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Module 1: Measurement and Significant Figures Goal: Use significant figures from measurements to adjust calculated answers. Chemworks 1 Objectives a. Distinguish between a measured number and an exact number. Mini-Lecture Measurement Standards of Measurement Tools for Measurement Exact Numbers b. Distinguish between accuracy and precision in a measurement. Accuracy Precision Pizza Precision c. Indicate correct number of significant figures in a number. Significant Figures in Measurement Reading A Meterstick Known + Estimated Digits Zero as a Significant Digit Counting Significant Figures Leading Zeros Sandwiched Zeros Trailing Zeros d. Report answers to calculations using the correct number of significant figures. Significant Figures in Calculations Team Activities Worksheet M1: Types of Numbers Learning Checks M1 M2 M3 Worksheet M2: M&M’s Statistics M4, M5 M6, M7, M8 Worksheet SF1: Counting Significant Figures \ SF1 SF2 SF3 SF4 SF5 SF6 Worksheet SF2:Rounding Numbers Worksheet SF3:Calculator Operations Worksheet SF4:Significant Figures in Reported Answers SF7 Types of Numbers Worksheet M1 A. EXACT NUMBERS Form a group of 3-4 students and complete the numbers for the following data. People in your group People in your group with backpacks Inches in one foot Centimeters in one meter People wearing glasses in your group Seconds in one minute 1. How were the numbers in part A obtained? 2. Why are each of these numbers called exact numbers? B. MEASURED NUMBERS Have each student in your group individually use a meterstick or metric ruler to measure the width (cm) and the length (cm) of this page of paper. Record the results below. Width Length Student 1 Student 2 Student 3 Student 4 1. How were the numbers in part B obtained? 2. How close were your measurements for width and length? 3. List as many reasons as you can to explain why the measurements for width and length might differ. M & M’s Statistics Worksheet M2 Predicted Number Actual Number Counted or Measured Number? Data How many M&Ms are in the package? How many yellow M&Ms? How many red M&Ms? How many dark brown M&Ms? What is the total mass (grams) of M&Ms listed on the package? Calculations % Yellow M&Ms % Red M&Ms? % Dark brown M&Ms? Calories/ M&M What is the average mass of one M&M (g/M&M)? What is the total mass (grams) of all of the red M&Ms in the package? Work Result Counting Significant Figures Worksheet SF1 In each of the following example sets, observe the number of significant figures and complete the blanks. Write a rule for counting significant figures in each set by completing the statement with the term significant or not significant. EXAMPLE SET 1 Number of Significant Figures 38.15 cm 4 5.6 ft 2 65.6 lb _____ 122.55 m _____ EXAMPLE SET 2 Type of zeros Number of Significant Figures 0.008 mm leading 1 0.0156 oz leading 3 0.0042 lb _________ _____ 0.000262 mL _________ _____ EXAMPLE SET 3 Type of zeros Number of Significant Figures 50.8 mm confined 3 2001 min confined 4 0.702 lb _________ _____ 0.0405 m _________ _____ 0.008060 g _________ _____ Type of zeros Number of Significant Figures 25,000 in. trailing 2 200 yr trailing 1 48,600 gal _________ _____ 105,000 m _________ _____ EXAMPLE SET 4 Rule 1: All nonzero digits are (significant or not significant) Rule 2: Leading zeros (zeros in front of nonzero digits) are (significant or not significant) . Rule 3: Sandwiched zeros (zeros between nonzero digits) are (significant or not significant) Rule 4: Trailing zeros (zeros that follow nonzero digits) in numbers with no decimal point are _____________________ (significant or not significant) Rounding Numbers Worksheet SF2 In each problem, observe the number of significant figures, and complete the rules for determining the number of significant figures in calculated answers from operations of multiplication, division, addition, and/or subtraction. ROUNDING OFF NUMBERS OR ADDING PLACEHOLDER ZEROS Round the following measured numbers to the number of significant figures indicated: To 3 SFs To 2 SFs 1.48221 1.48 1.5 0.88822 _________________ _________________ 0.0028533 _________________ _________________ 508.25 _________________ _________________ 386,222 _________________ _________________ 3.582 x 105 _________________ _________________ 4 4.00 4.0 8 _______________ _________________ RULES FOR ROUNDING Complete the following to give rules for rounding off. When the first digit of the numbers to be dropped is less than 5_______________________, When the first digit of the numbers to be dropped is 5 or greater _____________________, Complete the following to give rule for adding zeros. When an answer has fewer significant figures than desired the proper number of significant figures is acquired by _____________________________________________________ Calculator Operations Worksheet SF3 Design a sequence to run on the calculator that will solve each of the following mathematical operations. Carry out the operations to give an answer. Share your sequence with you neighbors. Make sure that everyone in your group gets the same answer. Example: 3.5 x 340 x 0.10 = x 3.2 x .10 x 8.5 x 102 = 1. 0.050 x 1.2 2. 6.0 X 10-4 0.15 3. 0.85 x 24 4.8 x 2.5 4. 4.44 5. 55.2 - 24.484 + 15 = = 0.2 + 13.254 = = = 4.8 (answer) Significant Figures In Reported Answers Worksheet SF4 Multiplication and Division Problem 1: 3.8 in. x 2.54 cm 1 in. Calculator result = Reported Answer = 0.9652 0.97 cm How many significant figures are in 3.8 in? ______________________ How many significant figures are in 2.54 cm/in? ______________________ How many significant figures are in the reported answer? ______________________ Explain the reason for the number of significant figures in the reported answer: Explain how the unit of cm is obtained for the answer. Problem 2: 100.0 g x 1 mL 2.70 g Calculator result x 1 qt = 946 mL 0.039 15 1202 Reported Answer = 0.0392 qt In the setup, show how the units cancel out. How many significant figures are in 100.0 g? ______________________ How many significant figures are in 2.70 g/mL? ______________________ How many significant figures are in 946 mL/qt? ______________________ How many significant figures are in the reported answer? ______________________ Explain the reason for the number of significant figures in the reported answer: In setting up a problem, how are the units of the measurements arranged? Worksheet SF 4 continued Problem 3: Reported Answer Complete the setup and give the reported answer. 1.18 x 1010 in. x 1 sec 2.54 cm 1 in. x sec min x min hr = How many significant figures are in 1.18 x 1010 in.? ______________________ How many significant figures are in 2.54 cm? ______________________ Which values are exact numbers? ______________________ Why? How many significant figures should be in the reported answer? ______________________ Why? What are the unit(s) of the answer? ______________________ Summarize your method for remembering how to determine the number of significant figures for reported answers from multiplication and division? Worksheet SF 4 continued Addition and Subtraction Problem 4: Add: 24.8 Calculator result + 1.587 + 24.78 = 51.167 Reported Answer = 51.2 1. Align the numbers from problem 4 and indicate the number of decimal places in each. ________.____ ______decimal place(s) ________.____ ______ decimal place(s) ________.____ ______ decimal place(s) 2. Which of the added numbers has the fewest decimal places? ___. ________ 3. Now carry out the addition: Sum ________.___ ______decimal place(s) needed 4. Round off to the correct number of decimal places to find the reported answer: Reported answer ___________.______ 5. How should you determine the final reported answer for addition or subtraction problems? Problem 5: Add: Calculator result 45 + 1.0025 Subtract: Reported Answer + 3.78 ______________ _________ 41.04 - 34.889 ______________ _________ How do you determine the final reported answer for subtraction problems? Problem 6: 8.26 (2.45 + 5.7) (0.00452)(856) = Which rules will you apply first: rules of addition/subtraction or multiplication/division?