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Transcript
Atoms and Molecules
λc =
6
Chapter 10
hc 6,63 × 10 −34 × 3,00 ×108
m = 62 pm
=
eV
1,60 ×10 −19 × 20 ×10 3
X-ray or Röntgen’s pictures
These are Wilhelm Röntgen’s own pictures of his wife’s hand from 1895.
Wilhelm K. Röntgen 1845-1923
Moseley diagram
When one examined the peaks of the X-ray spectrum for different anode materials one could
see that the peaks corresponded to electronic transitions and photon emission from the
materials inner shells. The big peak of the spectrum is called Kα and the one at shorter
wavelength Kβ, which means an electron jumps to the K-shell, illustrated in the figure below.
One systematically examined Kα and Kβ radiation for various elements with different atomic
numbers, Z (proton number). Making a diagram where one puts the square root of the
frequency of the radiation f1/2 against Z one gets a straight line, like in the figure below, which
is called a Moseley diagram: