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SCI 1.5 (AS90189) – Homework Set 1: ATOMIC STRUCTURE - Solutions QUESTION ONE (2009, Question 1) Question ONE (a) (b) Achievement Excellence ONE Correct Statement. (a) 12 C: 6 protons, 6 neutrons OR 13 C: 6 protons, 7 neutrons OR Electron configuration of 2.4 for both 12C AND 13 C OR An atom is neutral when it has equal numbers of protons and electrons. OR Relevant labelled diagram. Atomic structure and electron configuration given for BOTH 12 C and 13C PLUS an explanation why they are neutral. (m) 12 C: 6 protons, 6 neutrons, electron configuration of 2.4 13 C: 6 protons, 7 neutrons, electron configuration of 2.4 AND 12 C and 13 C are neutral as they both contain equal numbers of protons and electrons. ONE correct statement. (a) Explains how particles contribute to the overall mass. (m) Mass is found by adding up protons and neutrons. OR Electrons have negligible mass (and are not included in mass calculation). OR Protons and neutrons make up (nearly) all the mass. (c) Merit ONE correct statement. (a) 13 N: 7 protons, 6 neutrons (or diagram). OR The mass of 13 N and 13 C are (nearly) the same. OR 12 and 13 refer to total mass of element(s). OR Mass of 13 N is greater than 12C. Explains that the overall mass of an atom is made up of protons and neutrons, as the mass of the electrons is negligible. ONE correct explanation. (m) 13 N will have the same atomic mass as 13 C because the total number of protons and neutrons is the same. OR 13 N is heavier than 12C because it has one extra proton / extra particle. Discusses how the mass of N13 compares to the other isotopes. (e) 13 N will have the same atomic mass as 13 C because the total number of protons and neutrons is the same. AND 13 N is heavier than 12C because it has one extra proton. QUESTION TWO (2008, Question 1a) Question Evidence ONE (a) (b) Diagram showing 8 protons and 10 neutrons in nucleus, with 8 electrons orbiting, 2 in first shell, six in second. Atom is neutral as there are the same number of positive particles / charges / protons as negative particles / charges / electrons. Achievement Merit Correct number of Correct diagram protons, neutrons and AND arrangement of explanation. electrons in diagram (accept conventional symbols (+ for protons, – for electrons), or p / n / e) OR description of same number of protons and electrons /positive and negative particles or charges Excellence QUESTION THREE (2007, Question 1a,b) Q Evidence Achievement 1(a) (i) protons = 19 electrons = 19 neutrons = 20 All correct. (a) (ii) protons and neutrons Both correct. (a) (iii) 2,8,8,1 Correct. (b) Similarities • All three have same number of protons (3). Differences • Number of neutrons are different between 6Li and 7 Li, 6Li has 3, 7Li has 4. • Number of electrons are different between the ion and the atoms. Li+ has 2 electrons whereas 6Li and 7 Li have 3. Either a similarity or difference described or complete description of one species. QUESTION FOUR (2006, Question 1a,b) Question Evidence 1(a) proton + electron neutron Achievement Merit Uses a similarity and a difference to explain atomic structure. Merit Excellence Uses one similarity and two differences, including numbers, to compare and contrast atomic structure. Excellence (a) correct T T 1(b)(i) Diagram showing 12 and 11 + in nucleus; 11 electrons orbit nucleus arranged 2, 8, 1. Electrons correct, ie 2,8,1 configuration. Achievement PLUS 11 protons and 12 neutrons in nucleus. 1(b)(ii) Sodium atom and sodium ion both have 11 protons in nucleus and both have 12 neutrons in the nucleus, ie no differences in nucleus. Sodium atom has one more electron than sodium ion and has three shells containing electrons. PLUS Sodium ion has a positive charge of one, whereas sodium atom is neutral. Comparison between atom and ion of TWO of the 4 criteria (number of protons, neutrons and electrons and charge), eg: Atom loses electron to form ion and they have the same number of protons. OR The atom is neutral it loses 1 electron to become a positive ion. Comparison between atom and ion of THREE of the 4 criteria (number of protons, neutrons and electrons and charge), eg: Atom loses electron to form ion and they have the same number of protons and neutrons. OR Atom has 11 protons, 12 neutrons, 11 electrons and ion has 11 protons, 12 neutrons and 10 electrons. Comparison between atom and ion of FOUR of the 4 criteria (number of protons, neutrons and electrons and charge) with specific details. PLUS The reason behind ion formation based on shells / electron configuration.