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2010 technical documentation BEST OF APPLICATION NOTES Featur e ALL NE s MATERIAW L! TECHSPEC® Diode and Broadband Laser Mirror TECHSPEC® Fused Silica Ball Lenses TECHSPEC® Fused Silica Cylinder Lenses O ssue I 1 0 1 ptics www.edmundoptics.com Table of Contents Anti-Reflection (AR ) Coatings …………………………………………………………….2 Cleaning Optics ……………………………………………………………………………………..5 Metallic Mirror Coatings ……………………………………………………………………….7 Optical Glass ………………………………………………………………………………….………10 Understanding Ball Lenses ……………………………………………………………………14 quickly explain the basics of optical coatings, or provide useful equations for coupling ball lenses to optical fibers – read our Best of EO Application Notes to find out what else! Edmund Optics® presents our top five Optics app notes in an easy to ready, simple PDF format. Selected by our customers over the past year, they represent the most popular app notes in our Technical Library. Forget about searching in those old optics textbooks or surfing the web for a reputable site, let EO make it easy! Look out for upcoming editions, and keep checking our website for new and updated app notes posted regularly. Table of Contents Written by EO engineers for you, our customers, we hope you find these application notes informative and fun. Let us Fellow Tech Geek, Thasha Ramdas Technical Content Editor page 1 www.edmundoptics.com Anti-Reflection (AR) Coatings Edmund Optics® offers all TECHSPEC® transmissive optics with a variety of anti-reflection (AR) coating options that vastly improve the efficiency of the optic by increasing transmission, enhancing contrast and eliminating ghost images. Most AR coatings are also very durable, with resistance to both physical and environmental damage. For these reasons, the vast majority of transmissive optics include some form of anti-reflection coating. When specifying an AR coating to suit your specific application, you must first be fully aware of the full spectral range of your system. While an AR coating can significantly improve the performance of an optical system, using the coating at wavelengths outside the design wavelength range could potentially decrease the performance of the system. COATING THEORY Figure 1: MgF2 Anti-Reflection Coating Performance Antireflective MgF2 Coating Properties 6.0 Figure 2: Illustration of Light Interacting with Thin Film Substrate: BK7 Air no Uncoated at 45° Reflectance % 5.0 Thickness, t Optical Thickness = n f * t Uncoated at 0° (Avg.=4.25%) 4.0 3.0 1.0 Thin Film Coated at 0° (Avg.=1.5%) 400 450 500 550 600 650 700 = + nf Coated at 45° 2.0 Substrate ns 750 Wavelength (nm) Why Choose an Anti-Reflection Coating? As light passes through an uncoated glass substrate, approximately 4% will be reflected at each interface. This results in a total transmission of only 92% of the incident light. Applying an AR coating on each surface will increase the throughput of the system and important if the system contains many transmitting optical elements. Also, many low-light systems incorporate AR coated optics to allow for efficient use of light. Figure 1 demonstrates the difference between an uncoated and coated single surface BK7 substrate. The coating used is a ¼ wave of MgF2 centered at 550nm. How Does an Anti-Reflection Coating Work? The transmission properties of a coating are dependent upon the wavelength of light being used, the substrate’s index of refraction, the index of refraction of the coating, the thickness of the coating, and the angle of the incident light. The coating is designed so that the relative phase shift between the beam reflected at the upper and lower boundary of the thin film is 180°. Destructive interference between the two reflected beams occurs, cancelling both beams before they exit the surface. The optical thickness of the coating must be an odd number of quarter wavelengths (l/4, where l is the design wavelength or wavelength being optimized for peak performance), in order to achieve the desired path difference of one half wavelength between the reflected beams, which leads to their cancellation. The equation for determining the index of refraction of the thin film needed for complete cancellation of the two beams is: nf is the index of refraction of the thin film n0 is the index of refraction of air (or the incident material) nf = (n0 + ns)½ ns is the index of refraction of the substrate Figure 3: UV and Visible Anti-Reflection Coating Performance Figure 4: NIR Anti-Reflection Coating Performance UV-VIS (250-700) ¼λ MgF2 @ 550nm 300 400 500 600 700 800 Wavelength (nm) 900 1000 1100 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 0.5 0 550 ¼ Wave MgF2 NIR I (600-1050nm) NIR II (750-1550nm) Telecom-NIR (1200-1600nm) AR Coating VIS-NIR (400-1000nm) Reflectance (%) Reflectance (%) VIS 0° (425-675nm) UV-AR (250-450nm) VIS 0, 45 NIR Anti-Reflection Coatings UV and Visible Anti-Reflection Coatings 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 0.5 0 200 Figure 5: Wavelength Selection Chart Anti-Reflection (AR) Coatings reduce hazards caused by reflections traveling backwards through the system (ghost images). Anti-reflection coatings are especially VIS-NIR UV-VIS Telecom-NIR UV-AR NIR I NIR II 200 300 400 500 600 700 800 900 1000 1100 1200 1300 1400 1500 1600 750 950 1150 Wavelength (nm) 1350 1550 1750 UV Visible Near-IR Wavelength (nm) page 2 www.edmundoptics.com Anti-Reflection (AR) Coatings COATING SPECIFICATIONS Anti-Reflection Coating Options Edmund Optics® offers all TECHSPEC® lenses with an optional single layer dielectric, anti-reflection (AR) coating to reduce surface reflections. In addition, custom single-layer, multi-layer, V, and 2V coatings are available for both our off-the-shelf and large volume custom orders. ¼λ MgF2: The simplest AR coating used is ¼λ MgF2 centered at 550nm (with an index of refraction of 1.38 at 550nm). MgF2 coating is ideal for broadband use though it gives varied results depending upon the glass type involved. VIS 0° and VIS 45°: VIS 0° (for 0° angle of incidence) and VIS 45° (for 45° angle of incidence) provide optimized transmission for 425 – 675nm, reducing average reflection to 0.4% and 0.75% respectively. VIS 0° AR coating is preferred over MgF2 for visible applications. VIS-NIR: Our visible/near-infrared broadband anti-reflection coating is specially optimized to yield maximum transmission (>99%) in the near infrared. Telecom-NIR: Our Telecom/near-infrared is a specialized broadband AR coating for popular telecommunications wavelengths from 1200 – 1600nm. UV-AR and UV-VIS: Ultraviolet coatings are applied to our UV fused silica lenses and UV fused silica windows to increase their coating performance in the Ultraviolet region. wavelengths of common fiber optics, laser diode modules and LED lights. Anti-Reflection Coating Information Name Wavelength Range Reflection Specifications MgF2 ¼ Wave @ 550nm Rave ≤ 1.75% 400-700nm (N-BK7) VIS 0° 425-675nm Rave ≤ 0.4% 425-675nm VIS 45° 425-675nm Rave ≤ 0.75% 425-675nm UV-AR 250-450nm Rabs ≤ 1.0% 250-425nm Rave ≤ 0.75% 250-425nm Rave ≤ 0.5% 370-420nm UV-VIS 250-700nm Rabs ≤ 1.0% 350-450nm Rave ≤ 1.5% 250-700nm VIS-NIR 400-1000nm Rabs ≤ 0.25% @ 880nm Rave ≤ 1.25% 400-870nm Rave ≤ 1.25% 890-1000nm NIR I 600-1050nm Rave ≤ 0.5% 600-1050nm NIR II 750-1550nm Rabs ≤ 1.5% 750-800nm Anti-Reflection (AR) Coatings NIR I and NIR II: Our near-infrared I and near-infrared II broadband AR coatings offer exceptional performance in near-infrared Rabs ≤ 1.0% 800-1550nm Rave ≤ 0.7% 750-1550nm Telecom-NIR 1200-1600nm Rabs ≤ 0.25% 1295-1325nm Rabs ≤ 0.25% 1535-1565nm Rave ≤ 0.25% 1200-1600nm page 3 www.edmundoptics.com Anti-Reflection (AR) Coatings TECHSPEC® Anti-reflection coating Products Lenses o Plano-Convex PCX Lenses o Achromatic Lenses o Double Convex DCX Lenses o Cylinder Lenses o Plano-Concave PCV Lenses o Drum Lenses o Double Concave DCV Lenses o Dispersion Prisms o Retroreflection Prisms o Right Angle Prisms o Specialty Prisms o Image Rotation Prisms o Penta Prisms o Visible Windows o UV and IR Windows Prisms More Information Online: Product Downloads o Spec Sheets o 2D Drawings & o Filter & Lens Curves 3D Models o Zemax Files & More! Anti-Reflection (AR) Coatings Windows page 4 www.edmundoptics.com Cleaning optics After purchasing an optical component, exercising proper care can maintain its quality and extend its usable lifetime. Choosing the proper cleaning products and using the proper methods are as important as cleaning the component itself. Improper cleaning practices can damage polished surfaces or specialized coatings that have been used on optics such as lenses, mirrors, filters, or gratings, degrading the performance in almost any application. Also, be aware of your clothing and your environment while cleaning optics; shirts with zippers and buttons can scratch your optics, likewise dirty or dusty environments are not well suited for optical applications. CLEANING PRODUCTS There are a variety of cleaning products and cleaning methods to use depending upon the type of optic to be cleaned and the nature of the care needed, ranging from removing dust to smudges on the surface. Products such as Pick-Up Tools, Tweezers, Gloves, Compressed Air, Cotton-Tipped Swabs, Lens Tissue, Lens Cleaners, Reagent-Grade Isopropyl Alcohol, Reagent-Grade Acetone, and De-Ionized Water can be used to ensure a long product lifetime. Each type of cleaning product has its own unique benefit: Pick-Up tools and Tweezers are useful for holding optics in place while cleaning, Gloves provide a protective barrier to optics from any moisture or oils on your hands, Compressed Air effectively removes surface dust without directly contacting any coating an optic may have, Cotton-Tipped Swabs and Lens Tissue offer an effective means to wipe away any dirt without scratching an optic, and Lens Cleaners, Reagent-Grade Isopropyl Alcohol and Acetone, and De-Ionized Water each safely clean an optic. An important point to stress is that you should NEVER clean plastic optics or optics in plastic housings with Acetone because it will damage the plastic. Therefore, if you have a plastic optic, then you should use Compressed Air, Reagent-Grade Alcohol, or De-ionized Water. If you are unsure about the type of optic that you have or the reactivity of your optical substrate or coating, then using De-Ionized Water and a little bit of dish soap is the safest way to make sure the optic is not damaged by harsh chemicals. Want to see one of our Applications Engineers demonstrate how to clean optics? View our Cleaning Optics video: www.edmundoptics.com/videos Cleaning Methods - Lenses Dust is the most common contaminant and can usually be removed using Compressed Air. If more cleaning is necessary, hold the lens in Lens Tissue and apply a few drops of Reagent-Grade Isopropyl Alcohol, Reagent-Grade Acetone, or Lens Cleaning Solution. Slowly turn the lens while applying pressure in the center and working outward, to pull should be cleaned as soon as possible to avoid staining or damaging the optic. Larger dirt particles, however, should be removed with a Dust-Free Blower before attempting to clean the optic with lens tissue. Larger particles trapped under the cloth will scratch the surface you are attempting to clean. If the lens is still dirty - for instance, if the oil was just redistributed and not cleaned off the optic - then a mild soap solution can be used to gently wash the lens. Repeat the procedure with Reagent-Grade Isopropyl Alcohol or Reagent-Grade Acetone to eliminate streaks and soap residue. Cleaning Methods - Mirrors After blowing off dirt and dust with Compressed Air, the Drag Method of cleaning can be used to remove fingerprints or other contaminants on mirrors. In the Drag Method, cleaning optics dirt off the lens instead of redistributing it on the surface. Fingerprints on a coated lens lens tissue saturated with Reagent-Grade Isopropyl Alcohol or Reagent-Grade Acetone is slowly dragged across the surface. If done correctly, the solvent will evaporate uniformly without leaving streaks or spots. Bare metallic coatings are delicate and cannot be cleaned in this manner. Dirt and fingerprints will permanently damage a bare metal-coated mirror, so preventive measures should be taken to prolong the lifetime of the coating. page 5 www.edmundoptics.com Cleaning optics Cleaning Methods - Filters Filters can be cleaned using the same methods as lenses or mirrors. The preferred method is to use Compressed Air or an Air Blower to remove dust. If additional cleaning is required, then using a Cotton-Tipped Swab or Lens Tissue saturated with Reagent-Grade Isopropyl Alcohol, Reagent-Grade Acetone, or Lens Cleaning Solution will work too. Cleaning Methods - Gratings Due to the construction of diffraction gratings, the only recommended cleaning method is to use Compressed Air or an Air Blower to remove surface dust. Avoid methods that require any direct contacting of the grating surface. Ultrasonic cleaning should not be used as it may separate the grating surface from the glass substrate. Note: The same precautions taken with Gratings should be applied to Wire Grid Polarizers in order to ensure a long product lifetime. Cleaning Methods - Micro Optics Micro Optics may also be cleaned using Reagent-Grade Isopropyl Alcohol or ReagentGrade Acetone but, due to their extremely small size, they require special handling and care. For example, micro lenses typically refer to lenses smaller than 3mm in diameter. Delicate tweezers, such as Non-Marring, Bamboo, and Plastic Tweezers, may be used to securely hold a micro optic by its edge, or a Vacuum Pick-Up Tool may be used. 1. Always handle optics by the edges, never touch the optical surface with your fingertips. The moisture on your fingertips can sometimes damage the coating on optics, and if a fingerprint is left on an optical surface for a long time, it can become a permanent stain. Even if you are wearing gloves, avoid touching the optical surface. 2. Never handle optics with metal implements. Reduce the chance of damage by using wooden, bamboo, or plastic implements to handle optics. Vacuum pens are handy for small optics. 3. Always place an optic on a soft surface, especially if the optical surface is convex. Resting on a hard tabletop can cause scratches in the surface. 4. For lens systems or assemblies, always replace the lens cap when not in use to protect the optical surface from damage. cleaning optics 5 Tips for Handling ANY Optics to Keep Them in Good Condition 5. To store optics, wrap them individually in clean, lint free Lens Tissue and put in a safe place. Never store unwrapped optics together in a box or bag, as they will damage each other if they touch. Never store optics with heavier items on top of them. Want to View our Cleaning Optics Whitepaper? Download a PDF Today: www.edmundoptics.com/downloads page 6 www.edmundoptics.com Metallic Mirror Coatings Just as with anti-reflection (AR) coatings, metallic mirror coatings are also designed for different regions of the spectrum. Edmund Optics® offers a series of protected metallic coatings capable of providing high reflectance values for applications using wavelengths ranging from 250nm to beyond 10μm. Our standard metallic mirror coatings include Protected Aluminum, Enhanced Aluminum, UV Enhanced Aluminum, Protected Gold and Protected Silver. Protected Aluminum and Enhanced Aluminum are typically used for visible applications. UV Enhanced Aluminum can be used for UV and visible applications. Protected Gold offers high reflectance for Infrared or near-Infrared wavelengths. Protected Silver provides the highest reflectance between 500-800nm but is best suited as a rear surface reflector due to its sensitivity to tarnishing. INTRO TO FIRST SURFACE AND SECOND SURFACE MIRRORS Figure 1 Figure 2 ΘI Incident Light Reflected Light Θr Reflected Light Incident Light ΘI = Θr First Surface is Coated First Surface is Uncoated Substrate Substrate Second Surface is Uncoated Second Surface is Coated Edmund Optics® offers a variety of mirror substrates and geometries coated with our standard metallic mirror coatings, laser-line coatings, as well as, custom broadband, narrowband, single laser line, dual laser line and laser-line beamsplitter coatings. All of our mirror products are first surface mirrors, Figure 1, featuring a high reflectivity coating, such as metallic or multi-layer dielectric, deposited on one surface of the glass substrate (we also offer a few families of metal substrate mirrors). By contrast, second surface mirrors, Figure 2, are manufactured in the same manner as first surface mirrors but feature an additional cover glass on the coated surface, usually silver-plated, for protection. This cover glass protects the coating layer from scratching and oxidization. Edmund Optics recommends 1. Light incident on a second surface mirror is subject to dispersion from reflection off the cover glass. Glass tends to disperse light, causing different wavelengths to refract at different angles. 2. Due to Fresnel reflections at the cover glass, reflected light exhibits ghost images, indicated by the dashed red line. 3. Due to Fresnel reflections, responsible for approximately 4% reflection loss at each interface, reflection efficiency is reduced by using a second surface mirror. Reflectance Curves for Metallic (Mirror) Coatings Ultraviolet Visible Infrared STANDARD METALLIC MIRROR COATING SPECIFICATIONS 100 Reflectance Curves for Metallic (Mirror) Coatings Visible Reflectance % Ultraviolet 90 Infrared 100 Reflectance % 90 80 70 60 50 80 Figure 3: Metallic Mirror Coating Reflectance Curves rises 0.7 gradually 10μm 0.2 Theoretical 0.3 0.4reflectance 0.5 0.6 0.8 through 0.9 1.0 1.1 70 Wavelength in Microns (µm) 60 UV Enhanced Aluminum (R >85% 0.25-0.7 Microns) Protected Aluminum (R>85% 0.4-0.7 Microns) Enhanced Aluminum (R >95% 0.45-0.65 Microns) Protected Gold (R>97% 0.8-2 Microns, R>94% 0.7-0.8 Microns) Protected Silver (R >98% 0.5-0.8 microns, R >98% 2-10 microns) 50 0.2 0.3 0.4 0.5 0.6 0.7 0.8 Wavelength in Microns (µm) 0.9 1.0 1.1 UV Enhanced Aluminum (R >85% 0.25-0.7 Microns) Protected Aluminum (R>85% 0.4-0.7 Microns) Enhanced Aluminum (R >95% 0.45-0.65 Microns) Protected Gold (R>97% 0.8-2 Microns, R>94% 0.7-0.8 Microns) Protected Silver (R >98% 0.5-0.8 microns, R >98% 2-10 microns) Metallic Mirror Coatings first surface mirrors to second surface mirrors for the following three reasons (Figure 2): Protected Aluminum Protected Aluminum is our most popular mirror coating for applications in the visible and near-Infrared. A half wavelength of Silicon Monoxide (SiO) is used as an overcoat to protect the delicate aluminum. This treatment provides an abrasion-resistant surface while maintaining the performance of aluminum. page 7 www.edmundoptics.com Metallic Mirror Coatings Enhanced Aluminum and UV Enhanced Aluminum A multi-layer film of dielectrics on top of aluminum is used to enhance the reflectance in the visible or ultraviolet regions. Enhanced Aluminum is ideal for applications requiring increased reflectance from 400nm-650nm while UV Enhanced Aluminum yields increased reflectance from 250nm-400nm. The multi-layer film also provides the handling characteristics of the protected aluminum coating. Protected Gold Protected Gold is effective for applications requiring high reflectance in the near-Infrared and Infrared regions. Since a durable coating is necessary for handling purposes, we offer gold with a Silicon Monoxide overcoat. The performance of gold (96% reflectivity from 750nm-1500nm) is maintained, while providing a more durable finish. Protected Silver Protected Silver offers excellent reflectivity in the visible and infrared regions, making it an excellent choice for broadband applications that span multiple spectra. Silver offers a reflectivity >98% from 500-800nm. A protective coating reduces silver’s tendency to tarnish but the coating is ideally suited to low humidity environments. Metallic Mirror Coating Information Name Reflection Specifications 400-700nm R(ave) >85% Enhanced Aluminum 450-650nm R(ave) >95% UV Enhanced Aluminum 250-700nm R(ave) >85% Protected Gold 700-800nm R(ave) >94% 800-10000nm R(ave) >97% 500-800nm R(ave) >98% 2000-10000nm R(ave) >98% Protected Silver CUSTOM MIRROR COATINGS AVAILABLE Edmund Optics® is a leading designer and manufacturer of laser coatings for mirrors, beamsplitters, windows, and other optical components. We work with a number of testing laboratories to independently qualify and certify our coatings for resistance to laser damage. All specified damage threshold values have been obtained by testing multiple coating runs to ensure an accurate result. The values specified are conservative, with typical data showing that our mirrors are able to withstand 2-3 times the specified threshold. We are able to design and manufacture coatings for single or multiple laser lines, as well as for broadband tunable laser sources. Coatings designs are also available for partial reflectors, output couplers, and etalons, and for any angle of incidence or polarization state. Our world class manufacturing facilities are able to produce substrates with surface accuracies of < 1/20λ, surface qualities of 10-5, parallelism of <0.5 arcseconds, and surface roughness of <5 Angstroms in any glass and most crystalline substrates. We will also coat customer-supplied substrates for prototype or production volumes. For high-power applications, coating designers choose materials with intrinsically low absorption at the relevant wavelengths. But the customer also needs to be aware that the choice of coating materials for high-power applications is limited. The system-designer does well to design for optics with the appropriate damage thresholds from the beginning of the optical design process. Coatings for use with high-power ultraviolet (UV) lasers are made of different materials from those for use in the visible and near- Metallic Mirror Coatings Wavelength Range Protected Aluminum infrared (IR). The core structure of high-reflection coatings is typically a repeating stack of high- and low-index layers, each a quarterwavelength thick. The design of the coating can significantly alter the damage threshold. Simply adding a half-wave of low-index material (normally silicon dioxide) as the final layer can result in measurably higher damage thresholds. Silicon dioxide (SiO2) is the generally accepted and ubiquitous choice for low-index layers, and dielectric metal oxides in general are preferred materials for UV, visible, and near-IR laser applications. Choosing a material for high-index layers is not as straightforward: oxides of titanium, tantalum, zirconium, hafnium, scandium, and niobium are all popular high-index materials. page 8 www.edmundoptics.com Metallic Mirror Coatings BBHR and NBHR (Notch Filter) oVisible Broadband: Rave >98%, o Custom Coatings Available Broadband and Narrow Band High Reflectors for Wavelengths between Visible Broadband Reflector oNotch Filter: R >90% at Center 300-1800nm (BBHR) and Wavelength (CWL), FWHM 350-850nm (Notch) < 0.12 CWL, Tave >90% for Out of Band Wavelengths o Max Reflectance at 1 or 2 o Single Line: R >99.5%, at Customer Selected Design Wavelength Wavelengths from o Dual Line: R >98.5%, at 190-3000nm (Single Line) Both Wavelengths of Interest or 350-1700nm (Dual Line) o Partial Reflectance from 5%R o 45°, Random and to 95%R, per Customer Non-polarizing Versions o Design Wavelengths from Figure 4 100 90 80 Reflection (%) 70 Single Stack High Reflector Narrow Band Reflector (Notch Filter) 60 50 40 425-675nm, 0-45° AOI 30 20 10 0 400 450 500 550 600 Wavelength (nm) 650 700 Single and Dual Laser Line Reflector Figure 5 Reflection (%) Dual Laser Line Reflector 100 90 80 70 60 50 40 30 20 10 0 400 500 600 700 800 900 1000 1100 1200 1300 1400 Wavelength (nm) Laser Line Beamsplitter Laser Line Beamsplitter Coatings Requirement Reflection (%) 100 90 80 70 60 50 40 30 20 10 0 1000 1200 1400 1600 1800 Wavelength (nm) 2000 2200 2400 o Reflectance Specification: R% = ±2%; Typical: R% = ±1% 250-3000nm Standard metallic mirror coatings Products Prisms Mirrors o Dispersion Prisms o Diverging Mirrors o Right Angle Prisms o Flat Mirrors o Image Rotation o Focusing Mirrors o Specialty Mirrors Prisms o Metallic Mirror Coatings Figure 6 Retroreflection Prisms o Specialty Prisms page 9 www.edmundoptics.com Optical Glass Optical Glass Specifications Selecting a glass material is important since different glass types have different characteristics. Edmund Optics® offers a wide variety of glass types which can be selected on the basis of the following characteristics. The index of refraction and Abbe number of a glass are typically used by designers as degrees of freedom when designing systems. The index of refraction refers to the ratio of the speed of light in a vacuum to the speed of light through a given material at a given wavelength, while the Abbe number of a material quantifies the amount of dispersion (variations in index) for a specific spectral range. For instance, a higher index of refraction generally bends light more efficiently so there is less of a need of curvature in the lens. Spherical aberration is less present in lenses with higher indices of refraction, while light travels faster through materials with lower indices of refraction. A high Abbe number generally gives less color dispersion and reduces color aberration. Also, certain glass types have different transmission wavelength regions. The density of a glass helps determine the weight of the optical assembly and, along with lens diameter, becomes critical for weight sensitive applications. Density also generally denotes the ability to work with the glass and is somewhat proportional to the cost of the material. When dealing with applications involving extreme temperatures and quick temperature differentials, a glass’ coefficient of expansion becomes a key factor. Opto-mechanical designers need to keep this in mind when designing optical assemblies. Many glass manufacturers offer the same material characteristics under different trade names and most have modified their products and processes to be ECO-friendly (free of lead and arsenic). Essential values for all types of glasses Abbe Number (vd) Density (g/cm3) Coefficient of Linear Expansion* Max Operating Temp (°C) CaF2 1.434 95.10 3.18 18.85 800 Fused Silica 1.458 67.70 2.20 0.55 1000 Schott BOROFLOAT™ 1.472 65.70 2.20 3.25 450 Corning Pyrex 7740® 1.474† 65.40† 2.23 3.20 490 S-FSL5 1.487 70.20 2.46 9.00 457 N-BK7 1.517 64.20 2.46 7.10 557 N-K5 1.522 59.50 2.59 8.20 546 B270/S1 1.523 58.50 2.55 8.20 533 Schott Zerodur® 1.542 56.20 2.53 0.05 600 N-SK11 1.564 60.80 3.08 6.50 604 N-BaK4 1.569 56.10 3.10 7.00 555 N-BaK1 1.573 57.55 3.19 7.60 592 L-BAL35 1.589 61.15 2.82 6.60 489 N-SK14 1.603 60.60 3.44 7.30 649 N-SSK8 1.618 49.80 3.33 7.10 598 N-F2 1.620 36.40 3.61 8.20 432 BaSF1 1.626 38.96 3.66 8.50 493 N-SF2 1.648 33.90 3.86 8.40 441 N-LaK22 1.651 55.89 3.73 6.60 689 page 10 www.edmundoptics.com Optical Glass Index of Refraction (nd) Glass Name Optical Glass Essential values for all types of glasses Glass Name Abbe Number (vd) Density (g/cm3) Coefficient of Linear Expansion* S-BaH11 1.667 48.30 3.76 6.80 N-BaF10 1.670 47.20 3.76 6.80 N-SF5 1.673 32.30 4.07 8.20 N-SF8 1.689 31.20 4.22 8.20 N-LaK14 1.697 55.41 3.63 5.50 N-SF15 1.699 30.20 2.92 8.04 N-BaSF64 1.704 39.38 3.20 9.28 N-LaK8 1.713 53.83 3.75 5.60 N-SF18 1.722 29.30 4.49 8.10 N-SF10 1.728 28.40 4.28 7.50 S-TIH13 1.741 27.80 3.10 8.30 N-SF14 1.762 26.50 4.54 6.60 Sapphire** 1.768 72.20 3.97 5.30 N-SF11 1.785 25.80 5.41 6.20 N-SF56 1.785 26.10 3.28 8.70 N-LaSF44 1.803 46.40 4.46 6.20 N-SF6 1.805 25.39 3.37 9.00 N-SF57 1.847 23.80 5.51 8.30 N-LaSF9 1.850 32.20 4.44 7.40 N-SF66 1.923 20.88 4.00 5.90 S-LAH79 2.003 28.30 5.23 6.00 ZnSe 2.403 N/A 5.27 7.10 Silicon 3.422 N/A 2.33 2.55 Germanium 4.003 N/A 5.33 6.10 *microns/m°C (-30 to 70°C) **Sapphire is a birefringent material. All specifications correspond to parallel to C-Axis. Pyrex 7740® nd and vd specified at 589.3nm † More Information Online: Application notes o Application Examples o Graphical Illustrations o Equations & More! Optical Glass Index of Refraction (nd) www.edmundoptics.com/appnotes page 11 www.edmundoptics.com Optical Glass Optical Glass Properties Today, the quality and integrity of optical glass is a fundamental assumption made by optical designers. Until recently, however, that was not the case. Nearly 125 years ago, Otto Schott began a revolution by systematicallyresearching and developing glass compositions. His development work on composition and the production process took glass manufacturing from the realm of trial and error to its state today as a truly technical material. Now optical glass properties are predictable, reproducible and homogeneous - the essential prerequisites of a technical material. The fundamental properties that characterize optical glass are: Refractive Index Refractive Index is the ratio of the speed of light in a vacuum to the speed of light in the specified material - a description of how light slows down as it passes through an optical material. The refractive index for optical glasses, nd, is specified at a wavelength of 587.6nm (Helium d-line). Materials with a low index of refraction are commonly referred to as “crowns” whereas materials with a high index of refraction are referred to as “flints.” The typical index of refraction tolerance for components in our catalog is ±0.0005. Dispersion Dispersion is a description of the variation of the refractive index with wavelength. It is specified using the Abbe number, vd, defined as (nd - 1) / (nF - nC) where nF and nC are the refractive indices at 486.1nm (Hydrogen F-line) and 656.3nm (Hydrogen C-line). A low Abbe number indicates high dispersion. Crown glasses tend to have lower dispersion than flints. The typical Abbe tolerance for components in our catalog is ±0.8%. Transmission Standard optical glasses offer high transmission throughout the entire visible spectrum and beyond in the near ultraviolet and near infrared ranges. Crown glasses tend to have better transmission in the NUV than do flint glasses. Flint glasses, because of their high index, feature higher Fresnel reflection loss and thus should always be specified with an Anti-Reflection coating. Figure 1: Sample Optical Glass Transmittance Curves 1 1 0.9 0.99 0.98 Pyrex 7740® 0.97 Pyrex 7740® 0.96 N-BK7 N-BK7 0.6 N-K5 0.5 B270 0.4 N-BaF10 N-SF5 0.3 N-SF10 0.2 N-SF11 0.1 N-LaSFN9 0 Transmittance (5 mm) Transmittance (5 mm) 0.7 BoroFloat™ 300 400 500 Wavelength (nm) 600 BoroFloat™ N-K5 0.95 B270 0.94 N-BaF10 0.93 N-SF5 N-SF10 0.92 N-SF11 0.91 700 0.9 1400 N-LaSFN9 1500 1600 1700 1800 1900 2000 2100 2200 Wavelength (nm) Optical Glass 0.8 Additional Properties When designing an optic that will be used in an extreme environment it is important to realize that each optical glass will have slightly different chemical, thermal and mechanical properties. These properties can be found on the glass datasheet. page 12 www.edmundoptics.com Optical Glass Optical Glass Selection Figure 2: Schott Abbe Diagram νd 2.05 95 n d 2.00 d 90 85 80 Abbe Diagram 75 70 65 60 55 50 40 1.90 1.85 35 33A 34 LAK 1.70 14 12 7 1.65 1.60 PSK PK FK 90 νd 85 80 75 2 5 7 7 10 BK ZK7 5 CaF2 nd 47 43 10 BAK K 2 4 5 SSK 5 8 BAF 52 KZFS4 LF LLF 1 KF 5 4 BALF KZFS2 KZFS5 KZFS11 2 1.80 14 4 7 BASF 51 6 56A 11 KZFS8 64 9 1.85 SF 45 LAF 2 35 1.90 57 40 10 8 22 21 16 4 2 53A 14 SK 5 11 57 14 3 1.55 52A 2.05 LASF 9 1.75 51 66 67 46A 31A 44 21 33 34 95 20 1.95 1.80 51A 25 2.00 41 1.50 30 nd – νd Description of Symbols N- or P-glass Lead containing glass N-glass or lead containing glass Glass suitable for Precision Molding CaF2 or Fused Silica 1.95 1.45 45 5 8 15 1 1.75 10 1.70 1.65 2 2 1.60 F 5 1.55 9 10 1.50 FS 70 1.45 65 60 55 50 45 40 35 30 25 20 Optical systems have to be optimized for a total set of functional characteristics. Geometrical and color induced aberrations can be compensated only by the use of more than one glass type. In most cases three or more glass types are used. The requirements on optical of glass types has been developed. Traditionally they are shown in the refractive index versus dispersion diagram - the Abbe diagram. The Abbe diagram, first introduced by SCHOTT in 1923, is a long established survey of the optical glass program. Glass types are given in a two-dimensional coordinate system with the Abbe number (vd) as x-axis and the refractive index (nd) as y-axis. The x-axis is in reversed direction with numbers increasing to the left side. In the Abbe diagram, glass materials are divided into type denominations like BK, SK, F, SF, etc. These “glass families” correspond to the regions in the Abbe diagram defined by the blue lines. There is a major line that separates crown glass types (last letter “K” from German “Kron” for crown) from flint glass types (last letter “F”). This line starts upwards from the bottom at Abbe number 55, steps aside at refractive index 1.60 to Abbe number 50, and continues upwards to the top. Optical Glass systems for different applications cover a range so wide that they cannot be met with just a small set of glass types. So a wide range The leading letters in the glass name characterize an important chemical element used in the glass type: F - Fluorine, P – Phosphorus, B – Boron, BA – Barium, LA – Lanthanum. Deviating from this rule are the glass types from the crown - flint series, which progresses from K (“Kron”) to KF (“Kronflint” – crownflint) to flints of increasing lead content and hence density: LLF (“Very light flint”), LF (“Light flint”), F (“flint”), and SF (“Schwerflint” – heavy flint). Another deviation is the SK and SSK glass types: SK (“heavy crown”) and SSK (“heaviest crown”). LAK, LAF and LASF mean Lanthanum crown, flint and dense flint glass types, respectively. page 13 www.edmundoptics.com Understanding ball lenses Ball lenses are great optical components for improving signal coupling between fibers, emitters and detectors. They are also used in endoscopy, bar code scanning, ball pre-forms for aspheric lenses and sensor applications. Ball lenses are manufactured from a single substrate of glass and can focus or collimate light, depending upon the geometry of the input source. Half-ball lenses are also common and can be interchanged with (full) ball lenses if the physical constraints of an application require a more compact design. Essential Equations for Using Ball Lenses D d Figure 1: Key Parameters BFL EFL P There are five key parameters needed to understand and use ball lenses (Figure 1): Diameter of Input Source (d), Diameter of Ball Lens (D), Effective Focal Length of Ball Lens (EFL), Back Focal Length of Ball Lens (BFL) and Index of Refraction of Ball Lens (n). EFL is very simple to calculate (Equation 1) since there are only two variables involved: Diameter of Ball Lens (D) and Index of Refraction (n). EFL is measured from the center of the ball lens, indicated by R in Figure 1. BFL (Equation 2) is easily calculated once EFL and D are known. Numerical Aperture NA (Equation 3) is dependent on EFL and d. It is a commonly referenced term and often used in lieu of d/D. EFL = nD D BFL = EFL – 4(n-1) Equation 1 NA = 2d(n-1) nD 2 Equation 2 Equation 3 1.600 Fused Silica N-BK7 N-SF8 Sapphire LaSFN9 S-LAH79 Numerical Aperture (NA) 1.400 1.200 1.000 0.800 Since NA is often used, Figure 2 illustrates how it increases as the Diameter of the Input Source (d) also increases. Figure 2: Numerical Aperture vs. Diameter for Ball Lens Glass Types offered by Edmund Optics®. 0.600 0.400 0.200 0.000 0.00 0.10 0.20 0.30 0.40 0.50 0.60 0.70 0.80 0.90 Understanding ball lenses Equations 1.00 d/D page 14 www.edmundoptics.com Understanding ball lenses Application Examples Figure 3: Laser to Fiber Coupling D d Example 1: Laser to Fiber Coupling When coupling light from a laser into a fiber optic, the choice of ball lens is dependent on the NA of the fiber and the diameter of the laser beam, or the input source. The diameter of the laser beam is used to determine the NA of the ball lens. The NA of the ball lens must be less than or equal to the NA of the fiber optic in order to couple all of the light. The ball lens in contact with the fiber as shown in Figure 3. Initial Parameters Calculated Parameter Diameter of Input Laser Beam = 2mm Diameter of Ball Lens Index of Refraction of Ball Lens = 1.517 Numerical Aperture of Fiber Optic = 0.22 D= 2d(n-1) 2 x 2mm(1.517 -1 ) = 6.2mm 1.517 x 0.22 A N-BK7 ball lens (index of refraction of 1.517) of 6-8mm in diameter would be ideal for coupling a 2mm laser source into a 0.22NA fiber optic. One can easily try different indices of refraction in order to find the best ball lens for a laser to fiber coupling application. Example 2: Fiber to Fiber Coupling To couple light from one fiber optic to another fiber optic of similar NA, two identical ball lenses are used. Place the two ball lenses in contact with the fibers as shown in Figure 4. If the fiber optics have the same NA, then the same logic as in Example 1 can be applied. Fiber Coupler Figure 4: Fiber to Fiber Coupling MORE INFORATION ONLINE: Connect with us! FACEBOOK www.facebook.com/edmundoptics TWITTER www.twitter.com/edmundoptics page 15 www.edmundoptics.com Understanding ball lenses nNA D=