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SI Units • The worldwide scientific community and most countries currently use an adaptation of the metric system to state measurements. The Système International d’Unités, or SI, uses seven base quantities, which are below. DERIVED UNITS Defined by a combination of base units • Volume: ml = cm3 • Density: g/ml • Molar Mass: g/mol PREFIXES USED WITH SI UNITS king henry died by drinking chocolate milk Equivalents For Conversions −3 10 Kilo 10−2 −1 1000 Hecto 10 units 100 Deka 1 units 10 10 Basic 2 units Unit Deci 3 0.1 Centi units 0.01 Milli units 0.001 1 10 10 units Prefixes used with SI Units Dimensional Analysis (AKA Factor Label) Dimensional analysis is used in choosing conversion factors. A conversion factor is a multiplier equal to 1. For example, because 1 kg = 1000 g, you can construct the following conversion factors: Conversion Factor Label Practice! 1. Convert 12 L into milliliters: 1𝑚𝑙 12𝐿 −3 = 12000𝑚𝑙 10 𝐿 OR move the decimal 3 places to the right. 2. Convert 132 cg into kg: 10−3 𝑘𝑔 132𝑐𝑔 2 =0.00132 10 𝑐𝑔 kg OR move the decimal 5 places to the left. More Conversion Factor Label Practice! 3. Convert 1201 seconds into hours: 1𝑚𝑖𝑛 1ℎ 1201𝑠 𝑥 60𝑠 60𝑚𝑖𝑛 = 0.3336h 4. Convert 17.3 g/mL to Kg/L 𝑔 10−3 𝑘𝑔 103 𝑚𝑙 17.3 𝑥 𝑥 =17.3 𝑚𝑙 1𝑔 1𝐿 kg/L Significant Figures (Digits) • The numbers in measurements are limited by the measuring tool. • Significant figures in a measurement include the known digits plus one estimated digit. 1. What is the 1st measurement? 1.42 cm 2. What is the 2nd measurement? 2.7 cm Counting Significant Figures • RULE 1. All non-zero digits in a measured number are significant. Only a zero could indicate that rounding occurred. Give the Number of Significant Figures a. 38.15 cm 4 b. 5.6 ft 2 c. 65.6 lb ___ d. 122.55 m ___ Leading Zeros RULE 2. Leading zeros in decimal numbers are NOT significant. Give the Number of Significant Figures a. 0.008 mm 1 b. 0.0156 oz 3 c. 0.0042 lb __ d. 0.000262 mL __ Sandwiched Zeros RULE 3. Zeros between nonzero numbers are significant. (They can not be rounded unless they are on an end of a number.) Give the Number of Significant Figures a. 50.8 mm 3 b. 2001 min 4 c. 0.702 lb __ d. 0.00405 m __ Trailing Zeros RULE 4. Trailing zeros in numbers without decimals are NOT significant. They are only serving as place holders. Give the Number of Significant Figures a. 25,000 in. 2 b. 200. yr 3 c. 48,600 gal __ d. 25,005,000 g __ Learning Check A. Which answers contain 3 significant figures? 1) 0.4760 2) 0.00476 3) 4760 B. All the zeros are significant in 1) 0.00307 2) 25.300 3) 2.050 x 103 C. 534,675 rounded to 3 significant figures is 1) 535 2) 535,000 3) 5.35 x 105 Learning Check In which set(s) do both numbers contain the same number of significant figures? A. 400.0 and 40 B. 0.000015 and 150,000 C. 22.0 and 22.00 Learning Check State the number of significant figures in each of the following: A. 0.030 m 1 2 3 B. 4.050 L 2 3 4 C. 0.0008 g 1 2 4 D. 3.00 m 1 2 3 E. 2,080,000 bees 3 5 7 How many sig figs in the following measurements? 1) 2) 3) 4) 5) 6) 7) 24689 1.00411 0.000062 8.01 23,000,000 2.30 x 107 2.000 Ans.1) 5 2) 6 3) 2 4) 3 5) 2 6) 3 7)4 Adding and Subtracting The answer has the same number of decimal places as the measurement with the fewest decimal places. 25.2 one decimal place + 1.34 two decimal places 26.54 answer 26.5 one decimal place Learning Check In each calculation, round the answer to the correct number of significant figures. A. 235.05 + 19.6 + 2.1 = 1) 256.75 B. 2) 256.8 58.925 - 18.2 1) 40.725 3) 257 = 2) 40.73 3) 40.7 Multiplying and Dividing Round (or add zeros) to the calculated answer until you have the same number of significant figures as the measurement with the fewest significant figures. Learning Check A. 2.19 X 4.2 = 1) 9 2) 9.2 B. 4.311 ÷ 0.07 = 1) 61.58 2) 62 C. 2.54 X 0.0028 = 0.0105 X 0.060 1) 11.3 2) 11 3) 9.198 3) 60 3) 0.041 Reading a Meterstick • . l2. . . . I . . . . I3 . . . .I . . . . I4. . cm First digit (known) = 2.?? cm Second digit (known) = 0.7 2.7? cm Third digit (estimated) between 0.05- 0.07 Length reported = 2.75 cm or 2.74 cm or 2.76 cm Known + Estimated Digits In 2.76 cm… • Known digits 2 and 7 are 100% certain • The third digit 6 is estimated (uncertain) • In the reported length, all three digits (2.76 cm) are significant including the estimated one Learning Check • . l8. . . . I . . . . I9. . . .I . . . . I10. . What is the length of the line? 1) 9.6 cm 2) 9.62 cm 3) 9.69 cm cm Zero as a Measured Number • . l3. . . . I . . . . I4 . . . . I . . . . I5. . What is the length of the line? First digit Second digit Last (estimated) digit is cm 5.?? cm 5.0? cm 5.00 cm