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KS4 Chemistry Earth and Atmosphere 1 of 48 © Boardworks Ltd 2005 Contents Earth and Atmosphere Development of the atmosphere O3 and CO2 The Earth’s structure Plate tectonics Rocks Summary activities 2 of 48 © Boardworks Ltd 2005 The early atmosphere • The Earth was formed about 4,500 million years ago. Mars • During the first billion years there was intense volcanic activity, which produced the early atmosphere. This would have contained large quantities of carbon dioxide (CO2) and water vapour. Methane (CH4) and ammonia (NH3) are thought to Venus have also been present. • This is rather like the atmosphere on Mars and Venus today. • The water vapour condensed to form the oceans. 3 of 48 © Boardworks Ltd 2005 Oxygen levels increase • Carbon dioxide reacted with rocks and much became trapped in them. Earth • The evolution of algae some 3,000 million years ago, and subsequently plants which successfully colonized the Earth’s surface, led us towards the present atmosphere. • Their photosynthesis replaced carbon dioxide with oxygen. • Over a period of time, billions of tonnes of carbon dioxide became locked up in fossil fuels. 4 of 48 Photosynthesis increased oxygen levels © Boardworks Ltd 2005 Nitrogen appears • As oxygen levels rose, atmospheric ammonia (NH3) reacted with oxygen(O2) to form water (H2O) and nitrogen (N2). • Also, living organisms, including denitrifying bacteria, broke down nitrogen compounds releasing more nitrogen into the atmosphere. • And so the atmosphere headed towards a composition that has remained fairly constant for the last 200 million years. 21% 1% Nitrogen Oxygen Other 78% 5 of 48 © Boardworks Ltd 2005 Atmosphere timeline Copy the timeline and arrange the blue boxes in appropriate places along the line. 4,500 million No gases 3,000 million H2O N2 O2 2,000 million 1,000 million CO2 NH3 CH4 500 million Volcanoes Algae 200 Now million H2 and He Plants 6 of 48 © Boardworks Ltd 2005 Timeline answers No gases Volcanoes 4,500 million 3,000 million H2 and He Plants Algae 2,000 million CO2 NH3 CH4 1,000 million 500 million 200 Now million O2 N2 H2O All positions are approximate 7 of 48 © Boardworks Ltd 2005 Changing gas levels 1. How long ago was the atmosphere 75% CO2? Approx 4,000M 2. How long ago were the CO2 and N2 levels in the atmosphere equal? Approx 3,300M 3. How long ago was the atmosphere 50% nitrogen? Approx 2,000M 8 of 48 100% Composition percentage Use the graph to estimate the answers. carbon dioxide nitrogen 50% oxygen 0% 5,000 3,000 now 0 Time (millions of years) © Boardworks Ltd 2005 Contents Earth and Atmosphere Development of the atmosphere O3 and CO2 The Earth’s structure Plate tectonics Rocks Summary activities 9 of 48 © Boardworks Ltd 2005 Ozone: a vital filter • Oxygen normally exists as pairs of atoms (O2). • Oxygen can, however, turn into another form that has three atoms joined together. This is ozone (O3). 3O2 oxygen 2O3 ozone Harmful UV rays stopped with ozone layer • As oxygen levels rose, so did the amount of ozone. Earth • This layer of ozone in the atmosphere filters out harmful ultraviolet rays from the sun. This will have allowed new organisms Harmful UV rays reach Earth’s surface to evolve and survive. without ozone layer 10 of 48 © Boardworks Ltd 2005 The carbon cycle 11 of 48 © Boardworks Ltd 2005 CO2 release or consumption? 12 of 48 © Boardworks Ltd 2005 Carbon dioxide and temperature Over millions of years the carbon cycle has maintained a constant, low percentage (approx. 0.03%) of carbon dioxide in the atmosphere. In 1860, the CO2 level was about 289 ppm (parts per million). Here is a table showing the CO2 levels over a recent 10-year period. Year 1979 1980 1981 1982 1983 1984 1985 1986 1987 1988 Carbon dioxide (ppm) 333.68 335.55 337.14 338.38 340.25 341.82 343.18 344.26 345.99 347.96 What percentage change is this and does it matter? 13 of 48 © Boardworks Ltd 2005 Changing CO2 concentrations From air trapped in Antarctic ice, we have a good idea of CO2 concentrations going back 160,000 years. We also know the temperatures over the same period. The very warm interglacial period of 130,000 years ago was accompanied by CO2 levels of around 300 ppm. The previous great Ice Age had CO2 levels around 200 ppm. 200ppm CO2 300ppm CO2 Which label goes with each picture? 14 of 48 © Boardworks Ltd 2005 The greenhouse effect Normally the Earth absorbs heat and emits heat at the same rate. Because of this the temperature remains constant. Certain gases, like CO2 and methane, act like a greenhouse. They let heat in but do not let it out. This is called the greenhouse effect. balanced same Earth temp More CO2 And hotter hotter! hotter Earth This means that the more CO2 there is, the hotter planet Earth is! 15 of 48 © Boardworks Ltd 2005 Contents Earth and Atmosphere Development of the atmosphere O3 and CO2 The Earth’s structure Plate tectonics Rocks Summary activities 16 of 48 © Boardworks Ltd 2005 The Earth’s structure Beneath the atmosphere the Earth consists of 3 main layers: 17 of 48 © Boardworks Ltd 2005 The core The core extends to about half the radius of the Earth. It is made mostly from iron and nickel and is where the Earth’s magnetic field comes from. It is very dense. 5,500 C The temperature is high and the outer core is molten. Towards the centre, high pressure makes the inner core solid. Intense heat is generated in the inner core by the decay of radioactive elements like uranium. 18 of 48 1,300 km 1,110 km 3,000 km Inner Outercore core © Boardworks Ltd 2005 The mantle The mantle extends outwards from the core to the crust: a distance of about 2,900 km. It is mostly a semi-molten liquid upon which the Earth’s crust floats. The heat coming from the core generates convection currents in the viscous mantle that cause the crust above to move. 2,900km Mantle 19 of 48 © Boardworks Ltd 2005 The crust The crust is the thin layer of rock at the surface upon which we live. Eight elements make up over 98% of the Earth’s Crust – although they are virtually entirely in the form of compounds. 50 % 45 40 35 30 25 20 15 10 5 0 20-60 km O 20 of 48 Si Al Fe Ca Na K Mg Crust © Boardworks Ltd 2005 What am I? • I’m a viscous semi-solid with convection currents circulating in me. Mantle • I’m iron and nickel too, but I’m liquid. Outer core • I just hang around on the outside. Atmosphere • I’m really very thin and am mostly silicon, oxygen and aluminium. Crust • I am dense, very hot, made mostly of solid iron and nickel. Inner core 21 of 48 © Boardworks Ltd 2005 Sections of the Earth Atmosphere Outer core Crust Mantle Inner core 22 of 48 © Boardworks Ltd 2005 Contents Earth and Atmosphere Development of the atmosphere O3 and CO2 The Earth’s structure Plate tectonics Rocks Summary activities 23 of 48 © Boardworks Ltd 2005 Tectonic plates • The crust is made of about twelve plates. • These are like big rafts floating on the semi-molten mantle. • Convection currents within the mantle cause the plates to move. • Although they only move about 2 cm a year this can have huge effects over long periods of time. 24 of 48 © Boardworks Ltd 2005 Why do plates move? 25 of 48 © Boardworks Ltd 2005 Sea floor spreading When two oceanic plates move apart molten rock rises to the surface. sea floor spreading oceanic plate magma rising 26 of 48 © Boardworks Ltd 2005 Continental drift • On average, the plates only drift about 2cm/year. However, 2cm multiplied by a million is a long way! • Scientists think the continents were originally all together in a super-continent called Pangaea. • 27 of 48 Pangaea Millions of years Over millions of years they have drifted to their present positions on the floating tectonic plates. © Boardworks Ltd 2005 Continental drift 28 of 48 © Boardworks Ltd 2005 Evidence for continental drift The theory is supported by several pieces of evidence. For example, if we consider Africa and South America there is: • The “jigsaw fit”. • The similarities in the rock layers from Africa and South America. • Similarities in the type and age of fossils. • Evidence of related species that definitely did not swim the Atlantic Ocean! 29 of 48 Jigsaw fit Similar rocks and fossils © Boardworks Ltd 2005 Plate boundaries 30 of 48 © Boardworks Ltd 2005 Effects at plate boundaries When a continental plate and an oceanic plate meet, the effects include: • plates juddering past each other producing earthquakes • the continental plate buckles upwards while the oceanic plate subducts (goes underground) • volcanoes result from the rising magma (melted oceanic plate) volcano oceanic plate magma rising continental plate 31 of 48 © Boardworks Ltd 2005 Contents Earth and Atmosphere Development of the atmosphere O3 and CO2 The Earth’s structure Plate tectonics Rocks Summary activities 32 of 48 © Boardworks Ltd 2005 Types of rocks There are three main types of rocks: Igneous – formed when molten rock cools. Sedimentary – formed by the “cementing together” of small grains of sediment. Metamorphic – rocks changed by the effect of heat and pressure. All of these are involved in a continuous flow of rock from the surface underground only to emerge again later as part of the on-going rock cycle. 33 of 48 © Boardworks Ltd 2005 Igneous rocks • These are rocks formed by the cooling of molten rock (magma). Magma cools and solidifies forming igneous rocks. volcano magma 34 of 48 © Boardworks Ltd 2005 Types of igneous rocks Igneous rocks divide into two main groups: • Intrusive igneous • Extrusive igneous • Intrusive igneous rocks, like granite, are formed when magma solidifies within the ground. 35 of 48 • Extrusive igneous rocks, like basalt, are formed when magma solidifies above the ground. © Boardworks Ltd 2005 Igneous rocks and crystal size The more slowly a rock changes from liquid to solid the bigger the crystals grow. Intrusive igneous rocks, like granite, usually have clearly visible crystals. Intrusive igneous rocks that cool really slowly can have very big crystals. 36 of 48 Extrusive igneous rocks, like basalt, have crystals that are usually small. Extrusive igneous rocks that cool really quickly can have a glassy appearance. © Boardworks Ltd 2005 Chemical and physical weathering • Surface rocks seem to be gradually reduced in size by weathering processes. • Chemical weathering occurs when chemicals, such as those in acid rain, ‘eat’ away certain rocks. • Physical weathering relates to rocks being broken down by the action of wind, rain and sun. For example, during the freezing and thawing of water in the cracks of rocks, the expansion of water makes the rocks splinter. • The small broken fragments wash into rivers and, eventually, reach the sea where they settle as sediment. 37 of 48 © Boardworks Ltd 2005 Sedimentary rocks Sedimentary rocks are rocks formed when particles of sediment build up and are “cemented together” by the effect of pressure and minerals. Fragments washed to the sea Rocks are broken up by the action of weather sea Sedimentary rocks 38 of 48 © Boardworks Ltd 2005 Types of sedimentary rocks Sedimentary rocks tend to have visible grains of sediment. Sometimes they contain fossils. They are usually softer than igneous rocks. Examples of sedimentary rocks are sandstone and mudstone. Getting older 39 of 48 Sandstone is formed from the cementing together of grains of sand. © Boardworks Ltd 2005 Metamorphic rocks Metamorphic rocks are formed by the effect of heat and pressure on existing rocks. This can greatly affect the hardness, texture and layer patterns of the rocks. Pressure from surface rocks metamorphic rock magma 40 of 48 forming here heat © Boardworks Ltd 2005 Types of metamorphic rocks Marble, slate and schist are metamorphic. Limestone is a rock often formed from the sediment of shells. Temperature and pressure cause the rock to reform as small crystals that are much harder. This is marble. It is used as a hard and decorative stone in buildings, sculptures etc. Slate is formed when pressure squeezes mudstone into plate-like grey sheets. It is used in roofing. Schist and mica are formed when mudstone is subjected to very high temperatures and pressure. Again, they contain layers, which is typical of many (but not all) metamorphic rocks. 41 of 48 © Boardworks Ltd 2005 What’s the rock? Match the rock with the correct description. Give an example of this type of rock. Rock type 42 of 48 Description intrusive igneous Large crystals, hard rock metamorphic Sandy texture, soft rock extrusive igneous Small crystals, hard rock sedimentary Wavy layers of crystals © Boardworks Ltd 2005 The rock cycle 43 of 48 © Boardworks Ltd 2005 Contents Earth and Atmosphere Development of the atmosphere O3 and CO2 The Earth’s structure Plate tectonics Rocks Summary activities 44 of 48 © Boardworks Ltd 2005 Glossary (1) atmosphere – The gases that surround the Earth. core – The central part of the Earth, divided into a solid inner section and molten outer section. crust – The outer section of the Earth, made up of plates. igneous – A rock formed by the crystallization of magma. mantle – The layer of molten, semi-solid rock under the Earth’s crust. metamorphic – A rock formed when an existing rock is changed by heat or pressure. 45 of 48 © Boardworks Ltd 2005 Glossary (2) ozone – A gas made up of three oxygen atoms, which forms a layer that filters harmful UV rays from the sun. plate – A large section of rock that floats on the Earth’s mantle and forms part of the crust. plate tectonics – A theory that movement of the Earth’s plates over time is responsible for the current position of continents, and the creation of mountains and volcanoes. sedimentary – A rock made up of layers of sediment. 46 of 48 © Boardworks Ltd 2005 Anagrams 47 of 48 © Boardworks Ltd 2005 Multiple-choice quiz 48 of 48 © Boardworks Ltd 2005