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Bohr Quantum Model of the Atom Bohr § postulated that classical radiation theory did not hold for atomic systems Classical theory: Continuous spectrum of radiation Bohr Quantum Model of the Atom Bohr § postulated that classical radiation theory did not hold for atomic systems § applied Planck’s ideas of quantized energy levels to orbiting electrons and postulated that: electrons in atoms are confined to stable, non-radiating energy levels and orbits (stationary states) Bohr Quantum Model of the Atom Bohr § postulated that classical radiation theory did not hold for atomic systems § applied Planck’s ideas of quantized energy levels to orbiting electrons and postulated that: electrons in atoms are confined to stable, non-radiating energy levels and orbits (stationary states) § applied Einstein’s concept of the photon to arrive at an expressions for the frequency of the light emitted when electron jumps from one stationary state (i) to another (f) ΔE = hν hν Ei − E f = hν Bohr Quantum Model of the Atom Bohr § postulated that classical radiation theory did not hold for atomic systems § applied Planck’s ideas of quantized energy levels to orbiting electrons and postulated that: electrons in atoms are confined to stable, non-radiating energy levels and orbits (stationary states) § applied Einstein’s concept of the photon to arrive at an expressions for the frequency of the light emitted when electron jumps from one stationary state (i) to another (f) § postulated that the electron orbital momentum is quantized L = n where n = 1, 2, … (integer) Bohr Quantum Model of the Atom Bohr § postulated that classical radiation theory did not hold for atomic systems § applied Planck’s ideas of quantized energy levels to orbiting electrons and postulated that: electrons in atoms are confined to stable, non-radiating energy levels and orbits (stationary states) § applied Einstein’s concept of the photon to arrive at an expressions for the frequency of the light emitted when electron jumps from one stationary state (i) to another (f) § postulated that the electron orbital momentum is quantized Justification of Bohr’s postulates: comparison with experimental observations!