E F 346. A B C D E F 367. A B C D E F 388. A B C D E F 347. A B C D E F 368. A B C D E F 389. A B C D E F 348. A B C D E F 369. A B C D E F 390. A B C D E F 349. A B C D E F 370. A B C D E F 391. A B C D E F 350. A B C D E F 371. A B C D E F 392. A B C D E F 351. A B C D E F 372. A B C D E F 393. A B C D E F 352. A B C D E F 373. A B C D E F 394. A B C D E F 353. A B C D E F 374. A B C D E F 395. A B C D E F 354. A B C D E F 375. A B C D E F 396. A B C D E F 355. A B C D E F 376. A B C D E F 397. A B C D E F 356. A B C D E F 377. A B C D E F 398. A B C D E F 357. A B C D E F 378. A B C D E F 399. A B C D E F 358. A B C D E F 379. A B C D E F 400. A B C D E F 359. A B C D E F 380. A B C D E F 360. A B C D E F 381. A B C D E F This course contains general EPA’s SDWA federal rule requirements. Please be aware that each state implements water / sampling procedures/safety/ environmental / building regulations that may be more stringent than EPA’s regulations. Check with your state environmental/health agency for more information. These rules change frequently and are often difficult to interpret and follow. Be careful to not be in non-compliance and do not follow this course for proper compliance. Please fax the answer key to TLC (928) 272-0747 7 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 8 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 CHEMICAL CONTAMINANTS 201 CEU TRAINING COURSE CUSTOMER SERVICE RESPONSE CARD NAME: __________________________ E-MAIL _________________________________ PHONE _____________________ PLEASE COMPLETE THIS FORM BY CIRCLING THE NUMBER OF THE APPROPRIATE ANSWER IN THE AREA BELOW. 1. Please rate the difficulty of your course. Very Easy 0 1 2 3 4 2. Please rate the difficulty of the testing process. Very Easy 0 1 2 3 4 5 Very Difficult 5 Very Difficult 3. Please rate the subject matter on the exam to your actual field or work. Very Similar 0 1 2 3 4 5 Very Different 4. How did you hear about this Course? _______________________________ 5. What would you do to improve the Course? ________________________________________________________________ How about the price of the course? Poor_____ Fair ____ Average ____ Good____ Great_____ How was your customer service? Poor___ Fair ____ Average ____ Good _____ Great_____ Any other concerns or comments. 9 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 10 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 Chemical Contaminants 201 CEU Training Course Assignment You will have 90 days from the start of this assignment to successfully complete it with a score of 70%. If you should need any assistance, please call or e-mail the Student Service Department, please fax or e-mail all concerns and the final test to TLC. You are expected to circle the correct answer on the enclosed answer key. Please include your name and address on your exam. The answer key is in the front. There are no intentional trick questions. You can e-mail or fax your Answer Key along with the Registration Form to TLC. Inorganic Chemical Introduction What are Inorganic Compounds? 1. Inorganic compounds are of inanimate, not biological origin. Inorganic compounds lack carbon and hydrogen atoms and are synthesized by the agency of geological systems. In contrast, the synthesis of __________________ in biological systems incorporates carbohydrates into the molecular structure. A. Volatile Organic Compounds (VOCs) D. Maximum Contaminant Levels (MCL) B. Synthetic Organic Chemicals (SOCs) E. Organic compounds C. Polychlorinated Biphenyls (PCBs) F. None of the Above 2. Organic chemists traditionally refer to any molecule containing carbon as an organic compound and by default this means that ___________________deals with molecules lacking carbon. However, biologists may distinguish organic from inorganic compounds in a different way that does not hinge on the presence of a carbon atom. A. Presence of a carbon atom D. Inorganic compounds B. Atmospheric CO2 E. Carbon C. Inorganic chemistry F. None of the Above 3. Pools of_____________, for example, that have been metabolically incorporated into living tissues persist in decomposing tissues, but as molecules become oxidized into the open environment, such as atmospheric CO2, this creates a separate pool of inorganic compounds. A. Volatile Organic Compounds (VOCs) D. Organic matter B. Synthetic Organic Chemicals (SOCs) E. Organic compounds C. Polychlorinated Biphenyls (PCBs) F. None of the Above 4. The distinction between inorganic and organic compounds is not always clear when dealing with open and closed systems, because everything is ultimately connected to everything else on the planet. Some scientists, for example, view the open environment (i.e., the ecosphere) as an extension of life and from this perspective may consider atmospheric CO 2 as_____________. IUPAC, an agency widely recognized for defining chemical terms, does not offer definitions of inorganic or organic. A. Presence of a carbon atom D. Inorganic compounds B. An organic compound E. Carbon C. Typical examples F. None of the Above 5. ______________ are rather simple chemicals present in ground water. These chemicals are generally described as mineral in nature and usually exist as ions (chemical substances with a positive or negative charge) when dissolved in water. A. Volatile Organic Compounds (VOCs) D. Maximum Contaminant Levels (MCL) B. Synthetic Organic Chemicals (SOCs) E. Organic compounds C. Polychlorinated Biphenyls (PCBs) F. None of the Above 11 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 6. Typical examples include sodium, iron, calcium, magnesium, manganese, nitrate, chloride, sulfate, and zinc. Many of these chemicals are naturally occurring _______________that are dissolved from the rock/soil which make up the aquifer or water-bearing rock formations below the soil surface. A. Presence of a carbon atom D. Inorganic compounds B. Atmospheric CO2 E. Minerals C. Typical examples F. None of the Above 7. However, some of these ______________ may be introduced into ground water by human activities. A. Volatile Organic Compounds (VOCs) D. Maximum Contaminant Levels (MCL) B. Synthetic Organic Chemicals (SOCs) E. Compounds C. Polychlorinated Biphenyls (PCBs) F. None of the Above 8. Nitrate (an agricultural fertilizer) and sodium chloride (road salt) are two examples. Water purveyors need to test for 30 different ________________ including all arsenic, barium, cadmium, lead, mercury, selenium, and thallium A. Presence of a carbon atom D. Inorganic compounds B. Atmospheric CO2 E. Carbon C. Typical examples F. None of the Above 9. _____________________ - these are once living, or are living and can bring life to cells. These contain carbon, and their electrons spin clockwise, just like those of the human body. Additionally, these cells can form an ionic bond with the body and can easily break down into materials to help with bodily function, such as tissue repair. A. Volatile Organic Compounds (VOCs) D. Maximum Contaminant Levels (MCL) B. Synthetic Organic Chemicals (SOCs) E. Organic compounds C. Polychlorinated Biphenyls (PCBs) F. None of the Above 10. ___________________- these were never living, without carbon and cannot bring life to cells. The body treats these metals like toxins and are tightly held together; they cannot be easily broken down. And, their electrons spin counterclockwise, out of sync with the rest of the body. A. Presence of a carbon atom D. Inorganic compounds B. Atmospheric CO2 E. Carbon C. Typical examples F. None of the Above SOC Section SOC Introduction 11. Synthetic Organic Chemicals (SOCs) are organic (carbon based) chemicals that are less volatile than ______________________. A. Volatile Organic Compounds (VOCs) D. Maximum Contaminant Levels (MCL) B. Synthetic Organic Chemicals (SOCs) E. Organic compounds C. Polychlorinated Biphenyls (PCBs) F. None of the Above 12. ______________________ are used as pesticides, defoliants, fuel additives and as ingredients for other organic compounds. They are all man made and do not naturally occur in the environment. A. Volatile Organic Compounds (VOCs) D. Maximum Contaminant Levels (MCL) B. Synthetic Organic Chemicals (SOCs) E. Organic compounds C. Polychlorinated Biphenyls (PCBs) F. None of the Above 13. Some of the more well-known SOCs are Atrazine, 2,4-D, Dioxin and _________________. A. Volatile Organic Compounds (VOCs) D. Maximum Contaminant Levels (MCL) B. Synthetic Organic Chemicals (SOCs) E. Organic compounds C. Polychlorinated Biphenyls (PCBs) F. None of the Above 12 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 14. SOCs most often enter the natural environment through application of pesticide (including runoff from areas where they are applied), as part of a legally discharged waste stream, improper or illegal waste disposal, accidental releases or as a byproduct of incineration. Some _____________ are very persistent in the environment, whether in soil or water. A. Volatile Organic Compounds (VOCs) D. Maximum Contaminant Levels (MCL) B. Synthetic Organic Chemicals (SOCs) E. Organic compounds C. Polychlorinated Biphenyls (PCBs) F. None of the Above 15. SOCs are generally toxic and can have substantial health impacts from both acute (short-term) and chronic (long-term) exposure. Many are known carcinogens (cancer causing). EPA has set Maximum Contaminant Levels (MCL) for 30 ______________ under the Safe Drinking Water Act. A. Volatile Organic Compounds (VOCs) D. Maximum Contaminant Levels (MCL) B. Synthetic Organic Chemicals (SOCs) E. Organic compounds C. Polychlorinated Biphenyls (PCBs) F. None of the Above 16. The Safe Drinking Water Act requires that all water sources of all public water systems be periodically monitored for regulated ______________________. The monitoring frequency can be adjusted through a waiver if SOCs are not detected. A. Volatile Organic Compounds (VOCs) D. Maximum Contaminant Levels (MCL) B. Synthetic Organic Chemicals (SOCs) E. Organic compounds C. Polychlorinated Biphenyls (PCBs) F. None of the Above 17. EPA established Maximum Contaminant Levels (MCL), _______________, monitoring requirements and best available technologies for removal for 65 chemical contaminants over a five year period as EPA gathered and analyzed occurrence and health effects data. A. Volatile Organic Compounds (VOCs) D. Maximum Contaminant Level Goals (MCLG) B. Synthetic Organic Chemicals (SOCs) E. Organic compounds C. Polychlorinated Biphenyls (PCBs) F. None of the Above 18. This series of rules are known as _______________and they define regulations for three contaminant groups: Inorganic Chemicals (IOC), Synthetic Organic Chemicals (SOC), and Volatile Organic Chemicals (VOC). A. Organic chemical rules D. The Chemical Phase Rules B. EPA contaminants E. Chemical compounds C. Three contaminant groups F. None of the Above 19. The Chemical Phase rules provide public health protection through the reduction of chronic risks from: _________________________________. A. Specific Treatment Techniques (TT) D. Benzene B. Aqueous solvents E. Methylene chloride C. VOCs F. None of the Above 20. They also help to reduce the occurrence of ____________________or "blue baby syndrome" from ingestion of elevated levels of nitrate or nitrite. A. Methemoglobinemia D. Elevated levels of nitrate or nitrite B. Most contaminants E. Chemical compounds C. Three contaminant groups F. None of the Above 21. All public water systems must monitor for__________________. Community water systems and Non-transient non-community water systems must also monitor for IOCs, SOCs, and VOCs. A. Volatile Organic Compounds (VOCs) D. Maximum Contaminant Levels (MCL) B. Synthetic Organic Chemicals (SOCs) E. Nitrate and Nitrite C. Polychlorinated Biphenyls (PCBs) F. None of the Above 13 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 22. This is a list of the organic chemicals—which include pesticides, industrial chemicals, and disinfection by-products—that are tested for in public water systems (those that provide water to the public), along with the_____________________, and a brief description of the potential health effects associated with long-term consumption of elevated levels of the contaminants. A. 60 organic chemicals D. Elevated levels of nitrate or nitrite B. Most contaminants E. Chemical compounds C. Maximum standard for the contaminant F. None of the Above 23. The federal standard for _____________ is listed as a Maximum Contaminant Level (MCL), the lowest concentration at which that particular contaminant is believed to represent a potential health concern. Unless otherwise noted, the MCL is expressed as parts per billion (ppb). A. Some organic chemicals D. Elevated levels of nitrate or nitrite B. Most contaminants E. Chemical compounds C. All contaminant groups F. None of the Above 24. Because of technological limitations or other factors, it is not possible to test for some contaminants in a reliable fashion. Instead, public water systems are required to use specific Treatment Techniques (TT) that are designed to remove these _______________from the water. A. Particular contaminants D. Benzene B. Aqueous solvents E. Methylene chloride C. VOCs F. None of the Above 25. In addition to the chemicals listed, monitoring is done for approximately 60 organic chemicals for which MCLs have not been established. If unacceptable levels are found of these________________—based on established state health standards and an assessment of the risks they pose—the response is the same as if an MCL has been exceeded: the public water system must notify those served by the system. A. 60 organic chemicals D. Elevated levels of nitrate or nitrite B. “Unregulated” contaminants E. Chemical compounds C. Three contaminant groups F. None of the Above Volatile Organic Compounds (VOCs) VOCs Explained 26. ___________________ are organic chemicals that have a high vapor pressure at ordinary, room-temperature conditions. Their high vapor pressure results from a low boiling point, which causes large numbers of molecules to evaporate or sublimate from the liquid or solid form of the compound and enter the surrounding air. An example is formaldehyde, with a boiling point of –19 °C (–2 °F), slowly exiting paint and getting into the air. A. Volatile Organic Compounds (VOCs) D. Maximum Contaminant Levels (MCL) B. Synthetic Organic Chemicals (SOCs) E. Organic compounds C. Polychlorinated Biphenyls (PCBs) F. None of the Above 27. VOCs are numerous, varied, and ubiquitous. They include both human-made and naturally occurring chemical compounds. _______________are of VOCs. VOCs play an important role in communication between plants. A. 60 organic chemicals D. Elevated odors B. Most scents or odors E. Chemical compounds C. Three contaminant groups F. None of the Above 14 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 28. Some VOCs are dangerous to human health or cause harm to the environment. _____________ are regulated by law, especially indoors, where concentrations are the highest. A. Anthropogenic VOCs D. Benzene B. Aqueous solvents E. Methylene chloride C. VOCs F. None of the Above 29. _________________are typically not acutely toxic, but instead have compounding long-term health effects. Because the concentrations are usually low and the symptoms slow to develop, research into VOCs and their effects is difficult. A. 60 organic chemicals D. Elevated levels of nitrate or nitrite B. Most contaminants E. Chemical compounds C. Three contaminant groups F. None of the Above Specific Components Paints and Coatings 30. A major source of man-made VOCs are coatings, especially paints and protective coatings. _______________are required to spread a protective or decorative film. Approximately 12 billion liters of paints are produced annually. A. Solvents D. Cleaning products B. VOC E. Carbon monoxide C. Benzene F. None of the Above 31. __________________are aliphatic hydrocarbons, ethyl acetate, glycol ethers, and acetone. Motivated by cost, environmental concerns, and regulation, the paint and coating industries are increasingly shifting toward aqueous solvents. A. Typical solvents D. Benzene B. Aqueous solvents E. Methylene chloride C. VOCs F. None of the Above Chlorofluorocarbons and Chlorocarbons 32. __________________, which are banned or highly regulated, were widely used cleaning products and refrigerants. A. Solvents D. Cleaning products B. VOC E. Carbon monoxide C. Benzene F. None of the Above 33. _________________is used widely in dry cleaning and by industry. Industrial use of fossil fuels produces VOCs either directly as products (e.g., gasoline) or indirectly as byproducts (e.g., automobile exhaust). A. Tetrachloroethene D. Benzene B. Aqueous solvents E. Methylene chloride C. VOCs F. None of the Above Benzene 34. One VOC that is a known human carcinogen is __________________, which is a chemical found in environmental tobacco smoke, stored fuels, and exhaust from cars in an attached garage. A. Solvents D. Cleaning products B. VOC E. Carbon monoxide C. Benzene F. None of the Above 15 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 35. _______________ also has natural sources such as volcanoes and forest fires. It is frequently used to make other chemicals in the production of plastics, resins, and synthetic fibers. A. Specific Treatment Techniques (TT) D. Benzene B. Aqueous solvents E. Methylene chloride C. VOCs F. None of the Above 36. _________________ evaporates into the air quickly and the vapor of benzene is heavier than air allowing the compound to sink into low-lying areas. A. Solvents D. Cleaning products B. VOC E. Carbon monoxide C. Benzene F. None of the Above 37. _______________ has also been known to contaminate food and water and if digested can lead to vomiting, dizziness, sleepiness, rapid heartbeat, and at high levels, even death may occur. A. Mother-in-law D. Benzene B. Aqueous solvents E. Methylene chloride C. VOCs F. None of the Above Methylene Chloride 38. Methylene chloride is another VOC that is highly dangerous to human health. It can be found in adhesive removers and aerosol spray paints and the chemical has been proven to cause cancer in animals. In the human body, ___________________is converted to carbon monoxide and a person will suffer the same symptoms as exposure to carbon monoxide. A. Solvent D. Methylene chloride B. VOC E. Carbon monoxide C. Benzene F. None of the Above 39. If a product that contains _____________needs to be used the best way to protect human health is to use the product outdoors. If it must be used indoors, proper ventilation is essential to keeping exposure levels down. A. Methylene chloride D. Benzene B. Aqueous solvents E. Methylene chlorite C. VOCs F. None of the Above Perchloroethylene 40. Perchloroethylene is a ___________that has been linked to causing cancer in animals. It is also suspected to cause many of the breathing related symptoms of exposure to VOC’s. A. Volatile organic compound D. Cancer causer B. Organic chemical E. Chemical C. SOC F. None of the Above 41. Perchloroethylene is used mostly in dry cleaning. Studies show that people breathe in low levels of this ______________ in homes where dry-cleaned clothes are stored and while wearing drycleaned clothing. While dry cleaners attempt to recapture perchlorothylene in the dry cleaning process to reuse it in an effort to save money, they can’t recapture it all. A. Formaldehyde D. Perchloroethylene B. MTBE E. Organic chemicals C. VOC F. None of the Above 42. To avoid exposure to perchlorothylene, if a _______________is coming from clothing when picked up from the dry cleaner, do not accept them and request that less of the chemical be used as well as a complete drying of the garments A. Perchloroethylene D. Strong chemical odor B. Organic chemical E. Furry creature C. VOC F. None of the Above 16 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 MTBE 43. MTBE was banned in the US around 2004 in order to limit further contamination of drinking water aquifers primarily from leaking underground gasoline storage tanks where MTBE was used as an octane booster and______________________. A. Formaldehyde D. Oxygenated-additive B. MTBE E. Organic chemicals C. VOCs F. None of the Above Formaldehyde 44. Many building materials such as paints, adhesives, wall boards, and ceiling tiles slowly emit____________________, which irritates the mucous membranes and can make a person irritated and uncomfortable. A. Perchloroethylene D. Sounds B. Organic chemicals E. Formaldehyde C. VOCs F. None of the Above 45. Formaldehyde emissions from wood are in the range of 0.02 – 0.04 ppm. Relative humidity within an indoor environment can also affect the emissions of formaldehyde. High relative humidity and high temperatures allow more vaporization of ________________________ from wood-materials. A. Formaldehyde D. Perchloroethylene B. MTBE E. Organic chemicals C. VOCs F. None of the Above Health Risks 46. Respiratory, allergic, or immune effects in infants or children are associated with man-made _____________ and other indoor or outdoor air pollutants. A. Perchloroethylene D. Cancer B. Organic chemicals E. An unhealthy place to breathe C. VOCs F. None of the Above 47. Some VOCs, such as styrene and limonene, can react with nitrogen oxides or with ozone to produce new oxidation products and secondary aerosols, which can cause sensory irritation symptoms. Unspecified ____________ are important in the creation of smog. A. Formaldehyde D. Perchloroethylene B. MTBE E. Organic chemicals C. VOCs F. None of the Above Health effects include: 48. Eye, nose, and throat irritation; headaches, loss of coordination, nausea; damage to liver, kidney, and central nervous system. _______________can cause cancer in animals; some are suspected or known to cause cancer in humans. A. Perchloroethylene D. Some organics B. Organic chemicals E. Water C. VOCs F. None of the Above 49. Key signs or symptoms associated with exposure to _______________ include conjunctival irritation, nose and throat discomfort, headache, allergic skin reaction, dyspnea, declines in serum cholinesterase levels, nausea, emesis, epistaxis, fatigue, dizziness. A. Formaldehyde D. Perchloroethylene B. MTBE E. Organic chemicals C. VOCs F. None of the Above 17 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 50. The ability of _______________ to cause health effects varies greatly from those that are highly toxic, to those with no known health effects. As with other pollutants, the extent and nature of the health effect will depend on many factors including level of exposure and length of time exposed. A. Perchloroethylene D. Cancer B. Organic chemicals E. An unhealthy place C. VOCs F. None of the Above 51. Eye and respiratory tract irritation, headaches, dizziness, visual disorders, and memory impairment are among the immediate symptoms that some people have experienced soon after exposure to ________________________. A. Formaldehyde D. Perchloroethylene B. MTBE E. Organic chemicals C. VOCs F. None of the Above 52. At present, not much is known about what health effects occur from the levels of organics usually found in homes. __________________are known to cause cancer in animals; some are suspected of causing, or are known to cause, cancer in humans. A. Perchloroethylene D. Many organic compounds B. Organic chemicals E. Unhealthy restaurants C. VOCs F. None of the Above Reducing Exposure 53. To reduce exposure to these toxins, one should buy products that contain Low-VOC’s or No VOC’s. Only the quantity which will soon be needed should be purchased, eliminating stockpiling of these chemicals. Use products with ____________ in well ventilated areas. A. Formaldehyde D. Perchloroethylene B. MTBE E. Organic chemicals C. VOCs F. None of the Above 54. When designing homes and buildings, design teams can implement the best possible ventilation plans, call for ____________________, and design assemblies to reduce the amount of infiltration into the building. These methods will help improve indoor air quality, but by themselves they cannot keep a building from becoming an unhealthy place to breathe. While proper building ventilation is a key component to improving indoor air quality, it cannot do the job on its own. A. Perchloroethylene D. Cancer detection B. Organic chemicals E. An unhealthy place to breathe C. VOCs F. None of the Above 55. As stated earlier, awareness is the key component to improving air quality, when choosing building materials, furnishings, and decorations. When architects and engineers implement best practices in ventilation and mechanical systems, the owner must maintain good _______________ thereafter. A. Perchloroethylene free homes D. Dinner parties B. Organic chemicals free homes E. Relationships C. VOCs free clothes F. None of the Above Allotropes Section 56. Allotropy or allotropism is the property of _______________to exist in two or more different forms, known as allotropes of these elements. A. Allotropy D. Some chemical elements B. Allotropes E. Metalloids C. Molecular formulae F. None of the Above 18 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 57. _________________ are different structural modifications of an element; the atoms of the element are bonded together in a different manner. A. Allotropy D. Some elements B. Allotropes E. Metalloids C. Molecular formulae F. None of the Above 58. The term allotropy is used for elements only, not for compounds. The more general term, used for any crystalline material, is_____________________. A. Allotropy D. Polymorphism B. Allotrope E. Metalloid C. Molecular formulae F. None of the Above 59. ________________ refers only to different forms of an element within the same phase (i.e. different solid, liquid or gas forms); the changes of state between solid, liquid and gas in themselves are not considered allotropy. A. Allotropy D. Element B. Allotrope E. Metalloid C. Molecular formulae F. None of the Above 60. For some elements, _____________________ have different molecular formulae which can persist in different phases – for example, two allotropes of oxygen (dioxygen, O 2 and ozone, O3), can both exist in the solid, liquid and gaseous states. A. Allotropy D. Some elements B. Allotropes E. Metalloids C. Molecular formulae F. None of the Above 61. Conversely, some elements do not maintain distinct allotropes in different phases – for example phosphorus has numerous_______________, which all revert to the same P4 form when melted to the liquid state. A. Allotropy D. Solid allotropes B. Allotropes E. Metalloids C. Molecular formulae F. None of the Above List of Allotropes 62. Typically, _____________capable of variable coordination number and/or oxidation states tend to exhibit greater numbers of allotropic forms. Another contributing factor is the ability of an element to catenate. A. Allotropy D. Elements B. Allotropes E. Metalloids C. Molecular formulae F. None of the Above 63. __________________ are typically more noticeable in non-metals (excluding the halogens and the noble gases) and metalloids. Nevertheless, metals tend to have many allotropes. A. Allotropy D. Some elements B. Allotropes E. Metalloids C. Molecular formulae F. None of the Above Small Water Filters 64. Water filters generally come in two forms. Portable ion exchange water filters, and reverse osmosis water filters. Both are used for "________________________" drinking water, that is, to filter out harmful or unwanted particles before the water is used for human consumption. A. A carbon filter D. Man-made filter B. Backwash carbon E. Point of use C. Activated carbon F. None of the Above 19 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 65. Reverse Osmosis works by forcing the water through a ________________that stops certain particles from passing through. A. Semi-permeable membrane D. Recommend treatment B. Activated carbon E. Carbon filter or system C. Process F. None of the Above 66. Portable water filters work using a cartridge containing activated carbon and_________________. The carbon absorbs and helps reduce the levels of chlorine and chlorine compounds, as well as pesticides, color and other organic substances. This improves taste and appearance. The ion exchange resin works to reduce temporary hardness. A. A carbon filter D. Ion exchange resin B. Backwash carbon E. Organic matter C. Activated carbon F. None of the Above Activated Carbon Filtration 67. __________________ has been used for many years to solve water problems. In the beginning, its use was more art than science. Today, however, we understand more about what activated carbon can remove and how it removes impurities. A. Reverse Osmosis D. Money B. Activated carbon E. Government C. The adsorption process F. None of the Above 68. _______________________quickly and effectively removes chlorine from water. A. A carbon filter D. Man-made organics B. Robots E. Organic matter C. Activated carbon F. None of the Above 69. The presence of organic matter in water can cause color, taste, and odor complaints. Activated carbon adsorbs organic matter in its extensive network of pores. ____________________ takes time, so service rates should be limited to 5 gpm/ft (12m/hr) or less for these applications. A. Reverse Osmosis D. Sand filter B. Activated carbon E. A carbon filter or system C. The adsorption process F. None of the Above Synthetic Organic Chemicals 70. Synthetic organic chemicals (SOC) include all __________________, some of which are volatile organic compounds (VOC). A. Carbon based units D. Man-made organics B. Carbon atoms E. Organic matter C. Re-activated carbon F. None of the Above 71. ___________________ can substantially reduce many VOCs such as benzene, trichlorethane and carbon tetrachloride. A. Reverse Osmosis D. Fire B. Activated carbon E. A carbon filter or system C. The adsorption process F. None of the Above 72. __________________ also removes SOCs such as Alachlor, EDB and toluene. The EPA is establishing limits for these chemicals in public drinking water supplies. A. A carbon filter D. Man-made machines B. Backwash carbon E. Organic filters C. Activated carbon F. None of the Above 20 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 73. Before recommending_______________, water suspected of containing any of these and other substances must be analyzed to determine their concentrations and whether they exceed the EPA standards. A. Reverse Osmosis D. Treatment B. Activated carbon E. A carbon filter or system C. The adsorption process F. None of the Above 74. _____________________compact with use so they may need occasional backwashing, however, backwash carbon as little as possible to prevent loss of the fragile material. Also, contaminant-laden carbon may migrate toward the bottom of the bed during backwash and reduce filter performance. A. A carbon filter D. MF B. Backwash carbon E. Activated carbon beds C. Activated carbon F. None of the Above 75. When operating ______________________ on turbid water supplies, remove suspended particles with a depth filter before treating it with activated carbon. A. Reverse Osmosis process D. A boat B. Activated carbon filters E. A carbon filter or system C. The adsorption process F. None of the Above 76. __________________typically backwashes at 10 gpm/ft (25 m/hr) for about 10 minutes, followed by a 5 minute downflow rinse. A. A carbon filter D. Man B. Backwash carbon filter E. Organic matter filtering C. Activated carbon process F. None of the Above 77. Over a period of several months to two years, the carbon's adsorption capacity diminishes. The exhausted _______________________should be replaced with fresh carbon. The old carbon should be hauled to an approved disposal facility. A. Reverse Osmosis D. Carbon bed B. Activated carbon E. A carbon filter or system C. Adsorption process F. None of the Above Membrane Filtration Processes 78. In 1748, the French physicist Nollet first noted that water would diffuse through a pig bladder membrane into alcohol. This was the discovery of__________________, a process in which water from a dilute solution will naturally pass through a porous membrane into a concentrate solution. A. Reverse osmosis D. RO membranes B. A porous membrane E. Osmosis C. Potable water F. None of the Above 79. Over the years, scientists have attempted to develop membranes that would be useful in industrial processes, but it wasn’t until the late 1950s that membranes were produced that could be used for what is known as ______________________. A. Direct filtration process D. Membrane filtration processes B. MF E. Reverse osmosis C. Desalinization F. None of the Above 80. In __________________, water is forced to move through a membrane from a concentrate solution to a dilute solution. A. Reverse osmosis D. RO membranes B. A porous membrane E. Rapid sand filters C. Potable water F. None of the Above 21 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 81. Since that time, continual improvements and new developments have been made in ________________, resulting in ever-increasing uses in many industries. In potable water treatment, membranes have been used for desalinization, removal of dissolved inorganic and organic chemicals, water softening, and removal of the fine solids. A. Direct filtration process D. Membrane filtration processes B. MF E. Reverse osmosis C. Desalinization F. None of the Above 82. In particular, ____________________ enables some water systems having contaminated water sources to meet new, more stringent regulations. In some cases, it can also allow secondary sources, such as brackish groundwater, to be used. A. Reverse osmosis D. RO membranes B. A porous membrane E. Rapid sand filters C. Potable water F. None of the Above 83. There is great potential for the continuing wide use of __________________ in potable water treatment, especially as technology improves and costs are reduced. A. Direct filtration process D. Membrane filtration processes B. MF E. Reverse osmosis C. Desalinization F. None of the Above Microfiltration 84. Microfiltration (MF) is a process in which water is forced under pressure through _________________________. A. Reverse osmosis D. RO membranes B. A porous membrane E. Rapid sand filters C. Potable water F. None of the Above 85. with the other _______________________. A. Direct filtration process D. Membrane filtration processes B. MF E. Reverse osmosis C. Desalinization F. None of the Above 86. This process has not been generally applicable to drinking water treatment because it either does not remove substances that require removal from potable water, or the problem substances can be removed more economically using___________________________. A. Reverse osmosis D. RO membranes B. A porous membrane E. Rapid sand filters C. Other processes F. None of the Above 87. The current primary use of _______________ is by industries to remove very fine particles from process water, such as in electronic manufacturing. In addition, the process has also been used as a pretreatment for other membrane processes. A. Direct filtration process D. Membrane filtration processes B. MF E. Reverse osmosis C. Desalinization F. None of the Above 88. In particular, _____________________ are susceptible to clogging or filter binding unless the water being processed is already quite clean. A. Reverse osmosis filters D. RO membranes B. Porous membranes E. Rapid sand filters C. Probable water filters F. None of the Above 22 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 89. However, in recent years, microfiltration has been proposed as a filtering method for particles resulting from the______________________. A. Direct filtration process D. Membrane filtration processes B. MF E. Reverse osmosis C. Desalinization F. None of the Above 90. Traditionally, this _______________ has used the injection of coagulants such as alum or polymers into the raw water stream to remove turbidity such as clay or silts. A. Direct filtration process D. Membrane filtration processes B. MF E. Reverse osmosis C. Desalinization F. None of the Above 91. The formed particles were then removed by ________________. The use of filter aids to improve filtering efficiency, especially for small particles that could contain bacterial and protozoan life are recommended. A. Reverse osmosis D. RO membranes B. A porous membrane E. Rapid sand filters C. Portable water filter F. None of the Above Ultrafiltration 92. ________________ A. EDR D. NF B. RO E. XF C. ED F. None of the Above 93. The smaller pore size is designed to remove colloids and substances that have larger molecules, which are called high-molecular-weight materials. __________________can be designed to pass material that weigh less than or equal to a certain molecular weight. This weight is called the molecular weight cutoff (MWC) of the membrane. A. Demineralizing compartments D. Direct electric current applied to the solution B. UF E. Membrane process C. Processes for this service F. None of the Above 94. Although ______________ does not generally work well for removal of salt or dissolved solids, it can be used effectively for removal or most organic chemicals. A. Electrodialysis Reversal (EDR) D. NF B. An important RO process E. UF C. These RO membranes F. None of the Above Nanofiltration 95. Nanofiltration (NF) is a process using membranes that will reject even smaller molecules than ___________. A. DO D. ET B. UF E. Membrane process C. UFO F. None of the Above 96. The process has been used primarily for water softening and reduction of total dissolved solids (TDS). NF operates with less pressure that reverse osmosis and is still able to remove a significant proportion of inorganic and organic molecules. This capability will undoubtedly increase the use of _________________ for potable water treatment. A. EDR D. NF B. RO process E. UF C. These RO membranes F. None of the Above 23 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 Reverse Osmosis 97. Reverse Osmosis (RO) is a membrane process that has the highest rejection capability of all the ______________________. A. Demineralizing compartments D. Machines B. UF E. Membrane processes C. Processes for this service F. None of the Above 98. _________________ have very low MWC pore size that can reject ions at very high rates, including chloride and sodium. A. Electrodialysis Reversal (EDR) mebranes D. NF B. RO process E. UF C. These RO membranes F. None of the Above 99. Water from this _____________________ is very pure due to the high reject rates. The process has been used primarily in the water industry for desalinization of seawater because the capital and operating costs are competitive with other processes for this service. A. Demineralizing process D. Device B. UF E. System C. Service F. None of the Above 100. The RO also works most organic chemicals, and radionuclides and microorganisms. Industrial water uses such as semiconductor manufacturing is also an important ________________. A. Purpose D. Function B. RO process E. UF C. RO membranes F. None of the Above Electrodialysis 101. Electrodialysis (ED) is a process in which ions are transferred through ______________as a result of direct electric current applied to the solution. The current carries the ions through a membrane from the less concentrated solution to the more concentrated one. A. Demineralizing compartments D. The solution B. A membrane E. Membrane process C. Processes for this service F. None of the Above Electrodialysis Reversal 102. Electrodialysis Reversal (EDR) is a process similar to_______________, except that the polarity of the direct current is periodically reversed. A. ED D. NF B. An important RO process E. UF C. RO membranes F. None of the Above 103. The reversal in polarity reverses the flow of ions _____________compartments, which provides automatic flushing of scale-forming materials from the membrane surface. A. Between demineralizing D. Direct electric current applied to the solution B. In the UF E. Make ice cream in the big C. In the processing F. None of the Above 104. As a result, EDR can often be used with little or no pretreatment of feedwater to prevent fouling. So far, ____________and EDR have been used at only a few locations for drinking water treatment. A. ED D. NF B. An important RO process E. UF C. These RO membranes F. None of the Above 24 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 Drinking Water Standards 105. The __________________is responsible for establishing maximum contaminant levels for drinking water. These standards are expressed as MCL (Maximum Contaminant Level). In most cases, this measurement is expressed as milligrams per liter of water (mg/l) or as parts per million (ppm). A. MCLG D. Emergency Planning and Community Right to Know Act (EPCRA) B. MCLs E. US Environmental Protection Agency C. Group USA F. None of the Above 106. In general terms, inorganic compounds are those materials that do not contain carbon. These compounds are often able to be dissolved in water. For example, dissolved gases such as nitrogen, oxygen, radon, and methane can be classified as _________________. A. Myriad organic compounds D. Ionic compounds B. Inorganic compounds E. Electron affinity (anions) C. Some metals F. None of the Above 107. In addition to dissolved gases, some metals may be present in water as well. Some of these metals can be hazardous to human health, and may be introduced into water either naturally or through__________________________. A. Myriad organic compounds D. Ionic compounds B. Inorganic compounds E. Electron affinity (anions) C. Some metals F. None of the Above 108. Some of the more common metals include arsenic and aluminum which the EPA has established a MCL of no more than____________________. A. 4.0 D. .015 B. .002 E. 10.0 C. 1.3 F. None of the Above 109. Lead with a MCL of____________________. A. 4.0 D. .015 B. .002 E. 10.0 C. 1.3 F. None of the Above 110. Mercury MCL of_______________ A. 4.0 D. .015 B. .002 E. 10.0 C. 1.3 F. None of the Above 111. In addition, zinc, calcium, sodium, magnesium, potassium, and copper, all with a _______ MCL. A. 4.0 D. .015 B. .002. E. 10.0 C. 1.3 F. None of the Above 112. ______________ can be dangerous to human health even at low concentrations, and as mentioned above can be introduced to our water from a variety of sources, including old pipes and lead solder. A. Crystallization compounds D. Organometallic compounds B. Inorganic salts E. Lead, mercury, and arsenic C. Compounds F. None of the Above 113. Some of the ________________such as sodium, potassium, calcium, and magnesium are important to our overall health and well-being. A. Myriad organic compounds D. Ionic compounds B. Other inorganic compounds E. Other organic compounds C. Metals F. None of the Above 25 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 114. Another class of inorganic compounds are known as negative ions. These include substances such as fluoride: MCL _______ PPM (parts per million). A. 4.0 D. .015 B. .002 E. 10.0 C. 1.3 F. None of the Above 115. Chloride and nitrate: MCL ____________ ppm. A. 4.0 D. .015 B. .002 E. 10.0 C. 1.3 F. None of the Above 116. Nitrite MCL ________________. A. 4.0 D. 1.0 B. .002 E. 10.0 C. 1.3 F. None of the Above 117. Sulfate, phosphate, carbonate, and cyanide: MCL _____________ A. 2.0 D. .025 B. .002 E. 20.0 C. 0.2 F. None of the Above Inorganic Chemistry 118. Inorganic chemistry is the study of the synthesis and behavior of________________. This field covers all chemical compounds except the myriad organic compounds (carbon based compounds, usually containing C-H bonds), which are the subjects of organic chemistry. A. Myriad organic compounds D. Ionic compounds B. Inorganic compounds E. Inorganic and organometallic compounds C. Some metals F. None of the Above 119. The distinction between the two disciplines is far from absolute, and there is much overlap, most importantly in the sub-discipline of ____________________. It has applications in every aspect of the chemical industry–including catalysis, materials science, pigments, surfactants, coatings, medicine, fuel, and agriculture. A. Crystallization D. Organometallic chemistry B. Inorganic salts E. Lead, mercury, and arsenic C. Electrically neutral F. None of the Above Key Concepts 120. Many inorganic compounds are ionic compounds, consisting of ________________joined by ionic bonding. A. Myriad organic compounds D. Cations and anions B. Inorganic compounds E. Electron affinity (anions) C. Some metals F. None of the Above 121. In any salt, the proportions of the ions are such that the electric charges cancel out, so that the bulk compound is__________________. A. A shiny crystal D. A sub-discipline of organometallic chemistry B. An inorganic salt E. Electrically positive C. Electrically neutral F. None of the Above 122. The ions are described by their oxidation state and their ease of formation can be inferred from the ionization potential (for cations) or from the electron affinity (anions) of the _______________. A. Myriad organic compound D. Ionic compound B. Inorganic compound E. Anions C. Metal F. None of the Above 26 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 123. Important classes of inorganic salts are the_____________, the sulfates and the halides. A. Crystals D. Sub-discipline of organometallic chemistry like B. Oxides, the carbonates E. Sulfites C. Electrically neutral cations F. None of the Above 124. Many inorganic compounds are characterized by high melting points. Inorganic salts typically are poor conductors in the___________________. A. Myriad D. Ionic compound B. Inorganic compound mixture E. Solid state C. Customer’s coffee F. None of the Above 125. Another important feature is their solubility in water, e.g.,_____________. Where some salts (e.g., NaCl) are very soluble in water, others (e.g., SiO2) are not. A. And ease of crystallization D. Sub-discipline of organometallic chemistry B. Inorganic salts E. Ionic compound C. Electrically neutral F. None of the Above 126. The simplest inorganic reaction is double displacement when in mixing of two salts the ions are swapped without a change in oxidation state. In redox reactions one reactant, the oxidant, lowers its ______________________and another reactant, the reductant, has its oxidation state increased. The net result is an exchange of electrons. A. pH D. Ionic count B. Redox state E. Electron affinity (anions) C. Oxidation state F. None of the Above 127. ________________can occur indirectly as well, e.g., in batteries, a key concept in electrochemistry. A. Crystallization D. Electron exchange B. Inorganic salts E. Regeneration C. Electrically neutral charges F. None of the Above 128. When one reactant contains hydrogen atoms, a reaction can take place by exchanging protons in acid-base chemistry. In a more general definition, an acid can be any chemical species capable of binding to electron pairs is called a Lewis acid; conversely any molecule that tends to donate an electron pair is referred to as a Lewis base. As a refinement of__________________, the HSAB theory takes into account polarizability and size of ions. A. Supramolecular coordination chemistry D. Grouping compounds by their structural similarities B. Classical coordination compounds E. Organometallic chemistry C. Inorganic compounds F. None of the Above 129. Inorganic compounds are found in nature as minerals. Soil may contain iron sulfide as pyrite or ________________________. A. Often similar reactivity D. Man-made inorganic compounds B. Coordination complexes E. Nature-made inorganic compounds C. Classification of compounds F. None of the Above 130. Inorganic compounds are also found multitasking as biomolecules: as electrolytes (sodium chloride), in energy storage (ATP) or in construction (______________________). A. Supramolecular coordination chemistry D. Grouping compounds by their structural similarities B. Classical coordination compounds E. Organometallic chemistry C. Inorganic compounds F. None of the Above 27 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 131. The first important ___________________ was ammonium nitrate for soil fertilization through the Haber process. Inorganic compounds are synthesized for use as catalysts such as vanadium (V) oxide and titanium (III) chloride, or as reagents in organic chemistry such as lithium aluminum hydride. A. Compound D. Man-made inorganic compound B. Complexed mineral E. Nature-made inorganic compounds C. Cation F. None of the Above 132. Subdivisions of inorganic chemistry are organometallic chemistry, ________________and bioinorganic chemistry. These fields are active areas of research in inorganic chemistry, aimed toward new catalysts, superconductors, and therapies. A. Supramolecular coordination chemistry D. Grouping compounds by their structural similarities B. Classical coordination compounds E. FUBAR chemistry C. Cluster chemistry F. None of the Above Descriptive Inorganic Chemistry 133. Descriptive inorganic chemistry focuses on the A. Classification of reactivity B. Classification of coordination complexes C. Classification of compounds _____________ based on their properties. D. Classification of inorganic compound E. Classification of nature F. None of the Above 134. Partly the classification focuses on the position in the periodic table of the heaviest element (the element with the highest atomic weight) in the compound, partly by grouping compounds by their ___________. A. Supramolecular similarities D. Structural similarities B. Classical coordination compounds E. Organometallic chemistry similarities C. Inorganic compounds similarities F. None of the Above 135. When studying inorganic compounds, one often encounters parts of the different classes of inorganic chemistry (an organometallic compound is characterized by its coordination chemistry, and may show interesting_______________________________). A. Often similar reactivity D. Man-made inorganic compound B. Coordination complexes E. Solid state properties C. Classification of compounds F. None of the Above Different classifications are: Coordination Compounds 136. Classical coordination compounds feature metals bound to "lone pairs" of electrons residing on the main group atoms of ligands such as H2O, NH3, Cl−, and CN−. In ______________almost all organic and inorganic compounds can be used as ligands. A. Supramolecular coordination chemistry D. Modern coordination compounds B. Classical coordination compounds E. Organometallic chemistry C. Inorganic compounds F. None of the Above 137. The "metal" usually is a metal from the groups 3-13, as well as the trans-lanthanides and transactinides, but from a certain perspective, all chemical compounds can be described as _____________________. A. Reactivity D. Man-made inorganic compound B. Coordination complexes E. Small nuclear explosions C. Classification of compounds F. None of the Above 28 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 138. The stereochemistry of coordination complexes can be quite rich, as hinted at by Werner's separation of two enantiomers of [Co((OH)2Co(NH3)4)3]6+, an early demonstration that chirality is not inherent to organic compounds. A topical theme within this specialization is ______________. A. Supramolecular coordination chemistry D. Bath tub chemistry B. Classical coordination chemistry E. Organometallic chemistry C. Inorganic chemistry F. None of the Above Main Group Compounds 139. These species feature __________________from groups 1, 2 and 13-18 (excluding hydrogen) of the periodic table. Due to their often similar reactivity, the elements in group 3 (Sc, Y, and La) and group 12 (Zn, Cd, and Hg) are also generally included. A. Often similar flavors D. Man-made inorganic compounds B. Coordination colors E. Minerals C. Elements F. None of the Above 140. ______________________have been known since the beginnings of chemistry, e.g., elemental sulfur and the distillable white phosphorus. A. Main group compounds D. Metal-metal bonded dimetallic complexes B. Organometallic chemistry E. Organic compounds C. Organometallic compounds F. None of the Above 141. Experiments on oxygen, O2, by Lavoisier and Priestley not only identified an important diatomic gas, but opened the way for describing compounds and reactions according to________________. A. Transition metals D. Metal carbonyls B. Diatomic gases E. Transition metal compounds C. Stoichiometric ratios F. None of the Above 142. The discovery of a practical synthesis of ammonia using iron catalysts by Carl Bosch and Fritz Haber in the early 1900s deeply impacted mankind, demonstrating the significance of _________________. A. Transition metal synthesis D. Metal-metal synthesis B. Organometallic chemistry synthesis E. Inorganic chemical synthesis C. Organometallic synthesis F. None of the Above 143. Typical main group compounds are SiO2, SnCl4, and N2O. Many main group compounds can also be classed as “_____________________”, as they contain organic groups, e.g., B(CH3)3). A. Transition metals D. Metal carbonyls and even metal alkoxides B. An important diatomic gas E. Transition metal compounds C. Organometallic F. None of the Above 144. Main group compounds also occur in nature, e.g., phosphate in DNA, and therefore may be classed as bioinorganic. Conversely, organic compounds lacking (many) hydrogen ligands can be classed as “______________”, such as the fullerenes, buckytubes and binary carbon oxides. A. Transition metal compounds D. Metal-metal bonded dimetallic complexes B. Organometallic chemistry E. Organic compounds C. Organometallic compounds F. None of the Above Transition Metal Compounds 145. Compounds containing metals from group 4 to 11 are considered transition metal compounds. Compounds with a metal from group 3 or 12 are sometimes also incorporated into this group, but also often classified as_____________________. A. Transition metal compounds D. Carbonyls compounds B. Main group compounds E. Transition metal compounds C. Organometallic compounds F. None of the Above 29 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 146. Transition metal compounds show a rich coordination chemistry, varying from tetrahedral for titanium (e.g., TiCl4) to square planar for some nickel complexes to octahedral for ______________of cobalt. A. Transition metal compounds D. Metal-metal bonded dimetallic complexes B. Organometallic complexes E. Coordination complexes C. Organometallic compounds F. None of the Above 147. A range of _______________ can be found in biologically important compounds, such as iron in hemoglobin. A. Transition metals D. Metal complexes B. Complexes E. Transition metal compounds C. Organometallic complexes F. None of the Above Organometallic Compounds 148. Usually, organometallic compounds are considered to contain the M-C-H group. The metal (M) in these species can either be a main group element or a___________________. A. Transition metal compound D. Metal-metal bonded dimetallic complex B. Transition metal E. Organic compound C. Organometallic compound F. None of the Above 149. Operationally, the definition of ______________________ is more relaxed to include also highly lipophilic complexes such as metal carbonyls and even metal alkoxides. A. Transition metals D. Metal carbonyls and even metal alkoxides B. An important diatomic gas E. Transition metal compounds C. An organometallic compound F. None of the Above 150. Organometallic compounds are mainly considered a special category because organic ligands are often sensitive to hydrolysis or oxidation, necessitating that _______________ employs more specialized preparative methods than was traditional in Werner-type complexes. A. Transition metal compounds D. Metal-metal chemistry B. Organometallic chemistry E. Organic chemistry C. Organometallic compounds F. None of the Above 151. ______________________, especially the ability to manipulate complexes in solvents of low coordinating power, enabled the exploration of very weakly coordinating ligands such as hydrocarbons, H2, and N2. Because the ligands are petrochemicals in some sense, the area of organometallic chemistry has greatly benefited from its relevance to industry. A. Transition metals D. Synthetic carbonyl and even metal alkoxides B. Synthetic gas methodology E. Transition metal compounds C. Synthetic methodology F. None of the Above Cluster Compounds 152. Clusters can be found in all classes of____________. According to the commonly accepted definition, a cluster consists minimally of a triangular set of atoms that are directly bonded to each other. But metal-metal bonded dimetallic complexes are highly relevant to the area. A. Transition metal compounds D. Chemical compounds B. Organometallic chemistry E. Organic compounds C. Organometallic compounds F. None of the Above 153. Clusters occur in "pure"____________________, organometallic chemistry, main group chemistry, and bioinorganic chemistry. The distinction between very large clusters and bulk solids is increasingly blurred. A. Transition metals D. Metal carbonyls and even metal alkoxides B. Inorganic systems E. Transition metal compounds C. Organometallic systems F. None of the Above 30 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 154. This interface is the chemical basis of nanoscience or nanotechnology and specifically arise from the study of quantum size effects in ______________________. Thus, large clusters can be described as an array of bound atoms intermediate in character between a molecule and a solid. A. Transition metal compounds D. Metal-metal bonded dimetallic complexes B. Organometallic chemistry E. Organic compounds C. Organometallic compounds F. None of the Above Bioinorganic Compounds 155. By definition, these compounds occur in nature, but the subfield includes anthropogenic species, such as pollutants (e.g., methylmercury) and drugs (e.g., Cisplatin). The field, which incorporates many aspects of biochemistry, includes many kinds of compounds, e.g., the phosphates in DNA, and also metal complexes containing ligands that range from_________________, commonly peptides, to ill-defined species such as humic acid, and to water (e.g., coordinated to gadolinium complexes employed for MRI). A. Crystallography D. Theoretical chemistry and computational chemistry B. Biological macromolecules E. Molecular symmetry C. Inter alia F. None of the Above 156. Traditionally bioinorganic chemistry focuses on electron- and energy-transfer in proteins relevant to respiration. ______________________includes the study of both non-essential and essential elements with applications to diagnosis and therapies. A. Symmetry to spectroscopy D. Medicinal inorganic chemistry B. Theoretical calculations E. Solid state chemistry C. Qualitative approach F. None of the Above Solid State Compounds 157. This important area focuses on structure, bonding, and the physical properties of materials. In practice, ______________________uses techniques such as crystallography to gain an understanding of the properties that result from collective interactions between the subunits of the solid. A. Crystallography D. Theoretical chemistry and computational chemistry B. VSEPR theory E. Molecular symmetry C. Solid state inorganic chemistry F. None of the Above 158. Included in _______________ are metals and their alloys or intermetallic derivatives. Related fields are condensed matter physics, mineralogy, and materials science. A. Symmetry to spectroscopy D. Precise quantum mechanical descriptions B. Theoretical calculations E. Solid state chemistry C. Qualitative approach F. None of the Above Theoretical Inorganic Chemistry 159. An alternative perspective on the area of inorganic chemistry begins with the _______________ and, using the tools and models of theoretical chemistry and computational chemistry, expands into bonding in simple and then more complex molecules. A. Crystallography D. Theoretical chemistry and computational chemistry B. VSEPR theory E. Molecular symmetry C. Bohr model of the atom F. None of the Above 160. Precise ________________________, the province of inorganic chemistry, is difficult. This challenge has spawned many semi-quantitative or semi-empirical approaches including molecular orbital theory and ligand field theory, In parallel with these theoretical descriptions, approximate methodologies are employed, including density functional theory. A. Symmetry D. Quantum mechanical descriptions B. Theoretical calculations E. Solid state chemistry C. Qualitative approaches F. None of the Above 31 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 Qualitative Theories 161. Inorganic chemistry has greatly benefited from qualitative theories. Such theories are easier to learn as they require little background in quantum theory. Within main group compounds, ___________________ powerfully predicts, or at least rationalizes, the structures of main group compounds, such as an explanation for why NH3 is pyramidal whereas ClF3 is T-shaped. A. Crystallography theory D. Theoretical chemistry theory B. VSEPR theory E. Molecular symmetry theory C. Inter alia theory F. None of the Above 162. For the transition metals, __________________allows one to understand the magnetism of many simple complexes, such as why [FeIII(CN)6]3− has only one unpaired electron, whereas [FeIII(H2O)6]3+ has five. A particularly powerful qualitative approach to assessing the structure and reactivity begins with classifying molecules according to electron counting, focusing on the numbers of valence electrons, usually at the central atom in a molecule. A. Spectroscopy theory D. Crystal field theory B. Theoretical calculation theory E. Solid state chemistry C. Qualitative theory F. None of the Above Molecular Symmetry Group Theory 163. A central construct in inorganic chemistry is the theory of _____________________. A. Crystallography theory D. Theoretical chemistry and computational chemistry B. VSEPR theory E. Molecular symmetry C. Inter alia theory F. None of the Above 164. ___________________provides the language to describe the shapes of molecules according to their point group symmetry. Group theory also enables factoring and simplification of theoretical calculations. A. Mathematical group theory D. Evolutionary theory B. Theoretical theory E. Solid theory C. Qualitative approach F. None of the Above 165. Spectroscopic features are analyzed and described with respect to the symmetry properties of the, ____________, vibrational or electronic states. Knowledge of the symmetry properties of the ground and excited states allows one to predict the numbers and intensities of absorptions in vibrational and electronic spectra. A. Crystallography D. Computational chemistry B. VSEPR theory E. Molecular symmetry C. Inter alia F. None of the Above 166. A ___________________ is the prediction of the number of C-O vibrations in substituted metal carbonyl complexes. The most common applications of symmetry to spectroscopy involve vibrational and electronic spectra. A. Symmetry to spectroscopy D. Precise quantum mechanical description B. Theoretical calculation E. Solid state chemistry C. Qualitative approach F. None of the Above 167. As an instructional tool, ___________________highlights commonalities and differences in the bonding of otherwise disparate species, such as WF6 and Mo(CO)6 or CO2 and NO2. A. Group theory D. Precise quantum mechanical description B. Theoretical calculation E. Solid state chemistry C. Qualitative approach F. None of the Above 32 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 Synthetic Inorganic Chemistry 168. Although some _______________ can be obtained in pure form from nature, most are synthesized in chemical plants and in the laboratory. A. Maximum Contaminant Level (MCL) D. Maximum Contaminant Level Goals (MCLG) B. Species E. Inorganic species C. Organisms F. None of the Above 169. Inorganic synthetic methods can be classified roughly according the volatility or solubility of the component reactants. ______________ are prepared using methods of organic synthesis. For metalcontaining compounds that are reactive toward air, Schlenk line and glove box techniques are followed. A. Soluble inorganic compounds D. Carcinogens B. Methemoglobinemia E. Chemicals C. Products and reactants F. None of the Above 170. _________________are manipulated in “vacuum manifolds” consisting of glass piping interconnected through valves, the entirety of which can be evacuated to 0.001 mm Hg or less. A. Maximum corrections D. Maximum odors B. Chain of custody procedures E. Inorganic species C. Volatile compounds and gases F. None of the Above 171. ______________are condensed using liquid nitrogen (b.p. 78K) or other cryogens. Solids are typically prepared using tube furnaces, the reactants and products being sealed in containers. A. Compounds D. Carcinogens B. Methemoglobinemia E. Chemicals C. Products and reactants F. None of the Above Regulated Chemical Contaminants 172. EPA established Maximum Contaminant Levels (MCL), _________________, monitoring requirements and best available technologies for removal for 65 chemical contaminants over a five year period as EPA gathered and analyzed occurrence and health effects data. A. Minimum Contaminant Level (MCL) D. Maximum Contaminant Level Goals (MCLG) B. Chain of custody procedures E. Inorganic species C. ACLs F. None of the Above 173. This series of rules are known as the Chemical Phase Rules and they define regulations for three contaminant groups:___________, Synthetic Organic Chemicals (SOC), and Volatile Organic Chemicals (VOC). A. Inorganic Chemicals (IOC) D. Carcinogens B. IOUs and UFOs E. Chemical Phase Rules C. Products and reactants F. None of the Above 174. ________________provide public health protection through the reduction of chronic risks from: cancer; organ damage; and circulatory, nervous, and reproductive system disorders. A. Maximum Contaminant Level (MCL) D. Maximum Contaminant Level Goals (MCLG) B. Chain of custody procedures E. Evolved species C. The Chemical Phase rules F. None of the Above 175. They also help to reduce the occurrence of ________________ or "blue baby syndrome" from ingestion of elevated levels of nitrate or nitrite. All public water systems must monitor for Nitrate and Nitrite. A. Aldicarb, aldicarb sulfone, and aldicarb sulfoxide D. Carcinogens B. Methemoglobinemia E. SMURF chemicals C. Products and reactants F. None of the Above 33 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 176. ________________ must also monitor for IOCs, SOCs, and VOCs. A. Maximum Contaminant Level (MCL) D. Maximum Contaminant Level Goals (MCLG) B. Chain of custody procedures E. Small systems C. All systems F. None of the Above 177. Aldicarb, aldicarb sulfone, and aldicarb sulfoxide are considered regulated chemicals although their ______________ are stayed. Therefore PWS are not required to meet an MCL. A. MCLs D. Carcinogen Rule B. CMOMs E. Chemical Phase Rules C. Products and reactants F. None of the Above 178. For each contaminant, EPA set a health goal, or ______________. This is the level at which a person could drink two liters of water containing the contaminant every day for 70 years without suffering any ill effects. This goal is not a legal limit with which water systems must comply; it is based solely on human health. A. Maximum Contaminant Level (MCL) D. Maximum Contaminant Level Goals (MCLG) B. Procedures E. A legal rule or sometimes a theory C. Field goal F. None of the Above 179. For known cancer-causing agents (_______________), EPA set the health goal at zero, under the assumption that any exposure to the chemical could present a cancer risk. A. Sulfoxides D. Carcinogens B. Methemoglobinemia E. Chemicals C. Reactants F. None of the Above 180. The rules also set a legal limit, or Maximum Contaminant Level (MCL), for each contaminant. EPA sets ________________as close to the health goal as possible, keeping in mind the technical and financial barriers that exist. A. Maximum Contaminant Level (MCL) D. Maximum Contaminant Level Goals (MCLG) B. Procedures E. Inorganic species C. Legal limits F. None of the Above 181. Except for contaminants regulated as _______________, most legal limits and health goals are the same. Even when they are less strict than the health goals, the legal limits provide substantial public health protection. A. Contaminants D. Carcinogens B. Pollutants E. Chemicals C. Products and reactants F. None of the Above Chain of Custody Procedures 182. Because a sample is physical evidence, ______________________are used to maintain and document sample possession from the time the sample is collected until it is introduced as evidence. Chain of custody requirements will vary from agency to agency. However, these procedures are similar and the chain of custody outlined in this manual is only a guideline. Consult your project manager for specific requirements. A. Samples D. Chain of custody procedures B. Seal E. Chain of custody record C. Evidence tape F. None of the Above 34 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 183. If you have ______________ of a sample, have it in view, or have physically secured it to prevent tampering then it is defined as being in “custody." A chain of custody record, therefore, begins when the sample containers are obtained from the laboratory. From this point on, a chain of custody record will accompany the sample containers. A. Physical possession D. Physical evidence B. A taste E. Chain of custody record C. Evidence tape F. None of the Above 184. Handle the samples as little as possible in the field. Each custody sample requires a chain of custody record and may require_____________. If you do not seal individual samples, then seal the containers in which the samples are shipped. A. A sample D. Physical evidence B. A seal E. A chain of custody record C. Evidence tape F. None of the Above 185. When the samples transfer possession, both parties involved in the transfer must sign, date and note the time on the chain of custody record. If a shipper refuses to sign the chain-of-custody you must seal the samples and _______________ inside a box or cooler with bottle seals or evidence tape. A. Chain of custody documents D. Physical evidence B. Seal E. Chain of custody record C. Squirrel F. None of the Above 186. The recipient will then attach the shipping invoices showing the transfer dates and times to the custody sheets. If the samples are split and sent to more than one laboratory, prepare a separate ______________________ for each sample. A. Sample score sheet D. Physical evidence of the original tap B. Seal E. Chain of custody record C. Evidence report F. None of the Above 187. If the samples are delivered to after-hours night drop-off boxes, the ___________should note such a transfer and be locked with the sealed samples inside sealed boxes. A. Sample taste record D. Physical evidence B. Custody record E. Chain of custody record C. Evidence record F. None of the Above Wastewater Priory Pollutants Section Wastewater/Pretreatment Sampling General Information 188. In accordance with the Clean Water Act and_____________ , the POTW conducts a variety of sampling activities which must be closely coordinated. A. General Pretreatment Program Regulations D. Priority Pollutants within B. Each site user and E. Characteristics of the wastes C. All industrial users and F. None of the Above Permit Application Policy Example 189. All industrial users that require a permit must be sampled to determine the characteristics of the ________________ to be discharged into the POTW’s sewer system. A. SROG D. Priority Pollutants B. Local limits E. Wastes C. Outer limits F. None of the Above 35 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 190. Prior to the issuance of a permit for existing industrial users, the POTW samples the user's effluent, and performs the analyses required by the applicable discharge standards (i.e., Categorical standards or_______________________). A. Taste test D. Priority Pollutants B. Local limits E. Characteristics of the wastes C. SDWA F. None of the Above 191. For new industrial users, estimates of the ______________ to be discharged into the POTW’s sewer system must be submitted along with the permit application. A. Wastes D. Priority Pollutants B. CWA E. Characteristics of the wastes C. Odor F. None of the Above 192. No sampling would be performed at these new facilities, since they do not presently discharge wastes into the____________________. A. POTWs D. Priority system B. Sewer system E. Interceptor C. CMOM F. None of the Above 193. A four-day sampling program is usually conducted at ____________ to collect both composite and grab (for pollutants not amenable to composite sampling) samples as needed. A. POTWs D. The interceptor B. Each site E. The manhole C. All industrial users F. None of the Above Wastewater Priory Pollutants 194. The concentrations of various substances in __________in dissolved, colloidal or suspended form are typically low but vary considerably. A. POTWs D. Priority Pollutants B. These 126 pollutants E. Water C. New industrial users F. None of the Above 195. Priority Pollutants refer to a list of 126 specific pollutants that includes heavy metals and specific organic chemicals. The priority pollutants are a subset of "_______________ " as defined in the Clean Water Act (USA). A. POTWs D. Priority Pollutants B. Toxic pollutants E. Safe contaminants C. Friendly pollutants F. None of the Above 196. _________________ were assigned a high priority for development of water quality criteria and effluent limitation guidelines because they are frequently found in wastewater. A. POTW managers D. Priority Pollutants B. These 126 pollutants E. The concentrations of various substances C. Safe contaminants F. None of the Above 197. ______________with an approved pretreatment program must develop local limits for arsenic, cadmium, chromium, copper, cyanide, lead, mercury, nickel, silver and zinc or demonstrate that limits are not necessary for these pollutants. A. Each POTW D. Priority pollutant producers B. Each city E. Home owners C. All industrial users F. None of the Above 36 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 198. The POTW must also identify all _________________and evaluate the need for limits for these pollutants. A. Other pollutants of concern D. Priority Pollutants B. 126 pollutants E. Concentrations of various substances C. New industrial users F. None of the Above 199. _______________ is defined as any pollutant limited in the POTW's NPDES permit or found in the collection system in sufficient quantity to have a reasonable potential to cause pass through or interference at the treatment plant, pose a threat to worker health and safety, or to cause other problems within the collection system or at the treatment plant, such as explosions or obstruction of wastewater flow. A. A pollutants of concern D. Priority Pollutants B. 126 pollutants E. Concentrations of various substances C. New industrial users F. None of the Above 200. The priority pollutant scans performed periodically by POTWs with approved pretreatment programs are useful in identifying___________________. A. Pollutants of concern D. Priority Pollutants B. These 126 pollutants E. The concentrations of various substances C. New industrial users F. None of the Above 201. POTWs with multiple plants may wish to develop ____________for each plant or after calculating the limits for each plant choose the most stringent as uniform local limits across all plants. A. Local limits D. Priority Pollutants B. Headworks E. Characteristics of the wastes C. Industrial users F. None of the Above 202. Local limits are most often associated with the control of toxic pollutants. However, if a POTW has experienced violations of their _______________(such as BOD, TSS, ammonia, phosphorus, or oil and grease), or has experienced operational problems due to these pollutants, the POTW should investigate the need for local limits for conventional pollutants as well. A. POTWs D. NPDES permit effluent limits for conventional pollutants B. Surcharge programs E. Local limits C. Industrial users F. None of the Above 203. Many POTWs have surcharge programs for________________. A surcharge program should not be confused with local limits for these pollutants. A. POTWs D. Priority Pollutants B. Conventional pollutants E. Local limits C. All industrial users F. None of the Above 204. In addition to a surcharge program, which is generally triggered by specific pollutant concentrations, a POTW should set absolute upper limits for __________________in its sewer use ordinance (SUO) or industrial user (IU) permits, based on total plant capacity. A. Conventional pollutants D. Priority Pollutants B. Surcharge programs E. Local limits C. All industrial users F. None of the Above 205. Nutrients: Carbon, nitrogen and phosphorus are substances that are excreted by humans and thus found in wastewater. ___________________can stimulate the growth of algae and other aquatic plants. A. Excess nutrients D. Carbon, nitrogen and phosphorus B. Industrial discharges E. Agricultural runoff C. Heavy Metal F. None of the Above 37 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 206. When these plants die and decompose, they may reduce the amount of _______________ in the water. This condition, called hypoxia, can affect the survival of fish and other aquatic organisms. A. Nutrients D. Carbon, nitrogen and phosphorus B. Oxygen E. Agricultural runoff C. Heavy Metal F. None of the Above 207. _______________ can also get into wastewater from industrial discharges, common household detergents and cleaners, runoff from streets and lawns and air pollutants that fall to the ground. A. Nutrients D. Carbon, nitrogen and phosphorus B. Industrial discharges E. Agricultural runoff C. Heavy Metal F. None of the Above 208. Treatment plants cannot remove all _________________ from the wastewater. They can be reduced by controlling pollution that comes from lawns, farmland, streets and construction sites. A. Nutrients D. Carbon, nitrogen and phosphorus B. Industrial discharges E. Agricultural runoff C. Heavy Metal F. None of the Above 209. Many of the heavy metals, pesticides, and other chemicals listed here are on the priority pollutant list: Heavy Metals (Total and Dissolved): "Heavy Metal" in the water treatment field refers to heavy, dense, ______________________that occur only at trace levels in water, but are very toxic and tend to accumulate. Arsenic, Cadmium, Chromium, Lead in industry or in households, Mercury and Zinc A. Nutrients D. Metallic elements B. Industrial discharges E. Agricultural runoff C. Heavy Metal F. None of the Above 210. Pesticides: Pesticides comprise a large class of compounds of concern. _________________ include DDT, Aldrin, Chlordane, Endosulfan, Endrin, Heptachlor, and Diazinon. Surprisingly, concentrations of pesticides in urban runoff may be equal or greater than the pesticides in agricultural runoff. A. Nutrients D. Typical pesticides and herbicides B. Industrial discharges E. Agricultural runoff C. Heavy Metal F. None of the Above 211. Polycyclic Aromatic Hydrocarbons (PAHs): Polycyclic Aromatic Hydrocarbons include a family of semi-volatile organic pollutants such as naphthalene, anthracene, pyrene, and benzo(a)pyrene. There are typically two main sources of_______________________: spilled or released petroleum products (from oil spills or discharge of oil production brines) and combustion products that are found in urban runoff. A. PAHs D. Open-ended groups of pollutants B. Priority Pollutants E. Inorganics C. Chemical standards F. None of the Above 212. Polychlorinated biphenyls (PCBs): Polychlorinated biphenyls are __________________that formerly had widespread use in electrical transformers and hydraulic equipment. This class of chemicals is extremely persistent in the environment and has been proven to bioconcentrate in the food chain, thereby leading to environmental and human health concerns in areas such as the Great Lakes. A. Appropriate for organics D. Toxic pollutants B. Preservatives E. Environmental and human health concerns C. Organic chemicals F. None of the Above 38 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 213. Key features of the list of priority pollutants and its relationship to the list of toxic pollutants: The Priority Pollutants are a set of _____________EPA regulates, and for which EPA has published analytical test methods. A. Combustion products D. Open-ended groups of pollutants B. Chemical pollutants E. Sampling requirements for inorganics C. Chemical standards F. None of the Above 214. The Priority Pollutant list makes the list of toxic pollutants more usable, in a practical way, for the purposes assigned to EPA by the Clean Water Act. For example, the ________________list is more practical for testing and for regulation in that chemicals are described by their individual chemical names. A. Organics D. List of toxic pollutants more usable B. Preservatives E. Environmental and human health concerns C. Priority Pollutant F. None of the Above 215. ___________________, in contrast, contains open-ended groups of pollutants, such as "chlorinated benzenes." That group contains hundreds of compounds; there is no test for the group as a whole, nor is it practical to regulate or test for all of these compounds. A. Combustion products D. Open-ended groups of pollutants B. Priority Pollutants E. The list of toxic pollutants C. Chemical standard F. None of the Above Derivation 216. Starting with the________________, EPA used four criteria to select and prioritize specific pollutants: We included all pollutants specifically named on the list of toxic pollutants; A. List of toxic pollutants D. List of toxic pollutants more usable B. Preservatives E. Environmental and human health concerns C. Most common preservatives F. None of the Above 217. There had to be a ________________available for the pollutant, so that testing for the pollutant could be performed; A. Chemical standard D. List of toxic pollutants more usable B. Preservative E. Environmental and human health concerns C. The most common preservatives F. None of the Above 218. The _________________had to have been reported as found in water with a frequency of occurrence of at least 2.5%, A. Combustion product D. Pollutant B. Priority Pollutant E. Sample C. Chemical standard F. None of the Above Proper Sample Handling 219. The proper handling of ____________________also includes wearing gloves. Gloves not only protect field personnel, but also prevent potential contamination to the water sample. Always wear powderless, disposable gloves. When sampling for inorganics, wear latex gloves. Nitrile gloves are appropriate for organics. A. Containers and preservatives D. Pre-preserved bottles B. Water quality samples E. Samples in the shade C. The most common preservatives F. None of the Above 39 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 220. Use chain-of-custody procedures when coolers and containers are prepared, sealed and shipped. They will remain sealed until used in the field. When making arrangements with the laboratory, make sure you request enough containers, including those for________________. Order extra sample bottles to allow for breakage or contamination in the field. A. Combustion products D. Open-ended groups of pollutants B. Priority Pollutants E. Sampling for inorganics C. Blank and duplicate samples F. None of the Above 221. Some samples require ________________and/or preservation with chemicals to maintain their integrity during shipment and before analysis in the laboratory. A. Containers and preservatives D. Pre-preserved bottles B. Low-temperature storage E. Samples in the shade C. The most common preservatives F. None of the Above 222. The most common _________________ are hydrochloric, nitric, sulfuric and ascorbic acids, sodium hydroxide, sodium thiosulfate, and biocides. A. Containers and preservatives D. Pre-preserved bottles B. Low-temperature storage E. Samples C. Preservatives F. None of the Above 223. Many laboratories provide pre-preserved bottles filled with measured amounts of preservatives. Although most federal and state agencies allow the use of _______________, some may require either cool temperatures or added preservatives in the field. A. Appropriate for organics D. List of toxic pollutants more usable B. Preservatives E. Environmental and human health concerns C. Pre-preserved sample containers F. None of the Above 224. When the ___________________are received from the laboratory, check to see that none have leaked. A. Containers and preservatives D. Pre-preserved bottles B. Paperwork E. Donuts C. Most common preservatives F. None of the Above 225. Be aware that many ____________ can burn eyes and skin, and must be handled carefully. A. Containers and preservatives D. Pre-preserved bottles B. Insects E. Samples C. Preservatives F. None of the Above 226. Sampling bottles should be labeled with type of preservative used, type of analysis to be done and be accompanied by a __________________. A. Certified operator D. List of toxic pollutants B. Preservatives E. Environmental and human health concerns C. Report F. None of the Above 227. Make sure you can tell which containers are_________________, because extra care must be taken not to overfill them when collecting samples in the field. Check with the laboratory about quality control procedures when using pre-preserved bottles. A. Invisible D. Plastic B. Low-temperature E. Used C. Pre-preserved F. None of the Above 40 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 228. Coolers used for sample shipment must be large enough to store containers, packing materials and ice. Obtain extra coolers, if necessary. Never store coolers and containers near solvents, fuels or other sources of _________________. In warm weather, keep coolers and samples in the shade. A. Contamination or combustion D. Promulgated by the U.S. EPA in 1992 B. Mix surface and ground water E. A one-time inorganic chemical analysis C. Gross alpha activity F. None of the Above Field Parameters 229. Measure and record the _________________of temperature, electrical conductivity, pH and dissolved oxygen in an undisturbed section of streamflow. Other parameters may be measured, if desired. A. Process D. Grab samples B. Optimal effects E. Field parameters C. Current F. None of the Above Chemical Monitoring 230. The final federal rules regarding Phase II and V contaminants were promulgated by the U.S. EPA in 1992 and initial monitoring began in January 1993. This group of contaminants consists of Inorganic Chemicals (IOC), Volatile Organic Chemicals (VOC) and Synthetic Organic Chemicals (SOC) and the rule applies to all ___________________________________. A. Contamination D. Promulgated by the U.S. EPA in 1992 B. Mix surface and ground water E. A one-time inorganic chemical analysis C. Gross alpha activity F. None of the Above Inorganic Chemical Monitoring 231. All systems must monitor for inorganics. The monitoring for these contaminants is also complex with reductions, waivers and detections affecting the sampling frequency. Please refer to the _______ provided by your state health or drinking water sections for assistance in determining individual requirements. A. Drinking water treatment process D. EPA book B. Manual E. EPA rule C. List F. None of the Above 232. All transient non-community water systems are required to complete a one-time inorganic chemical analysis. The sample is to be collected at__________ to the distribution system representative of each source after any application of treatment. A. Contamination sources D. Entry points (POE) B. Areas of surface and ground water E. Water main breaks C. Signs of gross alpha activity F. None of the Above Nitrates 233. Nitrate is an inorganic chemical that occurs naturally in some groundwater but most often is introduced into ground and surface waters by man. The most common sources are from fertilizers and treated sewage or septic systems. At high levels (over 10 mg/l) it can cause the “blue baby” syndrome in young infants, which can lead to serious illness and even death. It is regarded as an “______________________” because it can quickly cause illness. A. Drinking water treatment health risk D. Chronic health risk B. Optimal health risk E. Acute health risk C. A surface water system health risk F. None of the Above 41 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 234. Every water system must test for Nitrate at least yearly. Systems that use ____________must test yearly. Systems that use surface water and those that mix surface and ground water must test every quarter. A. Contamination D. Water B. Mix surface and ground water E. A one-time inorganic chemical analysis C. Ground water only F. None of the Above 235. ____________________may go to yearly testing if community and nontransient noncommunity water must do quarterly monitoring whenever they exceed 5 mg/l in a test. After 4 quarters of testing and the results show that the nitrate level is not going up, they may go back to yearly testing. A. Drinking water treatment process D. Some groundwater B. Mix surface and ground water E. All systems C. A surface water system F. None of the Above Radiological Contaminants 236. All community water systems shall monitor for gross alpha activity every four years for each source. Depending on your state rules, compliance will be based on the annual composite of 4 consecutive quarters or__________________. If the average annual concentration is less than one half the MCL, an analysis of a single sample may be substituted for the quarterly sampling procedure. A. Sample instructions D. Laboratory performance requirements B. Established action levels E. Average annual concentration C. Minimum aeration F. None of the Above Total Trihalomethanes (TTHM) 237. All community water systems serving a population of 10,000 or more and which add a disinfectant in any part of the drinking water treatment process shall monitor for total trihalomethanes (TTHM). The MCL is 0.1 mg/l and consists of a calculation of ______________________of the concentrations of bromodichloromethane, di-bromochloromethane, bromoform and chloroform. A. The drinking water treatment process D. Some groundwater B. Optimal corrosion control E. The running average of quarterly analyses of the sum C. Surface water system F. None of the Above Lead and Copper Rule 238. The Lead and Copper Rule was promulgated by the U.S. EPA on June 7, 1991, with monitoring to begin in January 1992 for larger water systems. This rule applies to all community and nontransient, noncommunity water systems and _______________for these two contaminants at the consumer’s tap. Action levels of 0.015 mg/l for lead and 1.3 mg/l for copper have been established. A. Sample instructions D. Laboratory performance requirements B. Establishes action levels E. Average annual concentration C. Establishes MCL levels F. None of the Above 239. This rule establishes maximum contaminant level goals (MCLGs) for lead and copper, treatment technique requirements for optimal corrosion control, _______________, public education and lead service line replacement. A. Drinking water treatment process D. Some groundwater B. Source water treatment E. All systems C. A surface water system F. None of the Above 240. Whenever_______________, the corrosion control treatment requirement is triggered. This is determined by the concentration measured in the 90th percentile highest sample from the samples collected at consumers’ taps. A. Sample instructions D. Laboratory performance requirements are exceeded B. Establishes action levels E. The action level for the system C. An action level is exceeded F. None of the Above 42 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 241. Sample results are assembled in ascending order (lowest to highest) with the result at the 90th percentile being the action level for the system. For example, if a water system collected 20 samples, the result of the 18th highest sample would be_______________________. A. Sample instructions D. Laboratory performance requirements are exceeded B. Establishes action levels E. The action level for the system C. An action level is exceeded F. None of the Above 242. The rule also includes the best available technology (BAT) for complying with the treatment technique requirements, mandatory health effects language for public notification of violations and analytical methods and ________________________. A. Sample instructions D. Laboratory performance requirements B. Establishes action levels E. The action level for the system C. An action level is exceeded F. None of the Above IOC Sample Collection – Things to Remember 243. Sample instructions should be supplied with the sample containers from the laboratory. If the laboratory fails to include sample instructions, contact the laboratory and____________. A. Collect samples D. Do not change the flow B. Run E. Maintain chemical analysis reports C. Request sample instructions F. None of the Above Some general practices to remember: 244. Samples should be collected at _________________after all treatment (finished water). A. Homes D. The entry point to the distribution system B. SNAFU E. At water storage tanks C. Sample locations F. None of the Above 245. Select a sampling faucet that does NOT have an aerator (sampling must be done with _______________. A. Sample instructions D. Laboratory performance requirements B. Proper action levels E. Average flow C. Minimum aeration F. None of the Above 246. ____________ the water until the temperature is as cold as it gets. A. Collect D. Do not change the flow of B. Run E. Maintain C. Sample F. None of the Above 247. Just before sample collection,______________________. Do not change the flow while collecting the sample. A. Adjust to a very mediocre flow D. Do not taste B. Adjust to a very low flow E. Maintain a drip C. Sample and seal with your tongue F. None of the Above 248. Routine nitrate and nitrite samples should be collected on a__________________. A. Monday or a Tuesday D. Chance of weather B. Wednesday E. Saturday or Thursday C. Sunday or Friday F. None of the Above 249. When filling sample bottle, tip bottle slightly so that water flows down the side wall of the container. Bring bottle to __________________as it fills. A. Wash out that powder D. Not change the flow B. An upright position E. Maintain position C. An side position F. None of the Above 43 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 250. Call the laboratory if bottles are received broken (or break while collecting samples). The owner or operator of a water supply must maintain chemical analysis reports (results) or a summary of those reports for at least______________. A. 5 years D. 7 years B. 10 years E. 50 years C. 3 years F. None of the Above Antimony - Inorganic Contaminant 0.006 mg/L MCL Metalloid 251. Antimony is a toxic chemical element with symbol Sb and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the____________________________. A. Contaminant D. Subsequent element B. Analytical element E. Stibnite with iron C. Sulfide mineral stibnite (Sb2S3) F. None of the Above 252. ___________________have been known since ancient times and were used for cosmetics; metallic antimony was also known, but it was erroneously identified as lead. It was established to be an element around the 17th century. A. Gray allotrope of arsenic D. Metallic antimony B. Four allotropes E. Antimony compounds C. Nitrogen group (group 15) F. None of the Above 253. For some time, China has been the largest producer of antimony and its compounds, with most production coming from the Xikuangshan Mine in Hunan. The industrial methods to produce antimony are roasting and subsequent carbothermal reduction or direct reduction of_____________________. A. Sulfide mineral stibnite (Sb2S3) D. Heat B. Copper E. Lead C. Stibnite with iron F. None of the Above What are EPA's drinking water regulations for antimony? 254. In 1974, Congress passed the Safe Drinking Water Act. This law requires EPA to determine the level of contaminants in drinking water at which no adverse health effects are likely to occur. These______________ , based solely on possible health risks and exposure over a lifetime with an adequate margin of safety, are called maximum contaminant level goals (MCLG). A. Grey areas are D. Non-enforceable health goals B. Enforceable health goals E. Maximum contaminant levels (MCLs) C. Nitrogen group contaminants F. None of the Above 255. Contaminants are _________________ or matter in water. A. Contaminants D. Organic and inorganic B. Analytical problems E. Prominent additives C. Commonly found F. None of the Above 256. The MCLG for antimony is 0.006 mg/L or 6 ppb. EPA has set this level of protection based on the best available science to prevent potential health problems. EPA has set an enforceable regulation for antimony, called a ________________, at 0.006 mg/L or 6 ppb. A. MCLG D. Emergency Planning and Community Right to Know Act (EPCRA) B. MCL E. EPA C. CWA F. None of the Above 44 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 257. MCLs are set as close to the health goals as possible, considering cost, benefits and the ability of public water systems to detect and remove contaminants using suitable treatment technologies. In this case, the MCL equals the ____________________, because analytical methods or treatment technology do not pose any limitation. A. MCLG D. Goal B. MCLs E. EPA C. Weight or law F. None of the Above 258. The Phase V Rule, the regulation for antimony, became effective in 1994. The Safe Drinking Water Act requires __________________ to periodically review the national primary drinking water regulation for each contaminant and revise the regulation, if appropriate. A. OSHA D. Emergency Planning and Community Right to Know Act (EPCRA) B. MCLs E. EPA C. States F. None of the Above 259. _______________ reviewed antimony as part of the Six Year Review and determined that the 0.006 mg/L or 6 ppb MCLG and 0.006 mg/L or 6 ppb MCL for antimony are still protective of human health. A. OSHA D. Emergency Planning and Community Right to Know Act (EPCRA) B. MCLs E. EPA C. States F. None of the Above Applications 260. The largest applications for metallic antimony are as alloying material for lead and tin and for lead antimony plates in lead-acid batteries. _____________ with antimony improves the properties of the alloys which are used in solders, bullets and plain bearings. A. Gray allotrope of arsenic D. Metallic antimony B. Four allotropes E. Alloying lead and tin C. Nitrogen group (group 15) F. None of the Above 261. ______________are prominent additives for chlorine- and bromine-containing fire retardants found in many commercial and domestic products. An emerging application is the use of antimony in microelectronics. A. Contaminants D. Metallic antimony B. Gray allotrope of arsenic E. Prominent additives C. Antimony compounds F. None of the Above 262. Antimony is in the nitrogen group (group 15) and has an electronegativity of 2.05. As expected by periodic trends, it is__________________ , and less electronegative than tellurium or arsenic. A. A gray allotrope of arsenic D. A metallic antimony B. Has four allotropes E. More electronegative than tin or bismuth C. In the Nitrogen group F. None of the Above 263. Antimony is stable in air at room temperature, but reacts with oxygen if heated to form antimony trioxide, Sb2O3. Antimony is a silvery, lustrous gray metal that has a Mohs scale hardness of 3. Therefore, pure antimony is______________________________: coins made of antimony were issued in China's Guizhou province in 1931, but because of their rapid wear, their minting was discontinued. Antimony is resistant to attack by acids. A. High chemical reactivity D. A metallic antimony B. Analytical methods E. Not used to make hard objects C. High chemical reactivity F. None of the Above 45 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 264. Four allotropes of antimony are known, a stable metallic form and_______________, explosive, black and yellow. A. Gray D. Liquid B. Three metastable forms E. Its high chemical reactivity C. In the Nitrogen group F. None of the Above 265. Metallic antimony is a brittle, silver-white shiny metal. When molten antimony is slowly cooled, metallic antimony crystallizes_________________ , isomorphic with that of the gray allotrope of arsenic. A. In a trigonal cell D. Metallic B. Four allotropes E. Its high chemical reactivity C. Nitrogen group (group 15) F. None of the Above 266. A rare explosive form of antimony can be formed from the electrolysis of antimony (III) trichloride. When scratched with a sharp implement, an exothermic reaction occurs and white fumes are given off as metallic antimony is formed; when rubbed with a pestle in a mortar, ________________. A. A strong detonation occurs D. An exothermic reaction occurs B. Safe detonation occurs E. Its high chemical reactivity C. Double-layer F. None of the Above 267. Black antimony is formed upon rapid cooling of vapor derived from metallic antimony. It has the same crystal structure as red phosphorus and black arsenic; it oxidizes in air and may ignite spontaneously. At 100 °C, it gradually transforms into the stable form. The yellow allotrope of antimony is the most unstable. It has only been generated by oxidation of stibine (SbH 3) at −90 °C. Above this temperature and in ambient light, this metastable allotrope transforms____________. A. Hardness and resistance to corrosion D. An exothermic reaction occurs B. Into the more stable black allotrope E. Its high chemical reactivity C. Double-layer F. None of the Above 268. Metallic antimony adopts a layered structure (space group R3m No. 166) in which layers consist of fused ruffled six-membered rings. The nearest and next-nearest neighbors form a distorted octahedral complex, with the three atoms in the same double-layer being slightly closer than the three atoms in the next. This relatively close packing leads to a high density of 6.697 g/cm 3, but the weak bonding between the layers leads to the____________________. A. Hardness and resistance to corrosion D. Low hardness and brittleness of antimony B. Safety E. Its high chemical reactivity C. Double-layer F. None of the Above Asbestos - Inorganic Contaminant 7 MFL 269. The MCLG for asbestos is 7________________. EPA has set this level of protection based on the best available science to prevent potential health problems. A. MCLG D. Emergency Planning and Community Right to Know Act (EPCRA) B. MCLs E. EPA C. MFL F. None of the Above 270. EPA has set an enforceable regulation for asbestos, called a maximum contaminant level (MCL), at 7 MFL. MCLs are set as close to the health goals as possible, considering cost, benefits and the ability of public water systems to detect and remove contaminants using suitable treatment technologies. In this case, the_______________, because analytical methods or treatment technology do not pose any limitation. A. MCLG D. Emergency Planning and Community Right to Know Act (EPCRA) B. MCL equals the MCLG E. EPA C. MFL F. None of the Above 46 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 271. The Phase II Rule, the regulation for asbestos, became effective in 1992. The Safe Drinking Water Act requires EPA to periodically review the national primary drinking water regulation for each contaminant and revise the regulation, if appropriate. EPA reviewed asbestos as part of the Six Year Review and determined that the 7 MFL MCLG and ____________ for asbestos are still protective of human health. A. MCLG D. Emergency Planning and Community Right to Know Act (EPCRA) B. MCL equals the MCLG E. 7 MFL MCL C. MFL F. None of the Above Barium - Inorganic Contaminant 2 mg/L MCL 272. In 1974, Congress passed the________________ . This law requires EPA to determine the level of contaminants in drinking water at which no adverse health effects are likely to occur. These non-enforceable health goals, based solely on possible health risks and exposure over a lifetime with an adequate margin of safety, are called maximum contaminant level goals (MCLG). Contaminants are any physical, chemical, biological or radiological substances or matter in water. A. MCLG D. Emergency Planning and Community Right to Know Act (EPCRA) B. Phase IIB Rule E. EPA C. Safe Drinking Water Act F. None of the Above 273. The MCLG for barium is 2 mg/L or 2 ppm. EPA has set this level of protection based on the best available science to prevent potential health problems. EPA has set an enforceable regulation for barium, called a maximum contaminant level (MCL), at______________. A. MCLG D. Emergency Planning and Community Right to Know Act (EPCRA) B. MCL equals the MCLG E. 2 mg/L or 2 ppm C. MFL F. None of the Above 274. MCLs are set as close to the health goals as possible, considering cost, benefits and the ability of public water systems to detect and remove contaminants using suitable treatment technologies. In this case, the _______________, because analytical methods or treatment technology do not pose any limitation. A. MCLG D. SDWA B. MCL equals the MCLG E. 2 mg/L or 2 ppm C. EPA F. None of the Above 275. The _________________, the regulation for barium, became effective in 1993. The Safe Drinking Water Act requires EPA to periodically review the national primary drinking water regulation for each contaminant and revise the regulation, if appropriate. EPA reviewed barium as part of the Six Year Review and determined that the 2 mg/L or 2 ppm MCLG and 2 mg/L or 2 ppm MCL for barium are still protective of human health. A. MCLG D. Emergency Planning and Community Right to Know Act (EPCRA) B. Phase IIB Rule E. EPA C. Safe Drinking Water Act F. None of the Above 276. The major sources of barium in drinking water are discharge of drilling wastes; ________________ ; and erosion of natural deposits. A. Discharge from metal refineries D. Soluble barium compounds B. Barium E. Its high chemical reactivity C. Barium carbonate, BaCO3 F. None of the Above 277. A federal law called the _______________________ requires facilities in certain industries, which manufacture, process, or use significant amounts of toxic chemicals, to report annually on their releases of these chemicals. For more information on the uses and releases of chemicals in your state, contact the Community Right-to-Know Hotline: (800) 424-9346. A. MCLG Rule D. Emergency Planning and Community Right to Know Act (EPCRA) B. Phase IIB Rule E. EPA C. Safe Drinking Water Act F. None of the Above 47 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 278. When routine monitoring indicates that barium levels are above the MCL, your water supplier must take steps to reduce the amount of barium so that it is below that level. Water suppliers must notify their customers as soon as practical, but no later than 30 days after the system learns of the violation.______________, such as providing alternative drinking water supplies, may be required to prevent serious risks to public health. A. MCLG D. Additional actions B. MCL equals the MCLG E. 2 mg/L or 2 ppm C. MFL F. None of the Above Barium Explained 279. Barium is a ____________with symbol Ba and atomic number 56. It is the fifth element in Group 2, a soft silvery metallic alkaline earth metal. A. Erosion of natural deposits D. Soluble compounds B. Chemical element E. Highly reactive chemical C. Carbonate, BaCO3 F. None of the Above 280. Because of its high chemical reactivity barium is never found in nature as a free element. Its hydroxide was known in pre-modern history as______________; this substance does not occur as a mineral, but can be prepared by heating barium carbonate. A. A natural deposit D. A soluble compound B. Baryta E. Highly reactive chemical C. Barium carbonate, BaCO3 F. None of the Above 281. The most common naturally occurring minerals of barium are barite (barium sulfate, BaSO 4) and witherite (___________________), both being insoluble in water. Barium's name originates from the alchemical derivative "baryta", which itself comes from Greek βαρύς (barys), meaning "heavy." A. A natural deposit D. A soluble compound B. Baryta E. Highly reactive chemical C. Barium carbonate, BaCO3 F. None of the Above 282. _________________ was identified as a new element in 1774, but not reduced to a metal until 1808, shortly after electrolytic isolation techniques became available. A. Beryllium D. Soluble barium compound B. Barium E. Its high chemical reactivity C. Barium carbonate, BaCO3 F. None of the Above 283. _________________ has only a few industrial applications. The metal has been historically used to scavenge air in vacuum tubes. It is a component of YBCO (high-temperature superconductors) and electroceramics, and is added to steel and cast iron to reduce the size of carbon grains within the microstructure of the metal. A. Beryllium D. Soluble barium compound B. Barium E. Its high chemical reactivity C. Barium carbonate, BaCO3 F. None of the Above 284. __________________ are added to fireworks to impart a green color. For instance, barium sulfate is used as an insoluble heavy additive to oil well drilling fluid, and in purer form, as X-ray radiocontrast agents for imaging the human gastrointestinal tract. A. Beryllium D. Soluble barium compound B. Barium E. Barium compounds C. Barium carbonate, BaCO3 F. None of the Above 285. ______________________ are poisonous due to release of the soluble barium ion, and therefore have been used as rodenticides. A. Beryllium D. Soluble barium compounds B. Barium E. Its high chemical reactivity C. Barium carbonate, BaCO3 F. None of the Above 48 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 Beryllium - Inorganic Contaminant 0.004 mg/L MCL 286. In 1974, Congress passed the Safe Drinking Water Act. This law requires EPA to determine the level of contaminants in drinking water at which no adverse health effects are likely to occur. These non-enforceable health goals, based solely on possible health risks and exposure over a lifetime with an adequate margin of safety, are called________________________. Contaminants are any physical, chemical, biological or radiological substances or matter in water. A. MCLG D. SDWA B. MCL equals the MCLG E. Maximum contaminant level goals (MCLG) C. EPA F. None of the Above 287. The ___________for beryllium is 0.004 mg/L or 4 ppb. EPA has set this level of protection based on the best available science to prevent potential health problems. EPA has set an enforceable regulation for beryllium, called a maximum contaminant level (MCL), at 0.004 mg/L or 4 ppb. A. MCLG D. SDWA B. MCL equals the MCLG E. MCLG C. EPA F. None of the Above 288. MCLs are set as close to the health goals as possible, considering cost, benefits and the ability of public water systems to detect and remove contaminants using suitable treatment technologies. In this case, the _____________ equals the MCLG, because analytical methods or treatment technology do not pose any limitation. A. MCLG D. SDWA B. MCL E. 2 mg/L or 2 ppm C. EPA F. None of the Above 289. The_____________, the regulation for beryllium, became effective in 1994. The Safe Drinking Water Act requires EPA to periodically review the national primary drinking water regulation for each contaminant and revise the regulation, if appropriate. EPA reviewed beryllium as part of the Six Year Review and determined that the 0.004 mg/L or 4 ppb MCLG and 0.004 mg/L or 4 ppb MCL for beryllium are still protective of human health. A. Phase V Rule D. Emergency Planning and Community Right to Know Act (EPCRA) B. MCL E. EPA C. Group 2 F. None of the Above How does Beryllium get into my Drinking Water? 290. Beryllium naturally enters surface water and ground water through the weathering of rocks and soils or from industrial wastewater discharges. The major source of environmental releases from ____________ are coal and fuel oil combustion. A. Divalent elements D. Hardness and resistance to corrosion B. Brittle alkaline earth metal E. Waste batteries and paints C. Industrial waste disposal practices F. None of the Above 291. A federal law called the __________________ requires facilities in certain industries, which manufacture, process, or use significant amounts of toxic chemicals, to report annually on their releases of these chemicals. For more information on the uses and releases of chemicals in your state, contact the Community Right-to-Know Hotline: (800) 424-9346. A. Phase V Rule D. Emergency Planning and Community Right to Know Act (EPCRA) B. MCL E. EPA C. OSHA F. None of the Above How will I know if Beryllium is in my Drinking Water? 292. When routine monitoring indicates that beryllium levels are above the ______________, your water supplier must take steps to reduce the amount of beryllium so that it is below that level. A. MCLG D. SDWA B. MCL equals the MCLG E. 2 mg/L or 2 ppm C. EPA F. None of the Above 49 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 Beryllium Explained 293. Beryllium is the chemical element with the symbol Be and atomic number 4. Because any beryllium synthesized in stars is short-lived, _________________ in both the universe and in the crust of the Earth. It is a divalent element which occurs naturally only in combination with other elements in minerals. A. It is a divalent element D. Hard and resistant to corrosion B. Brittle alkaline earth metal E. It is a relatively rare element C. Is a relatively abundant element F. None of the Above 294. Notable gemstones which contain beryllium include beryl (aquamarine, emerald) and chrysoberyl. As a free element it is______________, lightweight and brittle alkaline earth metal. A. A divalent element D. Hard and resistant to corrosion B. A steel-gray, strong E. Shiny C. Coal based F. None of the Above 295. Beryllium increases _______________ when alloyed to aluminum, cobalt, copper (notably beryllium copper), iron and nickel. In structural applications, high flexural rigidity, thermal stability, thermal conductivity and low density (1.85 times that of water) make beryllium a quality aerospace material for high-speed aircraft, missiles, space vehicles and communication satellites. A. A divalent element D. Hard and resistance to corrosion B. A steel-gray, strong E. Shiny C. Coal based F. None of the Above Cadmium - Inorganic Contaminant 0.005 mg/L MCL 296. In 1974, Congress passed the_______________. This law requires EPA to determine the level of contaminants in drinking water at which no adverse health effects are likely to occur. These nonenforceable health goals, based solely on possible health risks and exposure over a lifetime with an adequate margin of safety, are called maximum contaminant level goals (MCLG). Contaminants are any physical, chemical, biological or radiological substances or matter in water. A. MCLG D. Emergency Planning and Community Right to Know Act B. CWA E. EPA C. Safe Drinking Water Act F. None of the Above 297. The MCLG for cadmium is______________. EPA has set this level of protection based on the best available science to prevent potential health problems. A. 4.0 D. .015 B. .002 E. 0.005 mg/L or 5 ppb C. 1.3 F. None of the Above 298. EPA has set an enforceable regulation for cadmium, called a maximum contaminant level (MCL), at __________________ are set as close to the health goals as possible, considering cost, benefits and the ability of public water systems to detect and remove contaminants using suitable treatment technologies. In this case, the MCL equals the MCLG, because analytical methods or treatment technology do not pose any limitation. A. 4.0 D. .015 B. .002 E. 0.005 mg/L or 5 ppb C. 1.3 F. None of the Above 299. The Phase II Rule, the regulation for cadmium, became effective in 1992. The Safe Drinking Water Act requires EPA to periodically review the national primary drinking water regulation for each contaminant and revise the regulation, if appropriate. EPA reviewed cadmium as part of the Six Year Review and determined that the __________________ MCLG and 0.005 mg/L or 5 ppb MCL for cadmium are still protective of human health. A. 4.0 D. .015 B. .002 E. 0.005 mg/L or 5 ppb C. 1.3 F. None of the Above 50 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 How does cadmium get into my drinking water? 300. The major sources of cadmium in drinking water are corrosion of galvanized pipes; erosion of natural deposits;______________________; runoff from waste batteries and paints. A. It is a divalent element D. It may burn and release toxic fumes B. Brittle alkaline earth metal E. Discharge from metal refineries C. Coal and fuel oil combustion F. None of the Above 301. A federal law called the ______________ requires facilities in certain industries, which manufacture, process, or use significant amounts of toxic chemicals, to report annually on their releases of these chemicals. For more information on the uses and releases of chemicals in your state, contact the Community Right-to-Know Hotline: (800) 424-9346. A. MCLG D. Emergency Planning and Community Right to Know Act B. CWA E. EPA C. Safe Drinking Water Act F. None of the Above How will I know if cadmium is in my drinking water? 302. When routine monitoring indicates that cadmium levels are above the _____________, your water supplier must take steps to reduce the amount of cadmium so that it is below that level. Water suppliers must notify their customers as soon as practical, but no later than 30 days after the system learns of the violation. Additional actions, such as providing alternative drinking water supplies, may be required to prevent serious risks to public health. If your water comes from a household well, check with your health department or local water systems that use ground water for information on contaminants of concern in your area. A. MCLG D. SDWA limit B. MCL E. 2 mg/L or 2 ppm C. EPA standard F. None of the Above How will cadmium be removed from my drinking water? 303. The following treatment method(s) have proven to be effective for removing cadmium to below _________________: coagulation/filtration, ion exchange, lime softening, and reverse osmosis. A. 4.0 D. .015 B. .002 E. 0.005 mg/L or 5 ppb C. 1.3 F. None of the Above Characteristics Physical Properties 304. Cadmium is a soft, malleable, ductile, bluish-white divalent metal. It is similar in many respects to zinc but forms complex compounds. Unlike other metals, cadmium is resistant to corrosion and as a result it is used as a protective layer when deposited on other metals. As a bulk metal, cadmium is_______________; however, in its powdered form it may burn and release toxic fumes. A. Insoluble in water and is not flammable D. It may burn and release toxic fumes B. Is in making steel and other alloys E. Reduces the amount of cadmium sulfate C. Normal industrial waste disposal practices F. None of the Above Chromium- Inorganic Contaminant 0.1 mg/L MCL 305. The Safe Drinking Water Act requires ___________________ to determine the level of contaminants in drinking water at which no adverse health effects are likely to occur. These nonenforceable health goals, based on possible health risks from exposure over a lifetime, are called maximum contaminant level goals (MCLG). A. MCLG D. Emergency Planning and Community Right to Know Act (EPCRA) B. MCL E. EPA C. Group 2 F. None of the Above 51 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 306. EPA sets enforceable standards for drinking water contaminants based on the best available science to prevent potential health problems. In most cases, the enforceable standard is known as a maximum contaminant level (MCL), the maximum permissible level of a contaminant in water which is delivered to any user of a public water system. ___________ are set as close to the health goals as possible after considering costs, benefits and the ability of public water systems to detect and remove contaminants using suitable treatment technologies. A. MCLG D. Emergency Planning and Community Right to Know Act (EPCRA) B. MCLs E. EPA C. Group 2 F. None of the Above 307. Chromium is___________________. Chromium is found naturally in rocks, plants, soil and volcanic dust, humans and animals. The most common forms of chromium that occur in natural waters in the environment are trivalent chromium (chromium-3), and hexavalent chromium (chromium-6). A. An odorless and tasteless metallic element D. Flammable B. Used for making steel and other alloys E. Fun to play with C. Normally found in industrial waste disposal F. None of the Above 308. Chromium-3 is an essential human dietary element and ___________________. A. An odorless and tasteless metallic element D. Flammable B. Used for making steel and other alloys E. Fun to play with C. Normally found in industrial waste disposal F. None of the Above 309. Chromium-6 occurs naturally in the environment from the erosion of natural chromium deposits but it can also be produced by________________. There are demonstrated instances of chromium being released to the environment by leakage, poor storage, or inadequate industrial waste disposal practices. A. Reverse osmosis D. Burning and releasing toxic fumes B. Making steel and other alloys E. Chemistry C. Industrial processes F. None of the Above What are Chromium's Health Effects? 310. Chromium-3 is a nutritionally essential element in humans and is often added to vitamins as a dietary supplement. Chromium-3 has relatively low toxicity and would be a concern in drinking water only at very high levels of contamination; Chromium-6 is more toxic and poses potential health risks. People who use water containing total chromium in excess of the ___________________over many years could experience allergic dermatitis. A. MCLG D. Rule B. MCL E. Standard C. Limit F. None of the Above 311. EPA proposed to classify chromium-6 as likely to be carcinogenic to humans when ingested. The Agency continues to work towards completing the human health assessment and making a final determination about the carcinogenicity of chromium-6. When the assessment is completed, __________ will determine whether the drinking water standard for total chromium needs to be revised. A. MCLG D. Emergency Planning and Community Right to Know Act (EPCRA) B. OSHA E. EPA C. CWA F. None of the Above 52 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 What are EPA's drinking water regulations for Chromium? 312. The ________________requires EPA to determine the level of contaminants in drinking water at which no adverse health effects are likely to occur. These non-enforceable health goals, based on possible health risks from exposure over a lifetime are called maximum contaminant level goals (MCLG). A. Safe Drinking Water Act D. Emergency Planning and Community Right to Know Act (EPCRA) B. OSHA E. EPA C. CWA F. None of the Above 313. The _______________for total chromium is 0.1 mg/L or 100 parts per billion (ppb). EPA has set this level of protection based on the best available science at the time the rule was promulgated. EPA has set an enforceable regulation for total chromium, called a maximum contaminant level (MCL), at 0.1 mg/L or 100 ppb. A. MCLG D. Rule B. MCL E. Standard C. Limit F. None of the Above 314. MCLs are set as close to the health goals as possible, considering cost, benefits and the ability of public water systems to detect and remove contaminants using suitable treatment technologies. In this case, the________________, because analytical methods or treatment technology do not pose any limitation. A. MCLG D. MCL equals the MCLG B. MCL E. Standard C. Limit F. None of the Above Chromium Explained Chromium Description 315. Chromium is a chemical element which has the symbol Cr and atomic number 24. It is the first element in _________________. A. Group 6 D. The roasting and leaching processes B. Trivalent chromium (Cr(III)) ion E. Forming stainless steel C. Toxic chromium classification F. None of the Above 316. Chromium metal and ferrochromium alloy are commercially produced from chromite by silicothermic or aluminothermic reactions, or by __________________. A. Adding copper D. Roasting and leaching processes B. Adding trivalent chromium E. Adding metallic chromium to form stainless steel C. Adding Aluminum F. None of the Above 317. Chromium metal has proven of high value due to_______________. A major development was the discovery that steel could be made highly resistant to corrosion and discoloration by adding metallic chromium to form stainless steel. A. Group 6 treatments D. Roasting and leaching processes B. Adding trivalent chromium E. Its high corrosion resistance and hardness C. Adding Aluminum F. None of the Above 318. _________________, along with chrome plating (electroplating with chromium) currently comprise 85% of the commercial use for the element, with applications for chromium compounds forming the remainder. A. Group 6 treatments D. Roasting and leaching processes B. Adding trivalent chromium E. Its high corrosion resistance and hardness C. Adding Aluminum F. None of the Above 53 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 319. Trivalent chromium (Cr(III)) ion is possibly required in trace amounts for sugar and lipid metabolism, although the issue remains in debate. In larger amounts and in different forms, chromium can be_________________________. A. Toxic and carcinogenic D. Part of the leaching processes B. Trivalent chromium (Cr(III)) ion E. Metallic chromium C. Toxic chromium F. None of the Above 320. The most prominent example of toxic chromium is______________. Abandoned chromium production sites often require environmental cleanup. A. Stainless steel D. Hexavalent chromium (Cr(VI)) B. Trivalent chromium (Cr(III)) ion E. Metallic chromium C. Toxic chromium F. None of the Above Copper - Inorganic Contaminant 1.3 mg/L MCLG What are Copper’s Health Effects? 321. Some people who drink water containing copper in excess of the ________________may, with short term exposure, experience gastrointestinal distress, and with long-term exposure may experience liver or kidney damage. People with Wilson's Disease should consult their personal doctor if the amount of copper in their water exceeds the action level. A. MCLG D. Standard B. MCL E. Action level C. Limit F. None of the Above What are EPA’s Drinking Water Regulations for Copper? 322. In 1974, Congress passed the Safe Drinking Water Act. This law requires EPA to determine the level of contaminants in drinking water at which no adverse health effects are likely to occur. These non-enforceable health goals, based solely on possible health risks and exposure over a lifetime with an adequate margin of safety, are called_______________. Contaminants are any physical, chemical, biological or radiological substances or matter in water. A. MCLG D. Standard B. MCL E. Action level C. Limit F. None of the Above 323. The _________________for copper is 1.3 mg/L or 1.3 ppm. EPA has set this level of protection based on the best available science to prevent potential health problems. A. MCLG D. Standard B. MCL E. Action level C. Limit F. None of the Above 324. For most contaminants, EPA sets an enforceable regulation called a maximum contaminant level (MCL) based on the MCLG. ___________as feasible, considering cost, benefits and the ability of public water systems to detect and remove contaminants using suitable treatment technologies. However, because copper contamination of drinking water often results from corrosion of the plumbing materials belonging to water system customers, EPA established a treatment technique rather than an MCL for copper. A. MCLG D. Standard B. MCL E. MCLs are set as close to the MCLGs C. Limit F. None of the Above 325. The regulation also requires systems to collect tap samples from sites served by the system that are more likely to have plumbing materials containing lead. If more than 10 percent of tap water samples exceed the copper action level of 1.3____________, water systems must take additional steps to reduce corrosiveness. A. MCLG D. Milligrams per Liter (mg/L) B. MCL E. Action level C. Limit F. None of the Above 54 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 326. _________________ promulgated the Lead and Copper Rule in 1991, and revised the regulation in 2000 and in 2007. States may set a more stringent regulation for copper in drinking water than EPA. A. CWA D. Emergency Planning and Community Right to Know Act (EPCRA) B. SDWA E. EPA C. OSHA F. None of the Above Copper Explained 327. Pure copper is _____________; a freshly exposed surface has a reddish-orange color. It is used as a conductor of heat and electricity, a building material, and a constituent of various metal alloys. A. Known also as Lead D. Related to turquoise B. Soft and malleable E. A liquid like Mercury C. A carbon-nitrogen chemical F. None of the Above 328. Its compounds are commonly encountered as ___________, which often impart blue or green colors to minerals such as turquoise and have been widely used historically as pigments. A. Copper (II) salts D. A mixture of gold and copper B. Element E. Salts C. Carbon-nitrogen chemical F. None of the Above Cyanide - Inorganic Contaminant 0.2 mg/L MCL 329. Cyanide is a carbon-nitrogen chemical unit which combines with many_____________. A. Copper (II) salts D. Nitrogen atoms B. Organic and inorganic compounds E. Salts C. Carbon-nitrogen chemicals F. None of the Above Uses for Cyanide. 330. The most commonly used form, __________________, is mainly used to make compounds and other synthetic fibers and resins. A. Copper (II) salts D. The nitrogen atom B. Cyanide (II) E. Salts of the anion CN− C. Carbon-nitrogen chemical F. None of the Above What are Cyanide's Health Effects? 331. Some people who drink water containing cyanide well in excess of the maximum contaminant level (MCL) for many years could experience nerve damage or problems with their thyroid. This health effects language is not intended to catalog all possible health effects for cyanide. Rather, it is intended to inform consumers of some of the possible health effects associated with cyanide in drinking water when the ___________ was finalized. A. MCLG D. Emergency Planning and Community Right to Know Act (EPCRA) B. MCL E. EPA rule C. Rule F. None of the Above What are EPA's Drinking Water Regulations for Cyanide? 332. In 1974, Congress passed the Safe Drinking Water Act. This law requires EPA to determine the level of contaminants in drinking water at which no adverse health effects are likely to occur. These non-enforceable health goals, based solely on possible health risks and exposure over a lifetime with an adequate margin of safety, are called________________. A. MCLG D. Standard B. MCL E. MCLs are set as close to the MCLGs C. Limit F. None of the Above 55 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 333. ________________are any physical, chemical, biological or radiological substances or matter in water. A. Naked contaminants D. Solutions of inorganic contaminants B. Halides E. Cyanides C. Contaminants F. None of the Above 334. The ___________ for cyanide is 0.2 mg/L or 200 ppb. EPA has set this level of protection based on the best available science to prevent potential health problems. EPA has set an enforceable regulation for cyanide, called a maximum contaminant level (MCL), at 0.2 mg/L or 200 ppb. A. MCLG D. Standard B. MCL E. MCLs are set as close to the MCLGs C. Limit F. None of the Above 335. __________________, considering cost, benefits and the ability of public water systems to detect and remove contaminants using suitable treatment technologies. In this case, the MCL equals the MCLG, because analytical methods or treatment technology do not pose any limitation. A. MCLG D. Standard B. MCL E. MCLs are set as close to the health goals as possible C. Limit F. None of the Above 336. The Phase V Rule, the regulation for cyanide, became effective in 1994. The Safe Drinking Water Act requires _____________ to periodically review the national primary drinking water regulation for each contaminant and revise the regulation, if appropriate. EPA reviewed cyanide as part of the Six Year Review and determined that the 0.2 mg/L or 200 ppb MCLG and 0.2 mg/L or 200 ppb MCL for cyanide are still protective of human health. A. MCLG D. Standard B. MCL E. MCLs are set as close to the health goals as possible C. Limit F. None of the Above Cyanide Explained 337. A cyanide is a chemical compound that contains the _______________, which consists of a carbon atom triple-bonded to a nitrogen atom. A. Naked contaminants D. Solutions of inorganic contaminants B. Halides E. Cyanides C. Contaminants F. None of the Above 338. Cyanides most commonly refer to ______________which is isoelectronic with carbon monoxide and with molecular nitrogen. Most cyanides are highly toxic. A. Cyanide salts D. Solutions of salts of the anion CN−, − B. Salts of the anion CN , E. Cyanides solutions C. Carbon-nitrogen chemical F. None of the Above Fluoride - Inorganic Contaminant 4.0 mg/L MCL What are EPA's Drinking Water Regulations for Fluoride? 339. In 1974, Congress passed the Safe Drinking Water Act. This law requires EPA to determine the level of contaminants in drinking water at which no adverse health effects are likely to occur. These non-enforceable health goals, based solely on possible health risks and exposure over a lifetime with an adequate margin of safety, are called maximum contaminant level goals (MCLG). __________ are any physical, chemical, biological or radiological substances or matter in water. A. MCLG D. Standard B. MCL E. MCLs are set as close to the health goals as possible C. Limit F. None of the Above 56 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 340. The _____________ for fluoride is 4.0 mg/L or 4.0 ppm. EPA has set this level of protection based on the best available science to prevent potential health problems. EPA has set an enforceable regulation for fluoride, called a maximum contaminant level (MCL), at 4.0 mg/L or 4.0 ppm. A. MCLG D. Standard B. MCL E. MCLs are set as close to the health goals as possible C. Limit F. None of the Above 341. MCLs are set as close to the health goals as possible, considering cost, benefits and the ability of public water systems to detect and remove contaminants using suitable treatment technologies. In this case, the_____________, because analytical methods or treatment technology do not pose any limitation. A. MCLG D. Standard B. MCL E. MCL equals the MCLG C. Limit F. None of the Above 342. EPA has also set a ________________for fluoride at 2.0 mg/L or 2.0 ppm. Secondary standards are non-enforceable guidelines regulating contaminants that may cause cosmetic effects (such as skin or tooth discoloration) or aesthetic effects (such as taste, odor, or color) in drinking water. EPA recommends secondary standards to water systems but does not require systems to comply. However, states may choose to adopt them as enforceable standards. A. MCLG D. Secondary standard (SMCL) B. MCL E. MCL equals the MCLG C. Limit F. None of the Above 343. Tooth discoloration and/or pitting is caused by excess fluoride exposures during the formative period prior to eruption of the teeth in children. The secondary standard of 2.0 mg/L is intended as a guideline for an upper bound level in areas which have high levels of naturally occurring fluoride. The level of the ____________ was set based upon a balancing of the beneficial effects of protection from tooth decay and the undesirable effects of excessive exposures leading to discoloration. A. MCLG D. Secondary standard (SMCL) B. MCL E. MCL equals the MCLG C. Limit F. None of the Above 344. _____________ is voluntarily added to some drinking water systems as a public health measure for reducing the incidence of cavities among the treated population. A. Naked fluoride D. Solutions of inorganic fluorides B. Halides E. Fluorite and fluorapatite C. Fluoride F. None of the Above Fluoride Explained 345. Fluoride is the anion F−, the reduced form of fluorine when as an ion and when bonded to another element. Inorganic fluorine containing compounds are called fluorides. Fluoride, like other halides, is a monovalent ion (−1 charge). Its compounds often have properties that are distinct relative to other halides. Structurally, and to some extent chemically, the _________resembles the hydroxide ion. A. Naked fluoride D. Solutions of inorganic fluorides B. Halides E. Fluoride ion C. Fluoride F. None of the Above 57 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 Occurrence 346. Solutions of inorganic fluorides in water contain F − and bifluoride HF−2. Few inorganic fluorides are soluble in water without undergoing significant hydrolysis. In terms of its reactivity, fluoride differs significantly from chloride and other halides, and is more strongly solvated due to its smaller radius/charge ratio. Its closest chemical relative is hydroxide. When relatively unsolvated, fluoride anions are called "_____________". A. Naked D. Solutions of inorganic fluorides B. Halides E. Fluorite and fluorapatite C. Fluoride F. None of the Above 347. _______________ is a very strong lewis base. The presence of fluoride and its compounds can be detected by F NMR spectroscopy. A. Naked fluoride D. Solutions of inorganic fluorides B. Halides E. Fluorite and fluorapatite C. Fluoride F. None of the Above Natural Occurrence 348. ________________are fluorapatite. A. Naked fluoride D. B. Halides E. C. Many fluoride minerals F. known, but of paramount commercial importance are fluorite and Solutions of inorganic fluorides Fluorite and fluorapatite None of the Above 349. ___________ is usually found naturally in low concentration in drinking water and foods. The concentration in seawater averages 1.3 parts per million (ppm). A. Naked fluoride D. Solutions of inorganic fluorides B. Halides E. Fluorite and fluorapatite C. Fluoride F. None of the Above 350. Fresh water supplies generally contain between 0.01–0.3 ppm, whereas the ocean contains between 1.2 and 1.5 ppm. In some locations, the fresh water contains dangerously high levels of _______________ , leading to serious health problems. A. Naked fluoride D. Solutions of inorganic fluorides B. Halides E. Fluorite and fluorapatite C. Fluoride F. None of the Above Mercury - Inorganic Contaminant 0.002 mg/L MCL 351. ________________regulates mercury in drinking water to protect public health. Mercury may cause health problems if present in public or private water supplies in amounts greater than the drinking water standard set by EPA. A. MCLG D. Emergency Planning and Community Right to Know Act (EPCRA) B. MCLs E. EPA C. SDWA F. None of the Above What is Mercury? 352. Mercury is a liquid metal found in natural deposits such as ores containing_____________ . A. Aluminum D. Mercury-aluminum amalgam B. Ultraviolet light E. Other elements C. Cinnabar (mercuric sulfide) F. None of the Above Uses for Mercury. 353. Electrical products such as dry-cell batteries, fluorescent light bulbs, switches, and other control equipment account for 50 percent of ______________used. A. Aluminum D. Mercury-aluminum amalgams B. Mercury E. Lead C. Cinnabar (mercuric sulfide) F. None of the Above 58 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 What are Mercury's Health Effects? 354. Some people who drink water containing mercury well in excess of the maximum contaminant level (MCL) for many years could experience kidney damage. This health effects language is not intended to catalog all possible _____________for mercury. Rather, it is intended to inform consumers of some of the possible health effects associated with mercury in drinking water when the rule was finalized. A. MCLG D. Standards B. MCLs E. EPA C. Health effects F. None of the Above What are EPA's Drinking Water Regulations for Mercury? 355. In 1974, Congress passed the_______________. This law requires EPA to determine the level of contaminants in drinking water at which no adverse health effects are likely to occur. These nonenforceable health goals, based solely on possible health risks and exposure over a lifetime with an adequate margin of safety, are called maximum contaminant level goals (MCLG). Contaminants are any physical, chemical, biological or radiological substances or matter in water. A. MCLG D. Secondary standard (SMCL) B. MCL E. Safe Drinking Water Act C. Limit F. None of the Above 356. The MCLG for mercury is 0.002 mg/L or 2 ppb. EPA has set this level of protection based on the best available science to prevent potential health problems. EPA has set_____________, called a maximum contaminant level (MCL), at 0.002 mg/L or 2 ppb. A. MCLG D. Secondary standard (SMCL) B. MCL E. An enforceable regulation for mercury C. Limit F. None of the Above 357. ________________, considering cost, benefits and the ability of public water systems to detect and remove contaminants using suitable treatment technologies. In this case, the MCL equals the MCLG, because analytical methods or treatment technology do not pose any limitation. A. MCLG D. MCLs are set as close to the health goals as possible B. MCL E. MCL equals the MCLG C. Limit F. None of the Above 358. _________________, the regulation for mercury, became effective in 1992. The Safe Drinking Water Act requires EPA to periodically review the national primary drinking water regulation for each contaminant and revise the regulation, if appropriate. EPA reviewed mercury as part of the Six Year Review and determined that the 0.002 mg/L or 2 ppb MCLG and 0.002 mg/L or 2 ppb MCL for mercury are still protective of human health. A. MCLG D. Secondary standard (SMCL) B. MCL E. The Phase II Rule C. Limit F. None of the Above How will I know if Mercury is in my Drinking Water? 359. When routine monitoring indicates that mercury levels are above the ____________, your water supplier must take steps to reduce the amount of mercury so that it is below that level. Water suppliers must notify their customers as soon as practical, but no later than 30 days after the system learns of the violation. Additional actions, such as providing alternative drinking water supplies, may be required to prevent serious risks to public health. A. MCLG D. MCLs are set as close to the health goals as possible B. MCL E. MCL equals the MCLG C. Limit F. None of the Above . 59 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 How will Mercury be removed from my Drinking Water? 360. The following treatment method(s) have proven to be effective for removing mercury to below 0.002 mg/L or 2 ppb: coagulation/filtration, granular activated carbon, _____________, and reverse osmosis. A. A carbon filter D. Lime softening B. Backwash carbon E. Point of use C. Activated carbon F. None of the Above Mercury Explained 361. Mercury occurs in deposits throughout the world mostly as cinnabar (mercuric sulfide). The red pigment vermilion is mostly obtained by__________________. A. Aluminum D. Mercury-aluminum amalgam B. Water-soluble forms E. Reduction from cinnabar C. Cinnabar (mercuric sulfide) F. None of the Above 362. Cinnabar is highly toxic by ingestion or inhalation of the dust. Mercury poisoning can also result from exposure to ______________of mercury (such as mercuric chloride or methylmercury), inhalation of mercury vapor, or eating seafood contaminated with mercury. A. Aluminum D. Mercury-aluminum amalgam B. Water-soluble forms E. Reduction from cinnabar C. Cinnabar (mercuric sulfide) F. None of the Above 363. Mercury is used in thermometers, barometers, manometers, sphygmomanometers, float valves, mercury switches, and other devices though concerns about the element's toxicity have led to mercury thermometers and sphygmomanometers being largely phased out in clinical environments in favor of alcohol-filled,__________. A. Bottles D. Galinstan-filled, digital, or thermistor-based instruments B. Ultraviolet light E. Sphygmomanometers C. Machinery F. None of the Above 364. It remains in use in scientific research applications and in amalgam material for dental restoration. It is used in lighting: electricity passed through mercury vapor in a phosphor tube produces short-wave ultraviolet light which then causes the _________to fluoresce, making visible light. A. Aluminum D. Mercury-aluminum B. Ultraviolet light E. Phosphor C. Cinnabar (mercuric sulfide) F. None of the Above Amalgams 365. Mercury dissolves to form amalgams with gold, zinc and many other metals. Because iron is an exception, iron flasks have been traditionally used to trade mercury. Other metals that do not form amalgams with mercury include tantalum, tungsten and platinum. __________is a common reducing agent in organic synthesis, and is also used in high-pressure sodium lamps. A. Aluminum amalgam D. Mercury-aluminum amalgam B. Ultraviolet amalgam E. Sodium amalgam C. Cinnabar (mercuric sulfide) F. None of the Above 366. Mercury readily combines with aluminum to form a _______________ when the two pure metals come into contact. A. Aluminum amalgam D. Mercury-aluminum amalgam B. Ultraviolet amalgam E. Sodium amalgam C. Cinnabar (mercuric sulfide) F. None of the Above 60 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 367. Since the amalgam destroys the ______________which protects metallic aluminum from oxidizing in-depth (as in iron rusting), even small amounts of mercury can seriously corrode aluminum. For this reason, mercury is not allowed aboard an aircraft under most circumstances because of the risk of it forming an amalgam with exposed aluminum parts in the aircraft. A. Aluminum amalgam D. Mercury-aluminum amalgam B. Aluminum oxide layer E. Sodium amalgam C. Cinnabar (mercuric sulfide) F. None of the Above Nitrate (Measured as Nitrogen) - Inorganic Contaminant 10 mg/L MCL 368. EPA regulates _____________in drinking water to protect public health. Nitrate may cause health problems if present in public or private water supplies in amounts greater than the drinking water standard set by EPA. A. Nitrates and nitrites D. Nitrates are converted to nitrites B. Nitrate ion E. Various organic and inorganic compounds C. Nitrate F. None of the Above What is Nitrate? 369. Nitrates and nitrites are ________________which combine with various organic and inorganic compounds. A. Nitrogen-oxygen chemical units D. Nitrates are converted to nitrites B. Nitrate ion E. Various organic and inorganic compounds C. Nitrate F. None of the Above Uses for Nitrate. 370. The greatest use of nitrates is as a fertilizer. Once taken into the body, nitrates are converted to _________________. A. Nitrates and nitrites D. Nitrites B. Nitrate ion E. Various organic and inorganic compounds C. Nitrate F. None of the Above What are EPA's Drinking Water Regulations for Nitrate? 371. In 1974, Congress passed the Safe Drinking Water Act. This law requires EPA to determine the level of contaminants in drinking water at which no adverse health effects are likely to occur. These non-enforceable health goals, based solely on possible health risks and exposure over a lifetime with an adequate margin of safety, are called maximum contaminant level goals (MCLG). Contaminants are any ______________________. A. MCLG D. Secondary standard (SMCL) B. MCL E. An enforceable regulation for nitrate C. Limit F. None of the Above 372. The MCLG for nitrate is 10 mg/L or 10 ppm. EPA has set this level of protection based on the best available science to prevent potential health problems. EPA has set an enforceable regulation for nitrate, called a maximum contaminant level (MCL), at 10 mg/L or 10 ppm.____________. A. MCLG D. MCLGs are set as close to the health goals as possible B. MCLs E. MCLs are set as close to the health goals as possible C. Limits F. None of the Above 373. The Phase II Rule, the _____________for nitrate, became effective in 1992. The Safe Drinking Water Act requires EPA to periodically review the national primary drinking water regulation for each contaminant and revise the regulation, if appropriate. EPA reviewed nitrate as part of the Six Year Review and determined that the 10 mg/L or 10 ppm MCLG and 10 mg/L or 10 ppm MCL for nitrate are still protective of human health. A. MCLG D. Regulation B. MCLs E. Standard C. Grouping F. None of the Above 61 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 How does Nitrate get into my Drinking Water? 374. The major sources of nitrates in drinking water are runoff from fertilizer use; leaking from septic tanks, sewage; and erosion of natural deposits. A federal law called the Emergency Planning and Community Right to Know Act (EPCRA) requires facilities in certain industries, which manufacture, process, or use significant amounts of toxic chemicals, to report annually on their releases of these chemicals. For more information on the uses and releases of chemicals in your state, contact the __________________. A. MCLG D. Emergency Planning and Community Right to Know Act (EPCRA) B. Water supplier E. EPA C. Cops F. None of the Above How will I know if Nitrate is in my Drinking Water? 375. When routine monitoring indicates that nitrate levels are above the MCL, ___________must take steps to reduce the amount of nitrate so that it is below that level. Water suppliers must notify their customers as soon as practical, but no later than 24 hours after the system learns of the violation. Additional actions, such as providing alternative drinking water supplies, may be required to prevent serious risks to public health. A. MCLG D. Emergency Planning and Community Right to Know Act (EPCRA) B. Your water supplier E. EPA C. Cops F. None of the Above Nitrate Explained 376. The nitrate ion is a polyatomic ion with the _____________nand a molecular mass of 62.0049 g/mol. A. Nitrates and nitrites D. Molecular formula NO3− B. Nitrate ion E. Various organic and inorganic compounds C. Nitrate F. None of the Above Structure 377. It is the conjugate base of nitric acid, consisting of one central nitrogen atom surrounded by three identically bonded oxygen atoms in a trigonal planar arrangement. The nitrate ion carries a formal charge of -1. This results from a combination formal charge in which each of the three oxygens carries a −2⁄3 charge, whereas the nitrogen carries a +1 charge, all these adding up to formal charge of the_____________________. A. Nitrates and nitrites D. Polyatomic nitrate ion B. Nitrate ion E. Various organic and inorganic compounds C. Nitrate F. None of the Above Nitrite (Measured as Nitrogen) - Inorganic Contaminant 1 mg/L MCL 378. EPA regulates nitrite in drinking water to protect public health. Nitrite may cause health problems if present in public or private water supplies in amounts greater than the drinking water standard set by ________________. A. MCLG D. Emergency Planning and Community Right to Know Act (EPCRA) B. Water supplier E. EPA C. Cops F. None of the Above What is Nitrite? 379. Nitrates and nitrites are ____________which combine with various organic and inorganic compounds. A. Nitrogen-oxygen chemical units D. Nitrates are converted to nitrites B. Nitrate ion E. Various organic and inorganic compounds C. Nitrate F. None of the Above 62 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 Uses for Nitrite. 380. The greatest use of nitrates is as a fertilizer. Once taken into the body, __________ are converted to nitrites. A. Nitrites D. Nitrogen ions B. Nitrate ions E. Various organic and inorganic compounds C. Nitrates F. None of the Above What are EPA's Drinking Water Regulations for Nitrite? 381. In 1974, Congress passed the Safe Drinking Water Act. This law requires EPA to determine the level of contaminants in drinking water at which no adverse health effects are likely to occur. These non-enforceable health goals, based solely on _____________ and exposure over a lifetime with an adequate margin of safety, are called maximum contaminant level goals (MCLG). Contaminants are any physical, chemical, biological or radiological substances or matter in water. A. MCLG D. MCLGs are set as close to the health goals as possible B. MCLs E. MCLs are set as close to the health goals as possible C. Limits F. None of the Above 382. The MCLG for nitrite is 1 mg/L or 1 ppm. EPA has set this level of protection based on the best available science to prevent potential health problems. EPA has set an enforceable regulation for nitrite, called a maximum contaminant level (MCL), at 1 mg/L or 1 ppm. MCLs are set as close to the health goals as possible, considering cost, benefits and the ability of public water systems to detect and remove contaminants using _______________. In this case, the MCL equals the MCLG, because analytical methods or treatment technology do not pose any limitation. A. MCLG D. MCLGs are set as close to the health goals as possible B. MCLs E. MCLs are set as close to the health goals as possible C. The Phase II Rule F. None of the Above 383. ______________, the regulation for nitrite, became effective in 1992. The Safe Drinking Water Act requires EPA to periodically review the national primary drinking water regulation for each contaminant and revise the regulation, if appropriate. EPA reviewed nitrite as part of the Six Year Review and determined that the 1 mg/L or 1 ppm MCLG and 1 mg/L or 1 ppm MCL for nitrite are still protective of human health. States may set more stringent drinking water MCLGs and MCLs for nitrite than EPA. A. MCLG D. MCLGs are set as close to the health goals as possible B. MCLs E. MCLs are set as close to the health goals as possible C. The Phase II Rule F. None of the Above How does Nitrite get into my Drinking Water? 384. The major sources of __________ in drinking water are runoff from fertilizer use; leaching from septic tanks, sewage; and erosion of natural deposits. A. Nitrites D. Nitrogen ions B. Nitrate ion E. Various organic and inorganic compounds C. Nitrate F. None of the Above Selenium- Inorganic Contaminant 0.05 mg/L MCL 385. Selenium (Se) is an essential element for_____________, with the majority of our intake coming from foods such as nuts, cereals, meat, fish, and eggs. A. Vitamins D. Selenide or selenate compounds B. Drinking water E. Human nutrition C. Minerals F. None of the Above 63 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 386. The concentration of Selenium in drinking water is usually low, and comes from natural minerals. In soils, selenium often occurs in soluble forms such as selenate, which are leached into rivers very easily by runoff increasing the amount of __________________. A. Selenium D. Selenide or selenate compounds B. Selenium in drinking water E. An essential element C. Minerals F. None of the Above 387. ____________is also a by-product of copper mining / smelting. Selenium is also used in photoelectric devises because its electrical conductivity varies with light. A. Selenium D. Selenide or selenate compounds B. Selenium in water E. An essential element for human nutrition C. Minerals F. None of the Above 388. Acute toxicity caused by ____________or other sources of intake has been observed in laboratory animals and in animals grazing in areas where high selenium levels exist in the soil. The US EPA has established the MCL for selenium in water at 0.05 mg/l. A. Selenium D. Selenide or selenate compounds B. Selenium in drinking water E. High levels of selenium in water C. Minerals F. None of the Above Selenium Explained 389. Selenium is found impurely in metal sulfide ores, where it partially replaces the sulfur. Commercially, selenium is produced as _________________in the refining of these ores, most often during copper production. A. Metal sulfide ores D. Silicon B. Natural deposits E. Glutathione peroxidase C. Antioxidant enzymes F. None of the Above 390. Minerals that are pure selenide or selenate compounds are known, but are _____________. The chief commercial uses for selenium today are in glassmaking and in pigments. Selenium is a semiconductor and is used in photocells. A. Selenium based D. Compounds B. Found in drinking water E. An essential element for human nutrition C. Minerals F. None of the Above 391. Uses in electronics, once important, have been mostly supplanted by silicon semiconductor devices. Selenium continues to be used in a few types of DC power surge protectors and one type of___________________. A. Metal sulfide ores D. Silicon semiconductor devices B. Natural deposits E. Fluorescent quantum dot C. Selenium F. None of the Above 392. Selenium salts are toxic in________________, but trace amounts are necessary for cellular function in many organisms, including all animals. A. The poisoner's poison D. Large amounts B. Pharmaceutical industry E. A heavy layer of oxide C. Selenium salts F. None of the Above Thallium- Inorganic Contaminant 0.002 mg/L MCL 393. Thallium is a metal found in natural deposits such as ores containing______________. A. Metal sulfide ores D. Silicon B. Natural deposits E. Other elements C. Selenium F. None of the Above 64 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747 Uses for Thallium. 394. The greatest use of ________________is in specialized electronic research equipment. A. Nonselective toxicity D. Potassium ores B. Thallium E. This soft gray poor metal C. Selenium F. None of the Above What are Thallium's Health Effects? 395. Some people who drink water containing thallium well in ___________ for many years could experience hair loss, changes in their blood, or problems with their kidneys, intestines, or liver problems. A. MCLG D. MCLGs are set as close to the health goals as possible B. MCLs E. Excess of the maximum contaminant level (MCL) C. The Phase II Rule F. None of the Above Thallium Explained 396. Thallium is a chemical element with symbol Tl and atomic number 81. This soft gray poor metal is not found free in nature.______________, it resembles tin, but discolors when exposed to air. A. Nonselective toxicity D. Like Potassium ores B. When observed E. This soft gray poor metal C. When isolated F. None of the Above 397. Thallium tends to oxidize to the +3 and +1 oxidation states as ionic salts. The +3 state resembles that of the other elements in thallium's group (boron, aluminum, gallium, indium). However, the +1 state, which is far more prominent in thallium than the elements above it, recalls the chemistry of alkali metals, and thallium(I) ions are found geologically mostly in potassium-based ores, and (when ingested) are handled in many ways like ____________by ion pumps in living cells. A. Metal sulfide ores D. Potassium ions (K+) B. Natural deposits E. Antioxidant enzymes C. Selenium F. None of the Above 398. The radioisotope thallium-201 (as the____________) is used in small, nontoxic amounts as an agent in a nuclear medicine scan, during one type of nuclear cardiac stress test. A. Nonselective ion D. Potassium ore B. Thallium 111 E. Soluble chloride TlCl C. Thallium 3 F. None of the Above 399. Soluble thallium salts (many of which are nearly tasteless) are highly toxic in quantity, and were historically used in_________________________. A. Nonselective ion D. Rat poisons and insecticides B. Thallium 111 E. Soluble chloride TlCl C. Thallium 3 F. None of the Above 400. Thallium poisoning notably results in hair loss. Because of its historic popularity as a murder weapon, thallium has gained notoriety as "the poisoner's poison" and "_________________" (alongside arsenic). A. Inheritance powder D. Soluble sleeping powder B. Pharmaceutical powder E. Sleeping powder C. Saltpeter powder F. None of the Above 65 Chemical Contaminants 201 ASS 9/1/2016 (928) 468-0665 Fax (928) 272-0747