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Transcript
10-11-16
•  Whatisthebasicstructureoftheatomaswe
knowittoday?Describethepartsofanatom
withasmuchdetailasyoucan...
Chapter4
EarlyTheoriesofMaAer
Democritus(400-370BC)–firstto
proposethatmaAernotinfinitelydivisible.
•  BelievedmaAermadeofparFcleshecalled
“atomos”.
•  MaAercomposedofemptyspacethrough
whichatomsmove.
•  AtomsindestrucFbleandindivisible.
EarlyTheoriesofMaAer
JohnDalton(1766-1844)–school
teacherandscienFst.
•  Dalton’satomictheorybasedonDemocritus’s
ideas.
•  AllmaAermadeofsmallparFclescalledatoms.
•  AtomsofagivenelementareidenFcal.
EarlyTheoriesofMaAer
Daltonalsopostulatedthat:
•  Atomscannotbecreated,destroyed
ordividedintosmallerpieces.
•  AtomscancombineinwholenumberraFos.
•  Inchemicalrxns,atomsareseparated,
combinedorrearranged.
DefiningtheAtom
•  Atom:ThesmallestparFcleofanelement
thatretainstheproperFesoftheelement.
•  BecauseofDalton’satomictheory,most
scienFstsin1800sbelievedthattheatomwas
likeaFnysolidballthatcouldnotbebroken
upintoparts.
•  NowknowthattheatomisNOTindestrucFble
orindivisible(subatomicparFcles)
EarlyExperimentstoDescribetheAtom
•  J.J.Thomsonusedcathoderaytube
tostudyatoms.
•  Showedthatthereweresmaller
parFclesinatoms.ThoseparFcles
latercametobeknownaselectrons.
•  LaterEugeneGoldsteinfound
parFclesflowinginother
direcFon.FirstindicaFonof
posiFveparFcles(protons).
J.J.Thomson
CathodeRayTube
TheAtomaround1900
•  Theprevailingtheory
wasthatofthe“plum
pudding”model,put
forwardbyJ.J.Thomson.
•  ItfeaturedaposiFve
sphereofmaAerwith
negaFveelectrons
imbeddedinit.
DiscoveryoftheNucleus
•  ErnestRutherford
shotαparFcles
atathinsheetof
goldfoiland
observedthe
paAernofscaAer
oftheparFcles.
DiscoveryoftheNucleus
DiscoveryoftheNucleus
•  SincesomeparFcles
weredeflectedatlarge
angles,Thomson’s
model(plumpudding
model)couldnotbe
correct.
TheNuclearAtom
•  Rutherfordpostulatedaverysmall,dense
nucleuswiththeelectronsaroundthe
outsideoftheatom.
•  Mostofthevolumeoftheatomisempty
space.
AtomicComposiFon–WhatWeKnow
Theatomismostlyemptyspace
• Protonsandneutronsinthenucleus.
• Numberofelectronsisequaltothe
numberofprotons.
• Electronsfoundinspace
aroundthenucleus.