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Name: __________________________________ Crowsnest Consolidated High School Science 10 Unit A Work booklet Mr. R. Peebles Science 10 – Unit A 1 Mr. R. Peebles Name: __________________________________ Unit A—Energy and Matter in Chemical Change W ORKSHEET 1 Science Laboratory Safety Rules 1. 2. 3. 4. 5. 6. Read all written instructions carefully before doing an activity. Listen to all instructions and follow them carefully. Wash your hands thoroughly after each activity and after handling chemicals. Wear safety goggles, gloves, or an apron as required. Think before you touch. Equipment may be hot and substances may be dangerous. Smell a substance by fanning the smell toward you with your hand. Do not put your nose close to the substance. 7. Do not taste anything in the lab. 8. Tie back loose hair and roll up loose sleeves. 9. Never pour liquids into containers held in your hand. Place a test tube in a rack before pouring substances into it. 10. Clean up any spilled substances immediately as instructed by your teacher. 11. Never look into test tubes or containers from the top. Always look through the sides. 12. Never use cracked or broken glassware. Make sure you follow your teacher’s instructions when getting rid of broken glass. 13. Label any container you put chemicals in. 14. Report all accidents and spills immediately to your teacher. 15. Read the WHMIS (Workplace Hazardous Materials Information System) safety symbols on any chemical you will be using and make sure you understand all of them. See Student Reference 1 at the back of Science 10 for more information. Science 10 – Unit A 2 Mr. R. Peebles Name: __________________________________ MSDS Unit A—Energy and Matter in Chemical Change W ORKSHEET 2 MATERIAL SAFETY DATA SHEET 12% SODIUM HYPOCHLORITE Section I: IDENTIFICATION PRODUCT: sodium hypochlorite (12% solution) SYNONYMS: sodium hypochlorite (12% available chlorine), Javel water, liquid bleach CHEMICAL FORMULA: NaOClO PRODUCT CODE NO.: 17547 Section II: HAZARDOUS INGREDIENTS COMPOSITION: sodium hypochlorite solution 10–15 % HAZARDS: oxidizer, corrosive Section III: EMERGENCY OVERVIEW Warning! Harmful if swallowed or inhaled. Causes irritation to eyes and respiratory tract. Causes substantial but temporary eye injury. Section IV: POTENTIAL HEALTH EFFECTS & FIRST AID MEASURES INHALATION: Poisonous vapour. Increasing doses may cause irritation of nose and throat, coughing, headaches, breathing difficulty, pulmonary edema, and lung injury. Remove patient to fresh air. Have patient rest and keep warm. Seek medical attention if symptoms are severe. INGESTION: Poisonous. Causes burns, abdominal cramps, nausea, vomiting, lowered blood pressure, diarrhea, and shock. If patient is conscious, give 1–2 glasses of milk. Do not induce vomiting. Seek medical attention. EYE CONTACT: Burns, irritation. Rinse with water for at least 15 minutes. Seek medical attention. SKIN CONTACT: Burns, irritation. Rinse with plenty of water. Wash contaminated clothing before reuse. Section V: PHYSICAL DATA BOILING POINT: 101oC, starts decomposing to NaCl and NaClO3 at 40oC FREEZING/MELTING POINT: −25°C VAPOUR DENSITY (AIR=1): 1.3 VAPOUR PRESSURE: 17.5 mm Hg at 20°C SOLUBILITY IN WATER: fully miscible SPECIAL FIRE FIGHTING PROCEDURES & PRECAUTIONS: Wear self-contained breathing apparatus. UNUSUAL FIRE & EXPLOSION HAZARDS: May release chlorine gas Section VI: REACTIVITY STABILITY: Inherently unstable; slowly decomposes liberating Cl 2; unstable above 40°C CONDITIONS & MATERIALS TO AVOID: Temperatures above 40 oC, direct sunlight, acids, metals, ammonia, oxidizable materials, urea HAZARDOUS DECOMPOSITION PRODUCTS: Cl2 Science 10 – Unit A 3 Mr. R. Peebles Name: __________________________________ continued... Section VII: EMPLOYEE PROTECTION CONTROL MEASURES: Use with adequate ventilation. RESPIRATORY PROTECTION: Use chlorine gas respirator. PROTECTIVE CLOTHING: Neoprene, rubber or plastic gloves, use plastic sleeves, apron and boots if handling large quantity. EYE PROTECTION: Safety goggles Section VIII: ENVIRONMENTAL PROTECTION ENVIRONMENTAL PRECAUTIONS: Local exhaust acceptable SPILL OR LEAK PRECAUTIONS: Wear gloves, boots, apron and goggles during clean-up. WASTE DISPOSAL: Small spills: mop up with water and run to waste. Large spills: transfer to salvage container and consult with professional disposal company. Inform local authorities if liquid has entered surface drains or sewers. Section IX: REGULATORY CONTROLS DEPT. OF TRANSPORTATION: Regulated under Transport of Dangerous Goods DOT CLASSIFICATION: Class 8 (9.2) UN: 1791 PG: III DOT PROPER SHIPPING NAME: Hypochlorite solutions OTHER DOT INFORMATION: N/A WHMIS CLASSIFICATION: C, E, F OTHER REGULATORY REQUIREMENT: none Section X: PRECAUTIONS: HANDLING, STORAGE, AND USAGE Store in cool, dry place away from acids. Do not store in metal containers. Use in well-ventilated area. Science 10 – Unit A 4 Mr. R. Peebles Name: __________________________________ SAFETY Unit A—Energy and Matter in Chemical Change W ORKSHEET 3 WHMIS and Hazardous Household Product Symbols Goal Review the meanings of warning labels in the science classroom and at home. Think About It Throughout Canada, standard symbols are used to identify dangerous materials The Workplace Hazardous Materials Information System (WHMIS) has produced symbols for such work places as science laboratories. These are known as WHMIS symbols. The Hazardous Household Product Symbols (HHPS) were developed for people buying and using materials around the home. WHMIS Both sets of symbols provide warnings about the possible hazards of using certain products, as well as the necessary precautions to take. What to Do Reinforce your understanding of WHMIS symbols and HHPS symbols by reading “Safety Symbols” on page 455 in your SCIENCE 10 textbook reviewing all the WHMIS symbols and HHPS symbols answering the questions that begin on the next page HHPS continued... Science 10 – Unit A 5 Mr. R. Peebles Name: __________________________________ 1. Briefly explain what kind of hazard each word describes. (a) toxic (b) flammable (c) explosive (d) reactive (e) corrosive 2. In the space provided, draw the standard WHMIS symbol for each material. Corrosive Material Flammable and Combustible Material Compressed Gas 3. Choose two WHMIS symbols you did not use to answer question 2. Describe some precautions you would take when handling a product labelled with each symbol. WHMIS symbol Meaning Precautions (a) (b) continued... Science 10 - Unit A 6 Mr. R. Peebles Name: __________________________________ 4. Study the display your teacher has provided, showing products that many people use in their homes. Look for symbols that are HHPS. Read the label on each product to find out how the product is used and decide why it has an HHPS. Complete the table below. HHPS How product used Suggested precautions (a) (b) (c) Science 10 - Unit A 7 Mr. R. Peebles Name: __________________________________ PRACTICE QUESTIONS Unit A—Energy and Matter in Chemical Change W ORKSHEET 4 Nuclear Notation Atomic Number and Mass Number Mass Number Atomic Number Number of Protons Number of Neutrons carbon-14 14 6 6 8 hydrogen-1 1 1 hydrogen-2 2 1 4 20 2 10 64 29 35 45 7 7 16 16 20 21 Name carbon-12 oxygen-18 9 10 26 30 53 74 calcium-40 119 50 26 208 33 82 silver-108 mercury-201 Science 10 - Unit A 8 Mr. R. Peebles Name: __________________________________ PRACTICE QUESTIONS Unit A—Energy and Matter in Chemical Change W ORKSHEET 5 Nuclear Notation 1. State the number of neutrons in each of the following isotopes. a) 2210 Ne b) 42 He c) 4020 Ca 27 d) 13 Al 2. State the number of each of the following subatomic particles in oxygen-17. a) protons b) electrons c) neutrons 3. A certain isotope has a mass number of 35. The isotope has 18 neutrons. a) What is the atomic number of the isotope? b) What is the atomic symbol of the isotope? c) Use nuclear notation to represent the isotope. Science 10 - Unit A 9 Mr. R. Peebles Name: __________________________________ PRACTICE QUESTIONS Unit A—Energy and Matter in Chemical Change W ORKSHEET 6 Bohr Models & EELR (Electron Energy Level Representations) Bohr Models are diagrams used to represent the placement of electrons around the nucleus of an atom. Electrons are arranged around the nucleus in varying ENERGY LEVELS. We will use rings around the nucleus to represent where we may find the electrons. To draw Bohr Models: 1. Draw a nucleus (circle) and write in the number of protons and neutrons for the specific element. Ex. Carbon - 12 6 p+ 6 n0 2. Count which period the element is located. The number of periods represents the number of energy levels that element contains. (a) ex. Carbon is in period 2 = 2 energy levels. (b) draw dashed rings to represent the levels 6 p+ 6 n0 3. To add in the electrons (e-) use the atomic number, this is equal to the number of electrons in the element, to determine how many electrons to add. (a) Use a dot, ● = e-. Carbon: atomic number = 6 = 6 electrons. (b) One pair of electrons on each side of the level, 1st level 2 e-, 2nd level 8 e-, 3rd level 8 e-, etc. Energy levels can only hold a max. of 8 electrons (except for the 1 st), this referred to the Octet Rule. 6 p+ 6 n0 ASSIGNMENT: On loose-leaf paper, divide the sheet into 3 columns (see example table) Complete the table for elements 1-20 from the periodic table (leave EELR column blank) Element Hydrogen # protons = # electrons= # neutrons= Bohr Model EELR Will be completed at a later time helium# protons = # electrons= # neutrons Science 10 - Unit A 10 Mr. R. Peebles Name: __________________________________ PRACTICE QUESTIONS Unit A—Energy and Matter in Chemical Change W ORKSHEET 7 Electron Dot Diagrams Goal Demonstrate your understanding of energy levels, and practice drawing electron dot diagrams. What to Do Answer each question in the space provided. 1. Complete the following table. Name of element Period number hydrogen Group number Number of energy levels Number of valence electrons 3 3 1 2 6 strontium 14 6 3 2 2. Complete the following table by drawing both the energy level diagram and electron dot diagram for each element. The first row is completed as an example. Energy level diagram Electron dot diagram Name of element carbon oxygen lithium Science 10 - Unit A 11 Mr. R. Peebles Energy level diagram Name: __________________________________ Electron dot diagram Name of element chlorine magnesium phosphorus 3. Draw the missing electron dot diagrams in the following table. Refer to the periodic table as necessary. 4. What feature of helium’s energy levels justifies placing its two valence electrons in a pair? (See the table above.) 5. Draw an electron dot diagram for an atom of each of the following elements. selenium (Se) bromine (Br) strontium (Sr) radon (Rn) francium (Fr) 6. Explain how you decided on the number and placement of the dots. Science 10 - Unit A 12 Mr. R. Peebles Name: __________________________________ PRACTICE QUESTIONS Unit A—Energy and Matter in Chemical Change W ORKSHEET 8 Ions and Isotopes What to Do Answer each question in the space provided. 1. Complete the following table by filling in the missing information about ions. Symbol Number of protons Number of electrons Ion charge Li+ 3 2 1+ 19 18 1+ Name of ion lithium ion Mg2+ chloride ion 9 1– O2– I– scandium ion 18 2– Se2– 7 10 Al3+ 10 4– calcium ion phosphide ion continue… Science 10 - Unit A 13 Mr. R. Peebles Name: __________________________________ 2. Complete the following table by drawing the EELR. The first row is completed as an example. Ion Symbol Lithium ion EELR Diagram Ion Symbol EELR Diagram Aluminum ion + Li Oxide ion Calcium ion Iodide ion Chloride ion Sodium ion Beryllium ion 3. What is a common feature in all of the EELR diagrams in question 2? (Hint: think “levels”) _______________________________________________________________________________________________ _______________________________________________________________________________________________ Science 10 - Unit A 14 Mr. R. Peebles Name: __________________________________ PRACTICE QUESTIONS Unit A—Energy and Matter in Chemical Change W ORKSHEET 9 Ionic Compounds Part 1: Modelling Ionic Bonds Model the formation of of the following ionic compounds using electron dot diagrams. Write the electron dot diagram for each element in the name. Show the transfer of electrons and the formation of the ionic compound. 1. lithium hydride 4. sodium fluoride continue… Science 10 - Unit A 15 Mr. R. Peebles Name: __________________________________ 5. calcium oxide 6. magnesium chloride 7. aluminium oxide Science 10 - Unit A 16 Mr. R. Peebles Name: __________________________________ PRACTICE QUESTIONS Unit A—Energy and Matter in Chemical Change W ORKSHEET 10 Ionic Compounds 1. Complete the following table. Element Anion Name Symbol Name Symbol fluorine F fluoride F– chloride bromide oxide sulfide nitride 2. Complete the following table. Formula Total charge on cation(s) Total charge on anion(s) Correct () or incorrect (X) formula? Correct formula and name of compound (a) LiO (b) MgO (c) K2S (d) AlBr3 (e) NaN3 continue… Science 10 - Unit A 17 Mr. R. Peebles Name: __________________________________ 3. Complete the following table to write the formula of each compound. Name of compound Cation Anion Formula (a) beryllium fluoride (b) sodium nitride (c) calcium sulfide (d) aluminum chloride (e) lithium oxide (f) magnesium nitride (g) gallium sulfide (h) barium bromide 4. Write the chemical formula of the following. Include the state. a) lithium hydride f) magnesium chloride b) silver chloride g) aluminum hydride c) sodium oxide h) barium sulfide d) calcium phosphide i) strontium phosphide e) sodium iodide j) potassium phosphide continue… Science 10 - Unit A 18 Mr. R. Peebles Name: __________________________________ 5. Write the proper chemical name of the following: a) NaCl(s) f) ScCl3(s) b) Al2S3(s) g) AlF3(s) c) MgI2(s) h) LiBr(s) d) Zn3As2(s) i) Na2S(s) e) CsF(s) j) BaI2(s) 6. Complete the following table to find the charge on the cation in these compounds. Decide if your answers are reasonable before you move on to question 7. Compound Charge on cation (a) Cu2S (b) Cr2O3 (c) PbO2 (d) NiCl2 (e) CrN (f) HgO 7. Complete the following table by adding the missing Stock system names. Formula Ion Name FeCl3 Fe3+ iron(III) chloride FeO Fe2+ Cu2S Cu + PbO 2 Pb 4+ continue… Science 10 - Unit A 19 Mr. R. Peebles Name: __________________________________ 8. Complete the following table to write the chemical formula for each compound. Name of compound Cation Anion Chemical formula (a) copper(I) oxide (b) lead(IV) bromide (c) iron(III) sulfide (d) nickel(III) fluoride (e) manganese(IV) sulfide 9. Write the chemical formula of the following (Remember: Stock System). Include the state. a) chromium(II) oxide f) vanadium(V) oxide b) tin(II) iodide g) copper(I) bromide c) copper(II) selenide h) lead(IV) oxide d) iron(III) chloride i) chromium (III) phosphide e) mercury(I) sulfide j) bismuth(III)selenide 10. Write the proper chemical name of the following: (Remember: Stock System). a) MnCl4(s) h) SnCl4(s) b) CuBr2(s) i) Hg2S (s) c) FeO (s) j) Ni2S3(s) continue… Science 10 - Unit A 20 Mr. R. Peebles Name: __________________________________ d) CoCl2(s) k) FeBr3(s) e) Hg3P2(s) l) CuCl2(s) f) Fe2O3(s) m) BiF5(s) g) TiO2(s) n) SnS2(s) Analyze 1. Explain why you must use the Stock system to name ionic compounds containing transition metals. In which cases do you not need to use the Stock system to name an ionic compound? Explain your answer. 2. There is something wrong with the name written beside each of the following compounds. In each case, explain why the name is wrong, and then write the correct name. Formula Incorrect name (a) Ti2O3 dititanium trioxide (b) NaCl sodium(I) chloride (c) CuCl2 copper chloride (d) NO2 nitrogen(IV) oxide Science 10 - Unit A Explanation 21 Correct name Mr. R. Peebles Name: __________________________________ PRACTICE QUESTIONS Unit A—Energy and Matter in Chemical Change W ORKSHEET 11 Polyatomic Ionic Compounds 1. Write the chemical formula of the following. Include the state. a) mercury(II) borate m) calcium hydrogen carbonate b) zinc dihydrogen phosphate n) barium chromate c) calcium sulfite o) silver dichromate d) iron(III) nitrate p) lead(IV) carbonate e) chromium(III) iodate q) tin(II) oxalate f) sodium borate r) sodium silicate g) zinc sulfate s) barium cyanide h) strontium acetate t) sodium silicate i) antimony (V) iodate u) cobalt(II) nitrate j) zinc phosphate v) hydrogen hypochlorite k) cesium borate w) silver acetate continue… Science 10 - Unit A 22 Mr. R. Peebles Name: __________________________________ 2. Write the proper chemical name of the following: a) K3PO4(s) k) Al2(SO4)3(s) b) PbCr2O7(s) l) CuMnO4(s) c) Co3(PO4)2(s) m) Hg(NO3)2(s) d) Fe2(CO3)3(s) n) Pb(CrO4)2(s) e) Sn(HSO 4)2(s) o) NiCO3(s) f) Cu3PO4(s) p) Ag2SO 4(s) g) Fe(HCO3)3(s) q) PbSO 4(s) h) Cr2(CO3)3(s) r) Ni3(PO4)2(s) i) Sr(IO3)2(s) s) CuSO4(s) j) Hg(ClO3)2(s) t) Sb2(HPO4)3 Science 10 - Unit A 23 Mr. R. Peebles Name: __________________________________ PRACTICE QUESTIONS Unit A—Energy and Matter in Chemical Change W ORKSHEET 12 Molecular Compounds Part 2: Modelling Covalent Bonds Model the formation of of the following molecular compounds using electron dot diagrams. Write the electron dot diagram for each element in the name. Show the sharing of electrons and the formation of the molecular compound. 1. molecular hydrogen 2. water, H2O 3. methane, CH4 Science 10 - Unit A 24 Mr. R. Peebles Name: __________________________________ 4. molecular oxygen 5. molecular nitrogen 6. carbon disulfide Science 10 - Unit A 25 Mr. R. Peebles Name: __________________________________ PRACTICE QUESTIONS Unit A—Energy and Matter in Chemical Change W ORKSHEET 13 Naming Molecular Compounds 1. Write the chemical formula of the following: a) sulfur hexafluoride g) dinitrogen hexabromide b) carbon dioxide h) sulfur dioxide c) dinitrogen monoxide i) carbon monoxide d) arsenic tribromide j) tetraphosphorous decaoxide e) tetranitrogen hexahydride k) dinitrogen pentachloride f) disulfur hexafluoride l) carbon tetrachloride 2. Write the proper chemical name of the following: a) P2Cl5 g) SiS2 b) NCl3 h) OCl2 c) CS2 i) NO2(g) d) ClBr2 j) P2O5 e) NO(g) k) SF6 f) N2O4 l) PBr5 Science 10 - Unit A 26 Mr. R. Peebles Name: __________________________________ PRACTICE QUESTIONS Unit A—Energy and Matter in Chemical Change W ORKSHEET 14 Review: Naming Ionic and Molecular Compounds Complete the following table. Chemical formula Ionic or molecular? Name of compound NH4Cl potassium sulfide CI4 calcium oxide ammonium chloride Li3N Mg(OH)2 zinc oxide CuNO 3 silicon dioxide oxygen dichloride CuCl FeCl2 calcium sulfide calcium hydrogencarbonate P2O5 silicon tetrabromide aluminium bromate Ca(HS)2 ammonium nitrite AgCH3COO calcium chromate N2O5 iron(III) carbonate HgS silver hydrogensulfate continue… Science 10 - Unit A 27 Mr. R. Peebles Name: __________________________________ Chemical formula Ionic or molecular? Name of compound KMnO 4 Mg(OH)2 AlPO4 carbon disulfide potassium sulfate SnF2 K2Cr2O 7 HgS sodium tetraborate vanadium(V) oxide (NH4)2Cr2O7 bismuth(V) phosphate Na2SiO 3 Co3(PO 4)2 Science 10 - Unit A 28 Mr. R. Peebles Name: __________________________________ PRACTICE QUESTIONS Unit A—Energy and Matter in Chemical Change W ORKSHEET 15 Solubility Table Goal Predict solubility using a solubility table. What to Do Use the following solubility table to complete the tables below. NH4+ NO3– CH3COO– Cl– SO 42– S2– OH– CO32– Ions all ClO3– Br– PO43– ClO4– I– SO32– all most most most group 1 group 1 group 1 group 2 NH4+ NH4+ NH4+ Sr2+ High solubility Ba2+ Tl+ none none Ag+ Ag+ Ag+ Hg+ Pb 2+ Pb 2+ Cu+ Ca2+ Hg+ Ba2+ Tl+ Sr2+ most most most Low solubility Ra2+ 1. Complete the following table. Cation Anion Na+ Cl– High or low solubility? Name Formula sodium chloride NaCl lithium iodide Mg(ClO3)2 strontium hydroxide BaCO3 continue… Science 10 - Unit A 29 Mr. R. Peebles Name: __________________________________ 2. Complete the following table. Name Formula High or low solubility? Al(OH)3 ammonium chloride K2S molybdenum(V) chlorate Pb(CH3COO)2 copper(II) iodide FeCO3 calcium sulfite Ba3(PO4)2 (s) palladium(II) bromide HgI strontium sulfate Science 10 - Unit A 30 Mr. R. Peebles Name: __________________________________ Unit A—Energy and Matter in Chemical Change Activity Water’s Purpose in a Reaction W ORKSHEET 16 1) Purpose: To examine some of the basic principles of chemical reactions and to make qualitative observations of chemical reactions 2) Design: Two solid substances will be mixed in order to produce a chemical reaction. 3) Materials: a) lead (II) nitrate b) potassium iodide c) Cream of tartar (potassium bitartrate) d) Baking soda (sodium bicarbonate) e) f) g) h) 10 weighing dishes 4 x 30mL beakers Glass stirring rod Scopula 4) CAUTION: LEAD (II) NITRATE AND SODIUM IODIDE ARE STRONG OXIDIZING AGENTS AND MAY IRRITATE OR BURN YOUR SKIN. GLOVES AND GOGGLES ARE MADITORY! FOLLOW ALL PROCEDURES AND DISPOSAL PROCEDURES! 5) Part 1: Lead (II) nitrate and sodium iodide a) A balanced chemical reaction for the mixing of lead (II) nitrate and sodium iodide is provided as followed. Label each compound correctly. (reactants) Pb(NO3)2 (s) +2 KI (s) (products) PbI2 + 2 KNO3 _____________ +______________ _______________ +________________ b) Are the reactants molecular or ionic substances? How do you know? _______________________________________________________________________________________________ ______________________________________________________________________________________________ c) Gather approximately 2 x 0.5 g of each reactant in labelled weighing dishes and return to your work table. CAUTION! Record your observations of the reactants: _______________________________________________________________________________________________ ______________________________________________________________________________________________ d) Combine 0.5 g of each reactant into a separate weighing dish and mix together using a glass stirring rod. Record your observations. _______________________________________________________________________________________________ ______________________________________________________________________________________________ e) In separate 30 mL beakers, dissolve the remaining 0.5 g of each solid in approximately 5 mL of water. Record your observations. _______________________________________________________________________________________________ ______________________________________________________________________________________________ continue… Science 10 - Unit A 31 Mr. R. Peebles Name: __________________________________ f) Pour the potassium iodide solution into the lead (II) nitrate solution and record your observations. _______________________________________________________________________________________________ ______________________________________________________________________________________________ g) Dispose of all liquids and solid waste into the appropriate containers. DO NOT POUR WASTE DOWN THE DRAIN OR PLACE IN THE GARBAGE. 6) Part 2: Baking soda and cream of tartar a) The following balanced reaction is provided for you: name the missing reactants and products. NaHCO3(s) + KHC4H4O6(s) NaKC4H4O6 (aq) + CO2(g) + H2O(l) _______________+potassium bitartrate sodium potassium tartrate + ________________+ ____________ b) Are the reactants molecular or ionic substances? How do you know? _______________________________________________________________________________________________ ______________________________________________________________________________________________ c) Based on the chemical equation, what do you expect to see when you mix the reactants provided? ___________________________________________________________________ d) Gather approximately 2 x 0.5 g of each reactant in labelled weighing dishes and return to your work table. Record your observations of the reactants: _______________________________________________________________________________________________ ______________________________________________________________________________________________ e) Combine 0.5 g of each reactant into a separate weighing dish and mix together using a glass stirring rod. Record your observations. _______________________________________________________________________________________________ ______________________________________________________________________________________________ f) In separate 30 mL beakers, dissolve the remaining 0.5 g of each solid in approximately 5 mL of distilled water. Record your observations. _______________________________________________________________________________________________ ______________________________________________________________________________________________ g) Pour the sodium bicarbonate solution into the potassium bitartrate solution and record your observations. _______________________________________________________________________________________________ ______________________________________________________________________________________________ h) For Part 2 ONLY, all waste may be thrown in the garbage and/or down the drain. continue… Science 10 - Unit A 32 Mr. R. Peebles Name: __________________________________ 7) Between your partner and you, devise a scientific theory for why the solid mixtures not react until you dissolved them in water as you observed in Parts 1 and 2. ____________________________________________________________________________________________ ____________________________________________________________________________________________ ____________________________________________________________________________________________ ____________________________________________________________________________________________ ____________________________________________________________________________________________ ____________________________________________________________________________________________ ____________________________________________________________________________________________ 8) Based on how the reaction actually occurred, copy and rewrite the chemical equations with the appropriate states for each reactant and product as they where in the reaction. a) Part 1: (you will need to use your solubility table to determine which product formed the solid) b) Part 2: Science 10 - Unit A 33 Mr. R. Peebles Name: __________________________________ Unit A—Energy and Matter in Chemical Change Activity Physical or Chemical Reactions? W ORKSHEET 17 What to Do Classify each change in the following table as either chemical or physical. Explain your classification. Chemical or physical? Explanation Change A sheet of paper is crumpled into a ball. A sheet of paper is set on fire and burns to ashes. Steel wool is placed in a glass of salty water. The steel wool rusts. A sheet of flexible, colourless plastic is left outside, in bright sunlight, and becomes yellow and brittle over time. A teaspoon of white sugar (sucrose) dissolves in a glass of warm water. Vinegar is poured over a teaspoon of baking soda. The white powdered baking soda fizzes, and bubbles form. A red-hot nail is inserted into a large block of ice. Steam is formed as the nail contacts the block, and water flows away from the nail. Science 10 - Unit A 34 Mr. R. Peebles Name: __________________________________ Unit A—Energy and Matter in Chemical Change Activity Chemical Reactions W ORKSHEET 18 1. Complete the following tables writing the complete skeleton equation for each question. - Ensure to include: o Proper chemical formulas (remember: Ionic vs. Molecular) o States for each compound or element (refer to periodic table and solubility table) Word equation iron + sulfur → iron(II) sulfide Skeleton equation 2. calcium + oxygen gas → calcium oxide Word equation Skeleton equation 3. Word equation calcium oxide + carbon dioxide → calcium carbonate Skeleton equation 4. copper(II) oxide → copper + oxygen gas Word equation Skeleton equation 5. Word equation water → hydrogen gas + oxygen gas Skeleton equation continue… Science 10 - Unit A 35 Mr. R. Peebles Name: __________________________________ 6. potassium + water → potassium hydroxide + hydrogen gas Word equation Skeleton equation 7. Word equation zinc + tin(II) chloride → zinc chloride + tin Skeleton equation 8. Word equation copper + silver nitrate → copper(II) nitrate + silver Skeleton equation 9. Word equation potassium iodide + lead(II) nitrate → potassium nitrate + lead(II) iodide Skeleton equation 10. Word equation sodium chloride + silver nitrate → sodium nitrate + silver chloride Skeleton equation 11. Word equation barium chloride + potassium sulfate → barium sulfate + potassium chloride Skeleton equation continue… Science 10 - Unit A 36 Mr. R. Peebles Name: __________________________________ 12. Refer back to your chemical reactions, 1-11. What do the reactions in each group have in common? Reactions Similarities among reactions 1, 2, and 3 4 and 5 6, 7, and 8 9, 10, and 11 13. Develop a classification system for the chemical reactions you observed in this activity. continue… Science 10 - Unit A 37 Mr. R. Peebles Name: __________________________________ 14. Write the skeleton equations 1-11 on the following page. Using the pipe cleaners to assist you, devise a method to ensure that the Law of Conservation of Matter (the number of atoms in the reactants must equal the number of atoms in the products) remains true for each equation. Equation # Skeleton Equation 1 Fe (s) + S8 (s) FeS (s) 2 3 4 5 6 7 8 9 10 11 Science 10 - Unit A 38 Mr. R. Peebles Name: __________________________________ Unit A—Energy and Matter in Chemical Change Activity Balancing Chemical Reactions W ORKSHEET 19 What to Do Answer the questions in each section in the space provided. Balancing Formation Reaction Equations 1. Balance each equation for a formation reaction. (a) K(s) + O2(g) K2O (s) (b) P4(s) + Cl2(g) PCl5(s) (c) Cu(s) + S8(s) CuS(s) (d) Mg(s) + O2(g) MgO(s) (e) Fe(s) + O2(g) Fe2O3(s) (f) P4(s) + S8(g) P2S5(s) (g) C(s) + O2(g) CO(g) (h) N2(g) + O2(g) NO2(g) (i) Li(s) + N2(g) Li3N(s) (j) S8(s) + O2(g) SO2(g) 2. Write a balanced chemical equation to represent each reaction described below. (a) Solid aluminum metal reacts with oxygen gas to form solid aluminum oxide. (b) Metallic zinc combines with elemental sulfur to form zinc sulfide. Balancing Decomposition Reaction Equations 3. Balance each equation for a decomposition reaction. (a) NaCl(s) Na(s) + Cl2(g) (b) CaBr2(s) Ca(s) (c) CCl4(l) C(s) + Cl2(g) (d) NCl3 (g) N2(g) + Cl2(g) + Br2(l) continue… Science 10 - Unit A 39 Mr. R. Peebles Name: __________________________________ (e) P4O10(s) P4(s) + O2(g) (f) Ag2O(s) Ag(s) + O2(g) (g) HCl(aq) H2(g) + Cl2(g) (h) KI(s) K(s) + I2(s) (i) AlCl3(s) Al(s) + Cl2(g) (j) CuO(s) Cu(s) + O2(g) 4. Write a balanced chemical equation to represent each reaction described below. (a) Rubidium oxide decomposes into its elements. (b) Calcium chloride decomposes into its elements. Balancing Single Replacement Reaction Equations 5. Balance each equation for a single replacement reaction. (a) K(s) + H3PO4(aq) K3PO4(aq) + H2(g) (b) Fe(s) + H2S(aq) Fe2S3(s) + H2(g) (c) Cl2(g) + MgBr2(aq) MgCl2(aq) + Br2(aq) (d) Cu(s) + Ag2CO3(s) CuCO3(s) + Ag(s) (e) Br2(g) + KI(aq) I2(aq) + KBr(aq) (f) Mg(s) + Zn3(PO4)2(s) Mg3(PO4)2(s) + Zn(s) (g) K(s) + Al(NO3)3(aq) Al(s) + KNO3(aq) (h) Ca(s) + H2O(l) Ca(OH)2(s) + H2(g) (i) Na(s) + H2SO4(s) Na2SO 4(aq) + H2(g) (j) K(s) + H2O(l) KOH(aq) + H2(g) 6. Write a balanced chemical equation to represent each reaction (a & b) described below. (a) Silver reacts with gold(III) nitrate. continue… Science 10 - Unit A 40 Mr. R. Peebles Name: __________________________________ (b) Copper reacts with lead(II) sulfate. Balancing Double Replacement Reaction Equations 7. Balance each equation for a double replacement reaction. (a) Na2SO 4(aq) + BaCl2(aq) BaSO4(s) + NaCl(aq) (b) HNO3(aq) + Ba(OH)2(aq) H2O(l) + Ba(NO3)2(aq) (c) Na2CO3(aq) + Fe(NO3)3(aq) Fe2(CO3)3(s) + NaNO3(aq) (d) CaCl2(aq) + K3PO 4(aq) Ca3(PO4)2(s) + KCl(aq) (e) Al2(SO4)3(aq) + Ba(OH)2(aq) Al(OH)3(s) + BaSO 4(s) (f) NaOH(aq) + H2SO 4(aq) H2O(l) + Na2SO4(aq) (g) Na3PO 4(aq) + Ag2SO4 (s) Na2SO4(aq) + Ag3PO4(s) (h) Na2CrO4(aq) + Cu(NO 3)2(aq) NaNO3(aq) + CuCrO4(aq) (i) H3PO4(aq) + KOH(aq) H2O(l) + K3PO 4(aq) (j) Na2CO3(aq) + HNO3(aq) H2CO3(aq) + NaNO3(aq) 8. Write a balanced chemical equation to represent each reaction described below. (a) Solutions of sodium hydroxide and hydrochloric acid react. (b) A silver nitrate solution reacts with a sodium chloride solution. Balancing Combustion Reaction Equations 9. Balance each equation for a combustion reaction. (a) C2H6(g) + O2(g) CO2(g) + H2O(g) (b) C3H8(g) + O2(g) CO2(g) + H2O(g) (c) C6H14(g) + O2(g) CO2(g) + H2O(g) (d) C8H18(g) + O2(g) CO2(g) + H2O(g) (e) C2H2(g) + O2(g) CO2(g) + H2O(g) (f) C2H4(g) + O2(g) CO2(g) + H2O(g) continue… Science 10 - Unit A 41 Mr. R. Peebles Name: __________________________________ (g) ZnS(s) + O2(g) ZnO(s) + SO2(g) (h) CH3NO2(l) + O2(g) CO2(g) + H2O(g) (i) NH3(g) + O2(g) NO2(g) + H2O(g) (j) C2H5SH(g) + O2(g) CO2(g) + H2O(g) + NO2(g) + SO2(g) 10. Write a balanced chemical equation to represent each reaction described below. (a) Candle wax, C25H52, is burned to produce carbon dioxide and water. (b) Sucrose, C12H22O11, is burned to produce carbon dioxide and water. Classifying and Balancing Equations 11. Classify each reaction as a formation (F), decomposition (D), single replacement (SR), double replacement (DR), or combustion (C) reaction. Then balance each equation. Reaction Classification Li(s) + AlCl3(aq) Al (s) NH3(g) N2(g) + H2(g) K(s) + Br2(l) KBr(s) C10H22(l) + O2(g) NH4OH (aq) + H2CO3(aq) H2O (l) Al(s) Zn(s) + LiCl(aq) CO2(g) + H2O(g) H2O(l) + (NH4)2CO 3(aq) H2(g) + O2(g) + Cl2(g) AlCl3(s) + SnF4(aq) Sn(s) + ZnF2(aq) Science 10 - Unit A 42 Mr. R. Peebles Name: __________________________________ Unit A—Energy and Matter in Chemical Change Activity Mole Calculations W ORKSHEET 20 Find the molar mass of each of the following elements. 1. potassium , K(s) 2. zirconium, Zr(s) 3. chlorine, Cl2(g) 4. oxygen, O 2(g) Determine the molar mass of each of the following compounds. 5. potassium bromide, KBr(s) 6. methane, CH4(g) Science 10 - Unit A 43 Mr. R. Peebles Name: __________________________________ 7. sodium sulfate, Na2SO4(s) 8. aluminum nitrate, Al(NO3)3 (s) Calculate the number of moles in each of the following: 9. 1000 g of NaCl 10. 32.5 g of NaHCO 3(s) 11. 4.69 g of Na2CO3(s) 12. 0.258 g of MgSO 47H2O(s) Science 10 - Unit A 44 Mr. R. Peebles Name: __________________________________ 13. 550 g of sodium phosphate 14. 6.2 g of carbon dioxide 15. 500 mL of water Calculate the mass in grams of the following: 16. 0.21 mol of NaCl(s) 17. 55.56 mol of H2O(l) Science 10 - Unit A 45 Mr. R. Peebles Name: __________________________________ 18. 0.100 mol of KHC4H4O6(s) 19. 1.2 mol of sodium sulphate decahydrate 20. 0.15 mol of phosphorus 21. 0.025 mol of tin (II) fluoride 22. 0.400 mol of calcium sulphate dihydrate Science 10 - Unit A 46 Mr. R. Peebles