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Topic 3 Atoms Download the topic outline / worksheet from the website for the section. View the PowerPoint. Try to reflect on everything you see, to internalize the concepts and new terminology as much as possible. Be sure to pay attention to fly-ins: these can include additional concepts which are important to your study of chemistry. Watch also for links to websites which will help you. Fill in outline. Outline should include all major concepts, clarifying details and examples. Pay close attention to math setups. Outlines will be scored so try to stay neat and organized. They should be useful for you to review for tests. Continue to study the required elements list. Try to recognize their position on the periodic table. Do the “test your understanding” and old regents questions as they come up. These do not need to be handed in, but can become part of your notes outline. Do your best, to do problems on your own first, before looking at answers. Do the textbook “sample exercises” as they come up. These must be integrated into your notes outline. Do the exercises at the end of the outline handout. Be sure to justify your responses when directed. Rubric: 5= well developed answer with justification; 4= correct answer, no justification (when required); 3 = limited; incomplete 2; 1 = incorrect. Email me with questions: [email protected] Topic 3- A Sections 2.1 The Atomic Theory 2.2 Discovery of Atomic structure 2.3 Modern view of atomic structure 2.4 Atomic weights 2.5 periodic table Focus questions: • If an atom is too small to be seen how do we know it exists? • How do we know about the atom’s structure? • What does an atom look like? To consider: Suppose you were to break a piece of chalk in half. …then in half again. …and again. How many times could you continue break it in half? To consider: Your piece would go from one-half, to one quarter. …to 1/8th , 1/16th , etc. …and could never to zero. To consider: Or is there a point… …where the process would have to stop? When you reach a single particle of chalk. To consider: …this is the concept of the atom. History of atomic theory 2 views (theories) of matter: Continuous: matter broken down indefinitely Ex: how many times can a piece of chalk be divided? Indefinitely? Or will we reach a basic particle? Discontinuous: matter breaks down into a simple building block Democritus (400BC)–was an ancient Greek philosopher Coined the term “atomos” meaning indivisible His was the Philosophical atom – as no evidence was examined Philosophers like to think about things that usually can’t be experimented on, so they don’t look for evidence. Hey, sometimes you gotta make this stuff up. Link 2.1 The Atomic Theory But if no one’s ever seen an atom, how do we know it exists? It’s a “theory” Theory: a mental picture (a concept) created to help understand an observed phenomenon Realize: since theories are mental creations, they aren’t real and can’t be “proven”. We can however find evidence to support them and use them to identify new relationships and make predictions. Laws state an observed regularity but without explanation. Example: “objects with mass are attracted to each other “ is the law of gravity. Why? No one really knows, but there are theories! John Dalton (1807) ultimate particle model 1. All matter made of ultimate particles (called atoms) that are extremely small 2. Atoms of a given element are identical, while different elements have different relative weights ex: Nitrogen atoms are 14 x heavier than Hydrogen atoms (the lightest atom) so we will say that H = 1, while N = 14 3. Atoms of elements cannot change into different elements nor can they be created or destroyed during reactions. 4. Compounds are formed by combining atoms of different elements in unique combinations. A chemical reaction is the rearrangement of atoms into new arrangements forming new compounds link Dalton took evidence from various laws; and the atomic theory provides an explanation for them…. Law of conservation of mass (mass is never lost or gained during reactions) Why? Because atoms can’t be created or destroyed, just rearranged Law of constant composition (compounds always have the same proportions of elements in them) Aka law of definite composition, law of definite proportions Why? A specific arrangement of atoms is required to make a given compound Dalton was also one of the first to use symbolism to represent atoms, elements, and compounds… Dalton bio 16 X + 8Y 8 X2Y Mass of 16 x + mass of 8 Y is still the same when rearranged into the 8 molecules of X 2Y 2.1 Link Dalton predicted the law of multiple proportions: Example: two compounds of Carbon and oxygen: When carbon is only partially burned it forms a gaseous product. …When carbon is completely burned it also forms a gaseous product. The mass of oxygen in the product from complete combustion is exactly twice the oxygen in the partial product. Why? For example; for every 10 grams of carbon there are 26 grams of oxygen in the complete product. Whereas for every 10 grams of carbon in the partial product there are only 13 grams of oxygen. Can you use the atomic theory to explain this? If your theory is correct it you should be able to see it at work in different ways! The two gases are carbon monoxide and carbon dioxide So, if you compare two different compounds made of the same elements, there must be a simple ratio between the two compounds, for a given element. If your theory is correct it you should be able to see it at work in different ways! The theory tells us that there must be exactly twice as much oxygen in carbon dioxide as carbon monoxide since there are twice as many atoms in one compared to the other Think about it…You can’t see the atoms to count them. So… It’s the only valid explanation! The idea (theory) of the atom… explains why chemicals exhibit multiple proportions (the law) Try one: Water is always 11.1% hydrogen and 88.9% oxygen (by weight) Hydrogen peroxide is 5.89% hydrogen, and 94.1% oxygen. This means that in 100 gram samples of those two compounds there is 11.1 grams of hydrogen and 88.9 grams of oxygen and 5.89 grams of hydrogen, and 94.1 grams of oxygen; respectively Show mathematically, how these two compounds illustrate the law of multiple proportions: To do this, calculate the simple whole number difference for oxygen in the two compounds, for a fixed quantity of hydrogen (or fix the oxygen, then compare the hydrogen, you’ll see that it doesn’t matter) Need a hint? Calculate the grams of oxygen per 1 gram of hydrogen for each. divide the mass of O by the mass of H for each For water, 89.9 grams H = 8 g O per g H 11.1 grams O For hydrogen peroxide, 94.1 grams H = 16 g O per g H 5.89 grams O See the ratio? 8:16 = 1:2 Twice as much O in peroxide! Use the atomic theory to explain the difference: If water is H2O, than peroxide can be H2O2? 2.2 Discovery of atomic structure Thomson electron discovery link This Thomson guy looks like a serious character, eh? Electron JJ Thomson (1897) did experiments with the cathode ray tube or “CRT” High voltage applied to the electrodes caused streams of particles from the negative “cathode” Found that Particles were emitted by any substance tested, and were smaller than any known atom (were subatomic) Where did they come from? What were they? Thomson deduced that they must come from inside the atoms and be part common to all atoms. First called cathode rays, become known as electrons. Shadow created by Maltese cross blocking cathode rays Older TVs and computer monitors are CRTs TV, computer monitor Cathode Ray Tube Cathode (-) Anode (+) How do we know that the cathode rays travel from the cathode to anode? 2.2 How can the size of the mass of the electron by measured? In another experiment, Thomson calculated the charge to mass ratio. By finding the magnetic force (controlling gravities pull on the mass) that canceled out the electric field force (controlling the pull and push on the electrical charges) he found their ratio as 1.76 x 108 coulombs per gram. As a result, if either the charge or mass of the electron could be found, then the other could be calculated from this ratio. (that’s up next!) In 1907, Robert Millikan, designed an experiment whereby he sprayed oil droplets into a chamber allowing a few to drop and gain excess electron charge with x-rays. He adjusted the electrical field charge until the drops were suspended in mid air between the plates. Because each drop had gained a different number of electrons, each drop took a different force to keep it suspended. Millikan knew that all the required charges were a simple multiple of the charge on just one electron. By finding this common factor, he was finding the charge on just one electron. For example, what if Millikan had found these values for charge: -4.8 x 10-19 Coulombs -3.2 x 10-19 Coulombs -6.4 x 10-19 Coulombs What value would he have concluded is the common factor, I.e.. What value is the charge on just one electron? Notice: all are multiples of -1.6 x 10-19 Coulombs This is the charge on a single electron It is slightly more complex than this but you get the idea? Click here to see a flash video clip for more explanation Millikan’s oil drop experiment link Now….Remember the charge to mass ratio: 1.76 x 108 coulombs per gram? -1.60 x 10-19 C = 1.76 x 108 C/gram 9.10 x 10-28 grams mass of an electron J.J. Thomson’s plum pudding model of the atom Thomson reasoned that these tiny electrons were imbedded in a positive atom. This model didn’t last too long! Radioactivity In the Late 1800’s Discovery of Uranium, Polonium, and Radium samples emitting high energy “radio-activity” of three types: Alpha radiation (+2 charge, with large mass) Beta particles radiation (-1, similar to cathode ray electrons) Gamma radiation (no charge or measurable mass) Separation of particles between charged plates link Studies by French scientists Henri Becquerel along with his students Pierre and Marie Curie provided further evidence for the existence of subatomic particles Link Both Curies died likely due to their exposure to radiation Discovery of the Nucleus: Rutherford Gold foil Experiment British scientist Ernest Rutherford experimented with Alpha radiation. He Shot alpha (+) particles at a piece of thin gold foil. The Results: Most alpha particles passed undeflected (as expected of radiation) Some alphas were slightly deflected from original path (not unexpected) A Few were significantly deflected.(unexpected) Link What Rutherford expected (based on thomson’s plum pudding model) The atom is mostly empty space with a tiny dense positive nucleus containing almost all of the mass. Electrons revolve rapidly around outside the nucleus, like planets orbiting the sun. What Actually Happened (alphas +, were deflected by the positive nucleus) Rutherford’s Model of the Atom Empty space (with a few tiny Electrons circling!) If the atomic radius ~ 100 pm = 1 x 10-10 m The nuclear radius ~ 5 x 10-3 pm = 5 x 10-15 m “If the atom is the Houston Astrodome, then the nucleus is a marble on the 50-yard line.” Video Link 2.2 Proton was discovered by Rutherford in 1919. Recognized as a Hydrogen nucleus (single proton) given off as radiation. Interpreted as other elements must be made of hydrogen nuclei-protons. Proton mass = 1.67 x 10-24 g Neutron: James Chadwick (1932) Rutherford’s Dilemma: Hydrogen atoms have 1 proton and mass = 1 atomic mass unit Helium atoms have 2 protons, but mass = 4 atomic mass units So, where does the extra mass come from? There must be additional particles in atoms that add mass but without charge + 9Be 1n + 12C + energy This is a nuclear equation. We will study these later in the year. In 1932 Chadwick bombarded Beryllium atoms with alpha particles and discovered neutron radiation Neutron mass = 1.67 x 10-24 g Same as a proton Check your understanding: 1. Which model of the atom was the simplest? What were its characteristics? Dalton’s, solid spheres with different masses 2. How did Thomson surmise that electrons were subatomic particles? How did he know they were negatively charged? Smaller than the smallest atom, attracted by positive charge 3. Why did most of the alpha particles pass through the gold foil undeflected? Why did a few get deflected? Atoms are mostly empty space, but have a small positive nucleus 4. Why can’t two atoms pass through one another if there’s so much empty space? Hint: what do negative electrons (like charges) do when near each other? They repel each other like a force field! Regents level questions 2.3 The modern view of atomic structure Video link The Charge cloud model: Nucleus containing Protons and neutrons Electrons circling rapidly around outside nucleus would appear as a cloud Protons Note: AMU = atomic mass unit Mass = 1.67262 x 10-24 g atoms so tiny, the gram is not a very convenient unit to -19 coulombs Charge =Since + 1.602 x 10are use to represent their mass. aka: +1 charge NeutronsSince it turns out that protons and neutrons are very close in mass, -24 Mass = 1.67493 x 10 a new unit wasgdeveloped called the atomic mass unit. Essentially, Neutral charge the mass of a proton or neutron is assigned a mass of one amu, or simply 1 u. Since protons and neutrons are so close in mass, we assign them both a mass of 1 atomic mass unit (1 u) As you will see, to find the mass of an atom you will need only add Atomic size: most atoms 1 to 5 Electronsup the mass of the number of protons and neutrons. (electrons, as it angstroms in diameter Mass = 9.10939 10-28 g = negligible mass turns outx have almost no mass) (1 Å = 10-10 meters) compared with Protons and neutrons ( 0 amu’s) -19 coulombs here if you want more detail on this idea Charge =Click - 1.602 x 10 aka -1 charge 10,000,000,000 atoms lined up would only form a line 1 mm long! *(For convenience, atomic mass units are used (u): 1 u = 1.66054 x 10-24 g Amu’s are much easier to work with than grams! AP (b) Hint: calculate atoms per line X 10 +2 1.54 Å x 10-10 m x 1 pm 1Å 10-12 m -2 1 atom x 1 Å x 10-3 m x 0.20 mm 1.54 Å 10-10 m 1 mm 1 line Atomic number, mass number, and isotopes Elements get their properties from the number of protons. Number of protons in nucleus is called the Atomic number (the “Z” number) The mass of an atom comes from its protons plus its neutrons (electron weight is negligible) The Mass number (“A” number) = number of protons + number of neutrons = atomic number (Z) + number of neutrons The neutrons are calculated by A# minus Z# Symbolism: Mass Number (superscript) Atomic Number A ZX Tutorial link Element Symbol (subscript) Ex: The most common form of carbon (atomic #6) has 6 protons and 6 neutrons 6 protons + 6 neutrons 6 protons Carbon –12 has 12 – 6 = 6 neutrons This is an isotope of carbon. It has 6 protons, but 8 neutrons. 6 + 8 = 14 mass Carbon –14 is radioactive (its nucleus is not stable) It is used to estimate the age of fossils, remember? Isotopes are atoms of the same element (X) with different numbers of neutrons in their nuclei. They have the same Z number (protons) but their A number (mass) is different Isotopes are identified by their masses: C-12 vs. C-14 The three isotopes of hydrogen Most hydrogen is H-1 (protium) Tutorial link Isotopes of an element have the same chemical properties and most samples of elements have at least a couple of different isotopes in them. You have radioactive carbon-14 in you! Do You Understand Isotopes? How many protons, neutrons, and electrons are 14 in 6 C ? 6 protons, 8 (14 - 6) neutrons, 6 electrons How many protons, neutrons, and electrons are 11 in 6 C ? 6 protons, 5 (11 - 6) neutrons, 6 electrons 2.3 Check your understanding An atom has 14 protons and 20 neutrons. A. Its atomic number is 1) 14 2) 16 3) 34 B. Its mass number is 1) 14 2) 16 C. The element is 1) Si D. 3) 34 2) Ca 3) Se Another isotope of this element is 1) 34X 2) 34X 3) 36X 16 14 14 AP AP The four basic forces of matter Gravity is the attraction between the mass in different objects The nuclear strong force overcomes the repulsion of protons packed together in the nucleus and holds it together In chemistry we deal mostly with electrostatic forces since they are responsible for the bonding between atoms that hold molecules together Electrostatic or electromagnetic Click here for a Bill Nye link Forces are between charged objects like electrons and protons (remember opposite charges attract, but like charges repel) The nuclear weak force is used to explain radioactive emissions. 2.4 Atomic weights Tutor link Elements in nature are mixtures of different isotopes. The atomic weights listed on the periodic table are averages of the different isotopes for an element Ex: Naturally occurring carbon is a mixture of three isotopes: Carbon 12, carbon 13 and an insignificant amount of carbon 14 The atomic weight for carbon listed on the periodic table is 12.0107 Sum of To calculate this value: Atomic weight = Notice that the atomic weight always comes close to isotope of greatest abundance. [(isotope mass) x (percentage abundance)] = (12.000 u )(0.9893) + (13.00335)(0.0107) = (11.8716) + (0.1391) = 12.0107 amu This is called “weighted averaging” The small amount of carbon 13 skews the mass to just above 12 Weighted averaging: here is a simpler example: Suppose you have three components to your grades: Labs, Tests, and homework. The weighting is Labs 25%, Tests 50%, and homework 25% Your grades are 90% on labs, 75% tests, and 87% Homework By adding up the product of the weight x grade you arrive at and overall average of 81.75 or 82 rounded Notice that this is closer to the test grade average since it carries the highest weight? In chemistry we are interested in the atomic weight average Obviously, most chromium atoms have masses less than 52.94, like maybe 51.94? A small fraction of Cr – 53 atoms (52.94) will skew the average mass up to 51.99! (92.23%)(27.97693) + (4.68%)(28.97649) + (3.09%)(29.97377) The mass spectrometer: measuring mass and abundance of isotopes 1) A sample of a gas enters and is ionized. 2) Ions accelerate and bend as they pass through a magnetic field Video link Chlorine’s atomic mass (average) is 35.5 According to the graph is that reasonable? 3) Lighter atoms bend more, heavier bend less 4) Detectors separate isotopes by mass and the relative signal intensity give the % abundance Information from the periodic table Much of the data related to atomic structure that you will need to solve problems in chemistry can be found on your periodic table Regents level questions: Electrons have equal but opposite charge from a proton but are only a fraction as large The nucleus contains protons and neutrons (making it always positive in charge. Electrons are in orbitals outside the nucleus Positve is attracted to negative. Alphas are large particles with an overall charge of +2 The charge of the nucleus is the origin of all properties in the nucleus. That charge is determined by the number of positive protons. Atomic number 7 means +7 charge in its nucleus Atomic number 11 means its nucleus has a +11 charge 15 protons has a +15 nuclear charge making its atomic number 15 phosphorus The lower value in the symbol is the atomic number – the number of protons. The lower number 11 – the atomic number identifies this as Na The additional mass in an isotope like C14 must come from extra neutrons since both must have the same proton # - 6 Protons and neutrons are the only massive particles each weighing 1 amu. 21 P + 24N = 45 amu. Carbon is atomic number 6 = 6 protons; and 6 electrons to make it neutral. A mass of 14 means there are an additional 8 neutrons of mass in the nucleus. The presence of different isotope mass forms for each and every element means they must be averaged to find the overall atomic mass Calculate, but if 75% has a mass of 35 vs. only 25% is 37, the mass should be closer to 35 than 37 Weighted averaging 2.5 The Periodic Table Link Dmitri Mendeleev (1834 - 1907) Dmitri Mendeleev was a Russian chemist, who, in 1870, looked for a way to organize the elements. He wrote the known properties of elements on blank playing cards. Explosive gas 1 H He placed element cards in order of increasing mass and looked for patterns. Inert gas 4 Notice the formulas of the compounds formed with F and O. He HF H2O Active metal 7 Li LiF Li2O Active metal 9 semimetal 11 Be B BeF2 BeO BF3 B2O3 nonmetal 12 unreactive gas 14 Explosive gas 16 active gas 18 Inert gas 20 C N O F Ne CF4 CO2 NF3 N2O3 OF2 O2 F2 F2O Active metal 23 Active metal 24 metal 27 semimetal 28 nonmetal 31 nonmetal 32 Active gas 35 Inert gas 40 Na Mg Al Si P S Cl Ar MgF2 MgO AlF3 Al2O3 SiF4 SiO2 PF3 P2O3 SF2 SO ClF Cl2O NaF Na2O Active metal 39 After fluorine, he noticed that sodium was similar to lithium, and the pattern repeated. K After chlorine, he noticed that potassium was similar to sodium, etc. KF K2O Hydrogen starts the table since it’s the smallest, and the noble gases, once discovered took their place at the end of the line. TED Link Notice how elements line up into columns with similar properties? Also, notice how the properties repeat each row? That’s “periodic”! If we add in the transitional elements in the middle and the rare earth elements below, the present table becomes recognizable Click for the element song (Tom Lehrer’s original) or Daniel Radcliffe Sings (cute clip) Mendeleev’s Table Was Organized first based on increasing mass (but he allowed elements to group by similar properties) Found properties of elements repeated periodically (in a regular pattern) Put elements in groups with similar properties Key: Left spaces for elements that weren’t yet discovered Eka-silicon - aka germanium Properties repeat! Mass dilemma: mass sometimes decreases Henry Moseley (1913) Did X-ray studies Periodic Law: “Properties of the elements are periodic functions of their atomic numbers” (nuclear charge, # protons) Organized into groups (vertical columns) of elements with similar properties Organized into periods (horizontal rows) – properties change systematically from metals to nonmetals to inert (unreactive) gases Group 1 Period 1 Period 2 Period 3 Etc. Properties are similar in columns Group 2 Etc. Properties change systematically Left to right The periodic table can be broadly divided into two categories: Nonmetals Metals: left side of the table are shiny, malleable elements, which have difficulty holding onto electrons during chemical reactions – that is they are chemically “weak” In my classes I refer to them as “losers” Metals Nonmetals: right side of table are dull, brittle elements which are chemically strong, holding onto their own electrons and gaining electrons during chemical reactions In my classes I refer to them as “gainers” Notice: Two ways to distinguish groups: Groups 1-18 or 1A to 8A and 3B to 10B In Regents Chem we use 1 to 18, AP is 1A through 8A with group B in the middle. The periodic table can be broadly divided into two categories: Metals Noble Gases Nonmetals The last column is a group of nonmetal elements which are so strong that they are stable and unreactive: The Noble Gases Hydrogen is the smallest so it starts the table, but its actually a nonmetal so it is sometimes also shown here: To Repeat: Hydrogen sits on the metal side, but it’s actually a NONMETAL H Nonmetals Metals Si Ge As Sb Te Po Between the losers and gainers, the metals and nonmetals – along the border between them sits the metaloids: These elements have properties of both metals and nonmetals, depending on the situation Noble Gases B H H Nonmetals Metals Si Ge As Sb Te In the middle of the table are the transition metals At the bottom are the rare earth metals These extra metals arise due to the way in which electrons arrange themselves in the atom. We will visit them in just a bit. Periodic table organization – for extra help click here Po Noble Gases B H Types of elements Metals Nonmetals Metalloids Solids (one liquid) Solids and gases (one liquid) Solids Shiny Luster Malleable Ductile Good conductors of Heat and electricity Noble gases Gases Dull Luster Brittle Poor conductors Good insulators Semiconductors Properties of both M & NM Inert or Unreactive Finding information on the table Periodic table squares usually give the basic information, but not always in the same positions. Some tables give lots of information but you have to look at the key to figure it out. Memorize the positions of the required elements on the periodic table Click a square below to play the element drag and drop game! Easy All elements Try to associate the elements with their type (metals, nonmetals, noble gase, etc.) and if possible, their group numbers. This will get you close. Don’t get discouraged. As you practice you’ll start to get a sense for where things are. This will help you figure stuff out when you don’t have a periodic table to look at (like on the AP test!) Knowing the position of the elements on the table tells a lot of information. Learning check: 1. State the modern periodic law: “Properties of elements are…. “Periodic functions of their atomic number” 2. What are “groups” on the periodic table? How are the members related to one another? Vertical columns, have similar properties 3. What are the periods on the periodic table? how do the properties change across a period? Horizontal rows: change from metals to inert gases 4. What are the 3 + 1 types of elements? Where is each located on the table? How do their properties differ? Metals on left are shiny, malleable, conductors: noble gases on right are inert gases nonmetals at the top right above the step are dull, brittle nonconductors: , metalloids along the step have properties of both metals and nonmetals Group 1 and 2 (S block) alkali metals and alkaline earth metals Both groups very reactive Found in nature only in compounds Obtained from breakdown of salts Transitional metals Group 3 to 12 Less reactive than s-block(group 1 and 2) metals Generally similar properties Many form colored ions Some found in elemental state in nature (ex Au) Transition from group 2 to group 13 Includes rare earth metals and actinides of the f block. Found in certain rare minerals Rare Earth metals and actinides Group 13 to 16 Nonmetals Nonmetals above Includes nonmetals of the pnictogens (Nitrogen family) chalcogens (oxygen family) and halogens (fluorine family) “Poor” Metals below Softer metals with low melting points Semimetals in between Poor metals semimetals Metalloids (semimetals ) • Along stepped line • B, Si, Ge, As, Sb, Te, Po • Properties of both metals and nonmetals • Ex: computer “semiconductors” made of silicon Group 17 Halogens (salt-makers) • Highly reactive nonmetals • Found in nature only in compounds • F gas - most active nonmetal (reactive) • Gas to liquid to solid due to increasing inter-molecular (sticky) forces Group 18 Noble gases “Neon” signs Very unreactive because they have full electron shells Learning check: 1. What families of elements are so reactive that they are only found in nature combined in compounds? Alkali metals – group 1 and halogens group 17 2. Where are the transitional elements located? What kind of elements are they? Other traits? Middle of table, relatively inactive, colored solutions 3. Which groups on the table contain both metals and nonmetals? Explain Groups 13-16, nonmetals above line, metals below 4. Which halogen is most reactive? Fluorine What trend occurs in melting and boiling points for elements in group 17? Why does this trend occur? MP and Bp increase, molecules get stickier as they get larger 5. List the 7 semimetals (metalloids): Why are they named as such? B, Si, P As, Se, Te, Po – properties of both metals and nonmetals 6. What elements exist as diatomic molecules when in their pure, uncombined state? BrINClHOF’s Regents level questions It the periodic law Periods are horizontal, groups vertical 20 protons is atomic number 20 – calcium, a group 2 element. That’s what they’re called. Same group (column) Left, middle and bottom are all metals. We’ll see why later in the year. Metals are conductors Metals are malleable. Left side of table Si is a metalloid Group 1 elements That’s what they’re called. Middle of the table, groups 3 - 11 Calculate, but if 75% has a transition elements like Cr can have bright colors. Cr produces yellow- orange ions. Only two liquids at STP. Hg and Br. That’s where they are.