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Oils and Fats 1- Oils and fats are members of: a- Simple lipids. b- Compound lipids. c- Derived lipids. d- Both a & c. 2- Waxes are: a- Fatty acids. b- Esters of fatty acids and glycerol. c- Esters of fatty acids and high molecular weight alcohol. d- All of the above 3- Derived lipids are: a- Fatty acids b- Sterols c- Phosphoric acid and carbohydrates d- All of the above 4- Fixed oils and fats contain traces of free fatty acids due to: a- Oxidative rancidity b- Hydrolysis in the presence of moisture c- Heating at high temperatures d- All of the above 5- When oils and fats are heated strongly, they decompose with the production of: a- Free fatty acids b- Glycerol c- Acrolein d- All of the above 6- Unsaponifiable part in an oil or fat is: a- Glyceride part or ester part b- Non-glyceride or no-ester part. c- Ester of fatty acids and long chain alcohol. d- All of the above 7- The following are unsaponifiable part of oils and fats Except: a- Steroids. b- Vitamins, A, D and E. c- Hydrocarbons d- Glycerides 8- Oils and fats are: a- Simple triglycerides b- Diglycerides c- Mixture of mixed triglycerides d- Monoglycerides 9- The carbon atoms in fatty acids are: a- Odd number arranged in branched chain and carboxylic group. b- Even number arranged in straight chain and carboxylic group. c- ester of alcohols and acids d- None of the above 10- The difference between the point of incipient fusion and complete fusion is known as: a- Refractive index b- Melting point c- Solidifying point d- None of the above 11- Saponification value is defined as, the number of mg of alcoholic KOH required to: a- Neutralize the free fatty acids present in 1 gm oil or fat. b- Hydrolize and react with the glycerides present in 1 gm oil or fat. c- Both a and b. d- None of the above 12- Presence of mineral oil as an adulterant in vegetable oil will: a- Decrease the S.V. b- Decrease the I.V. c- Both a and b. d- Increase I.V. and S.V. 13- The degree of unsaturation is measured in terms of, the weight of halogen fixed by; a- One gram of oil b- 5 gm of oil c- 100 gm of oil. d- All of the above 14- Oils having high I.V. are classified as: a- Non-drying oils b- Semi-drying oils c- Drying oils d- None of the above 15- Waxes has: a- Very small I.V. b- High I.V. c- I.V. similar to that of vegetable oils d- None of the above 16- Animal fat and butter have: a- High I.V. b- Zero I.V. c- Low I.V. d- None of the above 17- Iodine and thiocyanogen are added to the double bonds present in linoleic acid as follows: a- Both adds and saturate the two double bonds b- Thiocynogen adds to the two double bonds, while iodine adds to one. c- Both adds and saturate one of the two double bonds d- Iodine saturate the two double bonds, while (SCN)2 adds to one. 18- Diene value is useful for: a- Conjugated double bonds. b- Isolated double bonds c- Saturated fatty acids d- All of the above 19- The glycerides of butter fat contain: a- High % of long chain fatty acids b- Low % of short chain fatty acids. c- High % of short chain fatty acids d- None of the above. 20- Acetyl value equal: a- S.V. for acetylated hydroxyl fatty acids b- S.V. of non acetylated oil c- S.V. for acetylated oil - S.V. of non acetylated oil d- None of the above True and False Statements 1- Rancidity which leads to formation of low molecular weight fatty acids results in decrease in the S.V. 2- S.V. Is useful in the identification of oils and fats. 3- Oils with high I.V. are liable to rancidity and are liquids at room temperature. 4- Thiocyanogen is obtained by the reaction of Br2 with Pb(SCN) 2 in ether. 5- I.V and Thiocynogen value are equal when determined for lenoleinic acid. 6- the glycerides of butter fat contain low percentage of short chain fatty acids and its S.V. is low. Give reasons: 1- Rancidity increases acetyl value. 2- In the determination of S.V., Ph.Ph. is used as indicator (M.O. can not be used), when excess potassium hydroxide is back titrated with standard HCl solutin. 3- Alcoholic KOH is used for the S.V. of oils and fats, while aqueous KOH is used for saponification of oils and fats in case of Richert-Meissel value. 4- Iso-oleic acid present in hydrogenated fats, not present in natural oil or fat. 5- During hydrogenation of oils, the mixture of oil, Ni, and hydrogen, is heated just to start hydrogenation and further heating is not necessary. Write short notes on: 1- Oxidative rancidity 2- a- Define, Polenske and Kirchener values. b- Pro-oxidants and anti oxidants 3- Detection of hydrogenated oils in butter fat