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Name: Electrons Review This review is not all-inclusive. I. Vocabulary – Be sure that you can describe the following items and explain their significance to the unit to someone else. Amplitude Wavelength Frequency Hertz Electromagnetic radiation Electromagnetic spectrum Atomic emission spectrum Ground state Excited state Quantum Photons Heisenberg uncertainty principle Electron configuration Energy level / shell Sublevel Orbital II. Concepts – Discuss the following items with a classmate to ensure that you have a thorough knowledge of each. 1. Describe energy. What is it? Units? 2. Explain the work / contributions of each of the following scientists: Rutherford Planck Can you make connections between Bohr each scientist’s ideas related to electron behavior? How did each further the Einstein work of those before him? de Broglie Heisenberg Schrödinger 3. Use a labeled diagram of a Bohr atom to explain how emission spectra are used to study electrons. 4. Compare and contrast the Bohr model with the quantum mechanic model of the atom. 5. Describe each of the following rules governing electron configurations: Aufbau principle Can you illustrate each rule with an Pauli exclusion principle orbital drawing? Can you draw an orbital Hund’s rule that violates each rule? Cr / Cu exception 6. Create a list of steps for properly labeling and numbering a periodic table so that it can be used as a shortcut for writing electron configurations. Have a classmate check your steps by following them as written. 7. Answer each of the following in terms of “n”: Maximum # of electrons in a shell Maximum # of subshells in a shell Maximum # of orbitals in a shell _______ _______ _______ What does “n” tell you? Are you familiar with the terms used in this section? 8. Draw sketches of the orbitals in the following sublevels: s, p, d III. Gizmos u: haydenchem p: chemistry 1. Revisit the ExploreLearning Gizmos completed in class. 2. Can you explain the fundamental concepts involved? Can you complete the assessment questions at the end? IV. Wave Relationships 1. Draw a graph showing the relationship between each pair of terms. 1. Energy / Frequency 2. Energy / Wavelength 3. Frequency / Wavelength Which relationships are directly proportional? What equation is associate with each relationship? V. Practice Problems – Answers must include the appropriate unit. 1. The yellow light given off by a sodium vapor lamp used for public lighting has a wavelength of 589 nm. What is the frequency of this radiation? 2. A laser used in eye surgery to fuse detached retinas produces radiation with a frequency of 4.69 x 1014 Hz. What is the wavelength of this radiation in nanometers? 3. Calculate the smallest increment of energy, that is, the quantum energy, that an object can absorb from yellow light whose wavelength is 589 nm. 4. A laser emits light with a frequency of 4.69 x 1014 s-1. What is the energy of one quantum of this energy? The laser emits its energy in pulses of short duration. If the laser emits 1.3 x 10-2 J of energy during a pulse, how many quanta of energy are emitted during the pulse? 5. What wavelength of radiation has photons with energy of 5.44 x 10-18 J? In what portion of the electromagnetic spectrum would this radiation be found? 6. Excited mercury atoms emit light strongly at a wavelength of 436 nm. What is the frequency of this radiation? 7. Calculate and compare the energy of a photon of wavelength 3.3 μm with that of wavelength 0.154 nm. VI. Electron Configurations – For each of the following atoms, provide: a. Orbital notation b. Electron configuration c. Noble gas shorthand 1. 2. 3. 4. 5. 6. 7. B Ga Sr No Mn Bi #118