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StudyPacks STUDY. KS4 SCIENCE Chemistry Basics The Atom This Study Pack aims to cover: 1. The atomic structure. 2. Elements and compounds SC1 Study Packs are prepared by Qualified Teachers and Specialists and are a complete range of comprehensive compiled resources based on the UK National Curriculum covering the Primary and Secondary Frameworks including SATs and GCSE examinations. Student Name Contents Chemistry Basics Notes 2-5 Practice questions 6-15 Exam questions 16-27 Mark scheme 28-34 Inside atoms Aims There are about 100 elements. Each one is made up of one kind of atom. Scientists have discovered that atoms are made from smaller particles called protons, neutrons and electrons. In this activity you will check your knowledge of atoms and the particles in them. Questions Which particles are found in the nucleus of an atom? Highlight any correct answers. protons neutrons electrons Which particles orbit the nucleus? Highlight any correct answers. protons neutrons electrons Which atomic particle has a charge of +1? Highlight the correct answer. proton neutron electron Which atomic particle has no charge? Highlight the correct answer. proton neutron electron Which atomic particle has a charge of −1? Highlight the correct answer. proton neutron electron Two of the particles each have a mass of one atomic mass unit. The other has almost no mass. Which one has almost no mass? Highlight the correct answer. proton neutron electron The number of protons that an element has determines what atoms it contains. For example, all carbon atoms have six protons. In any atom, which particle is present in the same number as the number of protons? Highlight the correct answer. neutron electron 1 Why is there no overall charge on an atom? .............................................................................................................................. .............................................................................................................................. Revision Questions, Elements, Mixtures and Compounds 1. Copy and complete the following table 2. What is the smallest particle of an element called? 3. What contains only one type of atom and is found on the periodic table? 4. What contains two or more elements chemically combined? 5. What contains two or more chemicals together which are not chemically combined? 6. What do we call a chemical that contains a metal, carbon and oxygen only? 7. Give an example of the above. 8. Describe what is meant by a molecule? 9. What do we call the elements that react? 10. What are three signs that a chemical reaction has taken place? 11. What is meant by a displacement reaction? 12. Use the periodic table and give the name of the elements and the number of atoms in each of the following chemicals. I. (NH4)2SO4 III. H3PO4 V. Ca(OH)2 II. C6H12O6 IV. Na2CO3 VI. (NH4)2SO4 Atomic structure Aims In this worksheet you will learn about the structure of an atom. The electrons in an atom are arranged in shells or energy levels. Each shell can only hold up to a certain number of electrons. Is there a link between the way the electrons are arranged and where the element is placed on the periodic table? Look at this diagram of a calcium atom. Calcium has an atomic number of 20, which means each atom has 20 electrons. The electrons fill the lowest energy level first. This is the shell nearest the nucleus. Questions Use the diagram above to complete these sentences: The first shell can hold a maximum of ................. electrons. The second shell can hold a maximum of .................. electrons. The third shell can hold ..................... electrons. Using a periodic table to find the atomic numbers, fill in the following sketch diagrams for these atoms. Remember, you must fill up one shell before you start on the next. Lithium Number of electrons _____ 9 Neon Number of electrons _____ Magnesium Number of electrons _____ Chlorine Number of electrons _____ Complete this table and answer the question below: Element Number of shells with electrons in Row or period on periodic table Calcium Lithium Magnesium Neon Chlorine What is the link between the number of shells with electrons in and the row or period the element is in on the periodic table? .................................................................................................................................... .................................................................................................................................... 10 .................................................................................................................................... Lithium is in Group 1 of the periodic table, magnesium is in Group 2 and chlorine is in Group 7. Look at your sketches. Is there a link between the group and the way the electrons are arranged? ..................................................................................................................................... ..................................................................................................................................... ..................................................................................................................................... Discussion Chemical reactions are all about electrons. During a chemical reaction, atoms give, take or share electrons to make themselves more stable. Having electronic structures like the noble gases in Group 0 is best. Which of the elements on the previous page is likely to be very unreactive as a result of the way its electrons are arranged? Are there any other atoms on the periodic table which are likely to behave in the same way? 11 Inside compounds Aims A compound is made by joining two or more different elements together. It is important to understand what compound names are telling us. You also need to be able to read chemical formulae accurately. Rule What it means Find the metal first. If there is a metallic element in a compound, it goes first in the name. Change the name of the nonmetal. The non-metal in a compound forms the second part of the name. The end of the element name is changed to ‘ide’. For example, chlorine becomes chloride. Is there a metal + oxygen? If the only non-metal element is oxygen, the compound is an ‘oxide’. What if there is a metal and two non-metals? You often get oxygen and another non-metal in a compound. Use the name of the other non-metal and change the end of the name to ‘ate’ to show there is oxygen there. For example, a compound with chlorine and oxygen is a ‘chlorate’. Questions Name the compound made from sodium and fluorine. .............................................................................................................................. What compound is made from oxygen and zinc? .............................................................................................................................. What compound is made in the reaction between bromine and potassium? .............................................................................................................................. Marble is a rock that contains a compound made from the elements oxygen, calcium and carbon. What is the compound called? .............................................................................................................................. 12 Copper sulfate forms bright blue crystals. The atoms of which elements would you find in copper sulfate? .............................................................................................................................. When you are reading chemical formulae, the different symbols tell you which types of atoms are in the compound. Small (subscript) numbers tell you how many atoms there are of the element written just before the number. If there is no number after a symbol, there is one atom of that element. For example, the formula of water is H2O. Its molecules are made from two atoms of hydrogen and one atom of oxygen. What atoms are present in a molecule of CO2? How many of each type are there? .............................................................................................................................. .............................................................................................................................. What atoms are present in one formula unit of KNO3? How many of each type are there? .............................................................................................................................. .............................................................................................................................. .............................................................................................................................. What atoms would you find in one formula unit of Na2CO3? How many of each type are there? .............................................................................................................................. .............................................................................................................................. .............................................................................................................................. 13 Fundamental ideas Test Yourself 1 Use numbers from the list to complete the table to show the charge on each subatomic particle. (3) +2 +1 0 –1 –2 Subatomic particle Charge electron neutron proton 2 Use the periodic table at the back of your book to help you to answer this question. a How many protons are in an atom of fluorine? ................................................................................................................................... b How many electrons are in an atom of carbon? ................................................................................................................................... c Complete the electronic structure of aluminium: 2,8, ....... d What is the electronic structure of potassium? ................................................................................................................................... 3 (1) (1) (1) (1) Neon is a noble gas. a What does this tell you about its electronic structure? ................................................................................................................................... b (1) Draw a diagram to show the electronic structure of neon. (2) 14 4 a Magnesium has the electronic structure 2,8,2. Explain, in terms of its electronic structure, why magnesium is in Group 2 of the periodic table. ................................................................................................................................... b Give one way in which the electronic structures of the atoms of Group 2 elements are: i the same ................................................................................................................................... ii (1) different. ................................................................................................................................... c (1) (1) When magnesium is heated in air it burns with a bright flame and produces magnesium oxide. Calcium is also in Group 2. Describe what you expect to happen and what would be produced when calcium is heated in air. ................................................................................................................................... ................................................................................................................................... 5 (2) Sodium reacts with water to produce sodium hydroxide and hydrogen. The word equation for this reaction is: sodium + water → sodium hydroxide + hydrogen a Name one substance in this equation that is: i an element ................................................................................................................................... ii (1) a compound ................................................................................................................................... (1) iii has ionic bonds ................................................................................................................................... (1) iv has covalent bonds 15 ................................................................................................................................... b (1) If 2.3 g of sodium reacted with 1.8 g of water, what would be the total mass of sodium hydroxide and hydrogen produced? Explain your answer. ................................................................................................................................... ................................................................................................................................... c Balance the symbol equation for this reaction. ...... Na + ...... H2O → ...... NaOH + H2 d (2) (1) Lithium is in the same group of the periodic table as sodium. i Write a word equation for the reaction of lithium with water. ................................................................................................................................... ii (1) What is the formula of lithium hydroxide? ................................................................................................................................... (1) iii How many atoms are shown in the formula of lithium hydroxide you have written? ................................................................................................................................... (1) 16 Exam questions Q1. About 100 years ago a scientist called J. J. Thomson thought that an atom was a ball of positive charge with negative particles stuck inside. Today a different model is used. The diagram shows how an atom of carbon is represented by this model. (a) The negative particles are called electrons. (i) What is the name of the positive particles ? ........................................................................................................................... (1) (ii) What particle is represented by ●? ........................................................................................................................... (1) (iii) What is the central part of the atom called that contains both and ●? ........................................................................................................................... (1) (b) Use the model to explain why the six electrons are arranged as shown. ..................................................................................................................................... ..................................................................................................................................... ..................................................................................................................................... ..................................................................................................................................... (2) (Total 5 marks) 2 Sando-K is a medicine. It is given to people whose bodies contain too little of a particular element. Sando-K is a mixture of two compounds. The formulae of the two compounds are given below. KHCO3 KCl 17 (a) Use the Data Sheet to help you to name all the elements in these compounds. ..................................................................................................................................... ..................................................................................................................................... ..................................................................................................................................... ..................................................................................................................................... (3) (b) Which metal do people given Sando-K need? ..................................................................................................................................... (1) (Total 4 marks) Q3. (a) The list below gives six substances. • aluminium • beer • copper • milk • pure water • sodium chloride Put each substance in the correct column of the table. ELEMENTS COMPOUNDS MIXTURES (3) (b) Elements can be divided into two groups, metals and non-metals. The list below gives some properties of elements. • brittle • can be hammered into shape • dull • good conductors of electricity • poor conductors of electricity 18 • shiny Put each property into the correct column. PROPERTIES OF METALS PROPERTIES OF NON-METALS (3) (Total 6 marks) Q4. There are millions of different substances that make up our world. All these substances are made from chemical elements. (a) What is an element? ..................................................................................................................................... ..................................................................................................................................... ..................................................................................................................................... ..................................................................................................................................... (1) (b) Many substances are compounds. What is a compound? ..................................................................................................................................... ..................................................................................................................................... ..................................................................................................................................... ..................................................................................................................................... (2) (Total 3 marks) Q5. John Dalton wrote these statements in 1808. • “All substances are made of a vast number of extremely small particles called atoms.” • “Every particle of water is like every other particle of water, every particle of hydrogen is like every other particle of hydrogen, etc.” 19 (a) “Every particle of water is like every other particle of water.” Use Dalton’s ideas and your knowledge of water to explain why. ..................................................................................................................................... ..................................................................................................................................... ..................................................................................................................................... ..................................................................................................................................... (2) (b) Dalton thought that all atoms of an element are exactly the same. We now know that it is possible to have atoms of the same element but with different mass numbers. The diagrams represent two atoms of hydrogen. Atom A Atom B State, in terms of particles, how these two atoms are different. ..................................................................................................................................... ..................................................................................................................................... (1) (Total 3 marks) Q6. The diagram shows the structure of a lithium atom. (a) (i) What is represented by (ii) What is represented by ................................................................................. ........................................................................... (2) 20 (b) What is the symbol for lithium? ................................................................................ (1) (Total 3 marks) Q7. The diagrams show the electronic arrangement of the atoms of two elements. (i) Name the part of the atoms labelled X. .................................................................................................................................... (1) (ii) Why are these two elements in the same group of the Periodic Table? .................................................................................................................................... .................................................................................................................................... (1) (Total 2 marks) Q8. Lithium metal is used in alkaline batteries. (a) The diagram shows the atoms in lithium metal. Why is lithium metal described as an element? ..................................................................................................................................... ..................................................................................................................................... (1) 21 (b) The diagram below represents a lithium atom. Choose words from the box to label parts of the atom. bond electron molecule nucleus (2) (Total 3 marks) Q9. (a) Hydrogen is an element. The diagram shows the parts of a hydrogen atom. Use words from the box to label the diagram. electron group nucleus symbol (2) (b) Hydrogen can be used as a clean fuel for cars. 22 (i) When hydrogen burns in air, it reacts with another element. Complete the word equation for this reaction. hydrogen → + ................................. water (1) (ii) Suggest one reason why hydrogen is called a clean fuel. ......................................................................................................................... ......................................................................................................................... (1) (Total 4 marks) Q10. Atoms are made up of three main particles called protons, neutrons and electrons. Use the periodic table on the data sheet to help you to answer these questions. (a) Sodium is in Group 1 of the periodic table. (i) Why are potassium and sodium in the same Group of the periodic table? ............................................................................................................... ............................................................................................................... (1) (ii) How many protons are in an atom of sodium? ..................................... (1) (iii) The atomic number of sodium is 11. How many neutrons are in an atom of sodium with mass number 23? ...................................... (1) (iv) Each sodium atom has 11 electrons. Complete the electronic structure of sodium. (2) (b) The chemical equation for a reaction of sodium is shown below. 2Na + Cl2 → 2NaCl 23 Describe this reaction of sodium in terms of the names of the substances and the numbers of the atoms involved. ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ (3) (Total 8 marks) Q11. (a) The chemical equation for a reaction of sodium is shown below. 2Na + Cl2 → 2NaCl Describe this reaction of sodium in terms of the names of the substances and the numbers of the atoms involved. ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ ........................................................................................................................ (3) (b) Use the periodic table on the data sheet to help you to answer this question. (i) Complete the electronic structure of sodium. (2) (ii) How is the electronic structure of sodium different from the electronic structure of chlorine? 24 ............................................................................................................... ............................................................................................................... (1) (Total 6 marks) Limestone has been called the Earth’s most useful rock. Q12. (a) Limestone contains calcium carbonate, CaCO3. (i) Complete the table to show the number of atoms of each element in the formula of calcium carbonate. Calcium has been done for you. Element Number of atoms in the formula CaCO3 Calcium, Ca 1 Carbon, C Oxygen, O (2) (ii) The diagram below represents a carbon atom. Use words from the box to label the parts of this atom. bond electron molecule nucleus (2) (b) At a cement works, limestone is mixed with clay and heated in a kiln. 25 Use the information in the diagram to answer these questions. (i) Name the fuel that is used to heat the limestone and clay. ........................................................................................................................... (1) (ii) Limestone contains calcium carbonate, CaCO3. Draw a ring around the correct gas in the box to complete the sentence. argon. The gas formed when calcium carbonate decomposes is carbon dioxide. nitrogen. (1) (c) The cement works starts to burn a different fuel. Local residents are concerned because more children are suffering asthma attacks. Residents have also noticed that parked cars are becoming dirty because of smoke particles from the chimney. The table shows the possible medical risk from smoke particles. (i) Particle size in mm Medical effect Larger than 0.4 No medical risks known 0.3 and smaller Causes asthma attacks 0.2 and smaller May cause cancer Give two reasons why local residents are concerned about the cement works burning a different fuel. 1 ........................................................................................................................ ........................................................................................................................... 2 ........................................................................................................................ ........................................................................................................................... (2) (ii) The company operating the cement works stated that smoke particles from the chimney had not changed since it started burning the different fuel. If you were a local resident, what evidence would you like to see to help you decide if the company’s statement is true or not? ........................................................................................................................... ........................................................................................................................... 26 ........................................................................................................................... ........................................................................................................................... (2) (Total 10 marks) Q13. Use the Periodic Table of Elements on the Data Sheet to help you to answer this question. (a) Describe, in as much detail as you can, the structure of a fluorine atom. ..................................................................................................................................... ..................................................................................................................................... ..................................................................................................................................... ..................................................................................................................................... ..................................................................................................................................... ..................................................................................................................................... (3) (b) Complete the diagram to show the electronic structure of a magnesium atom. (1) (Total 4 marks) Q14. Hot air balloons burn hydrocarbons to heat the air. (a) (i) The hot air contains these gases: nitrogen, N2 oxygen, O2 argon, Ar carbon dioxide, CO2 water vapour, H2O Argon is an element. What is an element? .................................................................................... ....................................... 27 ........................................................................................................................... (1) (ii) Name one other gas in the hot air that is also an element. ........................................................................................................................... (1) (b) Propane, C3H8, can be represented as: H H │ │ H │ │ H H H │ │ H Use the correct words from the box to complete the sentences. bond (i) carbon compound element mixture Propane is a ....................................... and is made up of atoms of hydrogen and ....................................... (2) (ii) Each line between the atoms in propane represents a chemical ....................... (1) (Total 5 marks) 28 Mark Scheme M1. (a) (i) proton 1 (ii) neutron 1 (iii) nucleus 1 (b) there are shells or energy levels or orbitals do not accept ring 1 the maximum number of electrons found in the first shell or energy level is 2 accept first shell is full with 2 electrons 1 [5] (a) potassium, hydrogen, carbon, oxygen, chlorine or iodine 3 correct gains 1 mark 4 correct gains 2 marks all correct gains 3 marks (deduct 1 mark for each incorrect answer) 3 (b) potassium (K) for 1 mark 1 [4] (a) elements: compounds: mixture: aluminium, copper, pure water, sodium chloride, beer, milk 2/3 correct gains 1 mark 4/5 correct gains 2 marks all correct gains 3 marks 3 (b) metals: non metals: can be hammered into shape, good conductor of electricity, shiny brittle, dull, poor conductors of electricity 2/3 correct gains 1 mark 4/5 correct gains 2 marks all correct gains 3 marks 3 [6] M4. (a) a substance which contains one type of atom or a substance that cannot be broken down into anything simpler for 1 mark 1 (b) more than one element/more than one type of atom combined/join together/bonded for 1 mark each 2 [3] 29 M5. (a) water (molecules) contain two hydrogen atoms and one oxygen atom all water molecules have the formula H2O for 2 marks water molecules contain hydrogen and oxygen (atoms) for 1 mark water is H2O for 1 mark 2 (b) atom A has no neutrons / atom B has one neutron allow different numbers of neutrons 1 [3] M6. (a) (i) neutron (name only) 2 (ii) nucleus / protons and neutrons each for 1 mark (do not allow mass number) (b) Li (correct cases of letters required) for 1 mark 1 [3] M7. (i) nucleus 1 (ii) they both have seven electrons in the outer shell accept they both have the same number of electrons in the outer shell both need one electron to make full outer shell 1 [2] M8. (a) made of one sort of atom accept it is in the periodic table accept it only has lithium atoms 1 (b) nucleus labelled correctly 1 electron labelled correctly 1 [3] M9. (a) electron words must be in correct position 1 nucleus 1 (b) (i) oxygen / O2 ignore air 1 (ii) any one from: • (water) does not pollute accept no harmful gas(es) 30 • (only) water is produced • no carbon dioxide (is produced) accept no greenhouse gas(es) / effect • no sulfur dioxide (is produced) accept no acid rain • no nitrogen oxides (are produced) • no carbon / no particles (are produced) 1 [4] M10. (a) (i) both have one / 1 electron in the outer energy level / shell allow both react in a similar way 1 (ii) eleven / 11 1 (iii) twelve / 12 1 (iv) (2x) max 1 if candidate changes the number of electrons in the first energy level / shell 8x (in second energy level / shell) 1 1x (in outer energy level / shell) 1 (b) two sodium atoms (react) 1 two (bonded) chlorine atoms (react) allow one chlorine molecule (reacts) 1 two sodium ions and two chloride ions (are produced) allow two molecules of sodium chloride (are produced) or two sodium chloride particles (are produced) 1 [8] M11. (a) two sodium atoms (react) 1 two (bonded) chlorine atoms (react) allow one chlorine molecule (reacts) 1 two sodium ions and two chloride ions (are produced) allow two molecules of sodium chloride (are produced) or two sodium chloride particles (produced) 1 (b) (i) (2x) max 1 if candidate changes the number of electrons in the first energy level / shell 8x (in second energy level / shell) 1 1x (in outer energy level / shell) 1 31 (ii) sodium has 1 electron in its outer energy level / shell or chlorine has 7 electrons in its outer energy level / shell 1 [6] M12. (a) (i) 1 1 3 1 (ii) nucleus 1 electron 1 (b) (i) methane / CH4 accept natural gas ignore air do not allow other gases 1 (ii) carbon dioxide 1 (c) (i) any two from: • medical risks • asthma • cancer • dirt • causes global warming / global dimming / greenhouse effect / acid rain ignore death accept effect on health accept difficulty breathing/ lung disease allow smoke particles allow harmful for the environment 2 (ii) any two from: • have a test done / scientific evidence • independent (evidence) • comparison of smoke particles / when different fuels used • medical evidence or more / less asthma attacks or cancer or dirt on cars 2 [10] M13. (a) 9 protons /Proton Number 9 mass / atomic number is neutral 1 32 10 neutrons 1 electron arrangement 2,7 / 9 electrons incorrect configurations neutral if no points scored, allow 1 mark for nucleus surrounded by electrons or nucleus contains neutrons and protons 1 (b) Mark is for 2,8,2 arrangements. accept electrons anywhere in correct orbit 1 [4] M14. (a) (i) made up of one sort of atom accept it is in the periodic table or has its own symbol 1 (ii) nitrogen / N / N2 or oxygen / O / O2 do not accept argon or helium do not accept oxide 1 (b) (i) compound 1 carbon 1 (ii) bond 1 [5] Answers to worksheets Inside the atom Answers to questions 1 protons and neutrons 2 electrons 3 proton 4 neutron 5 electron 6 electron 7 electron 8 The charges on the protons and electrons cancel each other out if there is the same number of each. Atomic structure Answers to questions The first shell can hold a maximum of 2 electrons. The second shell can hold a maximum of 8 electrons. The third shell can hold a maximum of 8 electrons. 33 Element Number of shells with electrons in Row or period on periodic table Electron diagrams to atoms: Number of electrons: in second, or 2,1) Number of electrons: Neon electrons: 10 (2, 8) Number of electrons: Calcium 4 4 Lithium 2 2 Magnesium 3 3 Neon 2 2 Chlorine 3 3 represent these Lithium 3 (2 in first shell, 1 Magnesium 12 (2, 8, 2) Number of Chlorine 17 (2, 8, 7) The number of electrons in the outermost used shell is the same as the group number on the periodic table, e.g. chlorine is in Group 7 and has 7 electrons in the third shell. Elements in Group 0, where neon is found, have no space in the outermost used shell. Discussion Neon has a very stable electronic structure and is very unreactive as a result. All the elements in the final group in the periodic table (Group 0) are similarly unreactive. The heavier noble gases have been made to form compounds but only under very extreme conditions. The elements in Group 0 are useful precisely because they are unreactive. Argon is blown over welds as they are being made to exclude oxygen, which would otherwise react with and corrode the metal. Inside compounds Aims This worksheet is designed to focus students on the basic knowledge they should have of what compound names mean and how to read chemical formulae. Teaching notes Students will need access to a periodic table to complete this worksheet. Answers to questions sodium fluoride. Do not accept anything else, for example, sodium fluorine or fluoride sodium. zinc oxide potassium bromide calcium carbonate copper, sulfur and oxygen carbon and 2 oxygen atoms 1 potassium, 1 nitrogen and 3 oxygen atoms 2 sodium, 1 carbon and 3 oxygen atoms 34 Fundamental ideas Test yourself Answers Subatomic particle electron neutron proton Charge –1 0 +1 1 a b c d 9 6 2,8,3 2,8,8,1 2 a It is stable or it has 8 electrons in its outer energy level/shell (not it has a full shell). b Two electrons (dots or crosses) on inner circle, 8 electrons on outer circle. 3a Two electrons in its highest energy level/outer shell. b i Same number of electrons or 2 electrons in highest energy level/outer shell. (accept same number of electrons in first energy level/shell) ii Different number of energy levels/shells. c burns (with a bright flame) (produces) calcium oxide 4a i sodium or hydrogen ii water or sodium hydroxide iii sodium hydroxide iv water or hydrogen b 4.1 g mass is conserved in reactions or mass of reactants = mass of products c 2Na + 2H2O → 2NaOH + H2 d i lithium + water → lithium hydroxide + hydrogen ii LiOH iii 3 or error carried forward from answer to (ii) 35