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Introduction to Modern Physics a.k.a. Some stuff we've sort of figured out these last 100+ years Quantum Mechanics Quantum Mechanics begins with light. Some experiments proved beyond the shadow of a doubt that light was waves. Some other experiments proved beyond the shadow of a doubt that light was particles. The truth about light was obviously hidden and it wasn't until 1900 that people began to understand that there was something very weird about the world of the small. Something that required a complete revision of understanding. A brief history: The Quantum Mechanical era commenced in 1900 when Max Planck postulated that everything is made up of little bits he called quanta (one quantum; two quanta). Matter had its quanta but also the forces that kept material objects together. Forces could only come in little steps at the time; there was no more such a thing as infinitely small. A Blackbody is an object that absorbs all radiation reaching it, and blackbody radiation is radiation emitted by a blackbody. The specific problem that puzzled Planck is represented by a glowing hot object. https://phet.colorado.edu/sims/blackbody-spectrum/blackbody-spectrum_en.html Max Planck theorized that the metals begin to glow because their vibrating molecules can only vibrate at certain quantities of energy. These vibrating particles emit packets of energy, called quanta, which is directly proportional to its frequency. This was the first stepping stone to a new branch of physics called Quantum Mechanics. Albert Einstein took matters further when he successfully described how light interacts with electrons but it wasn't until the 1920's that things began to fall together and some fundamental rules about the world of the small where wrought almost by pure thought. But let's work with what we know. It is high school after all. Wave-Particle Duality: Light https://www.youtube.com/watch?v=wENZmBofwSw Christiaan Huygens helpped many others before him that light behaved as a wave. Huygens’ principle states that all points on a wave front can be thought of as new sources of spherical waves. Huygens also claimed that light required an invisible medium in which to travel called the æther (or just ether). Newton professed that light was a particle. His experiments proved as much, and he ... is... Newton. Who would question him? His light particle travels in straight lines with maximum velocity, and have kinetic energy. Newton’s particle theory of light does not need a medium for light to travel in. This theory accounted for the rectilinear propagation of light. This theory was held for many years, even though it could not be used to explain diffraction. Young's Double Slit Experiment. If light does travel like a wave, then it should undergo interference. Consider the wave interference pattern: The light waves are too small to detect any pattern, plus most light sources are INCOHERENT, which means out of phase, due to the many different frequencies emitted from the Sun, candle, etc. Young's Double Slit Experiment. COHERENT light must be used. This means one must use MONOCHROMATIC light, which is a single wave of light travelling in phase with the other waves of light. If this light is directed through a narrow slit, it will behave like a point source If you then direct the light from the single slit to a double slit, the double slit acts as a pair of sources of coherent, monochromatic light, which then allows you to observe interference effects. Young’s double-slit experiment demonstrated conclusively that light behaves as a wave. The experiment also provided a method to measure wavelength. Clearly particles cannot do this. (at least not classically) The behaviour of the tennis balls illustrates some important differences between particles and waves. • Particles do not show interference effects. • Waves do show interference effects. • Particles deliver energy in discrete quantities, that is, separate, individual “parcels” of energy that transfer to the screen in the small area where the particle strikes. • Waves do not deliver energy in discrete quantities. Waves deliver their energy continuously over time and spread out over the screen. (intensity) Later, studies of what happens when light shines onto metal gave some very puzzling results that the wave theory of light could not explain. Light, at specific frequencies, when shown on metals will cause them to emit electrons... Light This is puzzling, as it requires a packet of energy in order to break the Coulombic force and remove the electron from its proton pair. AND, photons have no mass! The minimum energy required to remove a single electron from a piece of metal is called the work function, W. This is measured in electron volts for convenience. Recall: W = q·V, where q = 1electron·e, and V= 1Volt (1V) 1eV = 1.602x10-19J These minimum amounts of energy can be determined by applying an electric potential. When the energy exceeds the work function and an electron is ejected and a table of values can be generated. The fact that light was able to also do this was puzzling. photoelectric effect refers to the emission, or ejection, of electrons from the surface of a metal in response to incident light. Light par cles are called photons Ephoton = hf Photons are discrete packets of energy Light is said to be “quan zed” the light must be larger than the threshold frequency, fo When an electron is emied aer a collision of a photon, it is called a photoelectron. The only way the photoelectric effect can work is if light behaves like a particle. (Think of two pool balls colliding.) E = hf Where: E is the energy (J) f is the frequency in Hertz h is known as Plank's constant 6.63 x 10-34 J·s (...We'll get to this later) The unit of Joules are rarely used for a photon or photoelectron, rather, all energies are converted into an ELECTRON VOLT (eV) 1 eV = 1.602 x 10-19 J Thus, we will divide our final result by 1.602 x 10-19 J/eV If the minimum amount of energy required of a photon to eject an electron is given by its threshold frequency, then the work function is: hf =W o Then any photon with f >fo will possess extra kinetic energy given by: Ek = hf - hf o Ek = hf - W Which provides a linear relationship between kinetic energy and the frequency. Ek = hf - W Kinetic energy of outgoing photoelectron. Energy of incoming light. Energy needed to free the photoelectron. (Threshold) Aluminum is being used in a photoelectric effect experiment. The work function of aluminum is 6.73x10-19 J. (a) Calculate the minimum photon energy in eV and the frequency needed to emit electrons. (b) Incident blue light of wavelength 450 nm is used in the experiment. Determine whether any electrons are emitted, and if they are, determine their maximum kinetic energy. NO ELECTRON EJECTED Stopping voltage Millikan set up an experiment that would allow him to measure the energy of the escaping electrons while he varied the frequency of the incident light source. He set up the photoelectric tube so that a reversed voltage could be applied across the anode and cathode which would stop the ejected photoelectrons from reaching the anode. He called the necessary voltage the cut off or stop voltage. Thus, the electric potential established would have the same energy as the escaping photoelectron. Ek electron = electric potential energy Ek = q Vstop Millikan now had a practical way to measure the energy of the photoelectrons by raising the voltage until the current across the tube stopped flowing. In this way he could measure very accurate values of the kinetic energy of the photoelectrons for different light frequencies. If the stopping voltage in a certain photoelectric effect is 10.0 V and the incident wavelength of the light source is 105 nm, what is the work function of the metal surface? Ek electron = Ephoton - W hλ - W qVstop = ---c The classical theory of electromagnetic waves predicts that a light wave with energy also carries a certain amount of momentum, E p = ___ c Einstein’s quantum theory states that light energy can only be absorbed or emitted in discrete parcels, as single photons. Each photon carries an energy, , therefore photon= hf pphoton = ___ c so... and f = ___ c λ h pphoton = ___ λ This momentum was proven with the Compton Effect. Leftover energy was re-emitted as a lower-energy x-ray photon, much like an elastic collision. Note: special relativity was needed. Suppose an atomic nucleus at rest emits a gamma ray with energy 140 keV. Calculate the momentum and the wavelength of the gamma ray. We'll stop here for today.