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Chem 4 Name: ANSVER KEY 1. Which of the following statements of the atomic theory proposed by John Dalton at the beginning of the 19th century are not quite true in light of modern atomic physics? Rewrite each statement to reflect the current understanding of the atomic theory. An element is made up of atoms. All Atoms cannot be created or destroyed. atoms of a given element are identical. 2. All atoms of a given element have the same number of protons in the nucleus. They may differ in the number of neutrons. Chemically the atoms of a given element are virtually indistinguishable: the types of chemical reactions are the same; the rates may slightly differ for different isotopes. Atoms cannot be created or destroyed in chemical reactions. In chemical reactions the old bonds between atoms are broken down and new bonds are formed. Atoms, however, can be created or destroyed in nuclear reactions: radioactive decays, nuclear fission and fusion. All atoms of one element have the same mass. Atoms of two different elements have different masses. Atoms of different elements may combine in the ratio of small, whole numbers to form compounds. The main characteristic of an element is the atomic number. Two elements differ from each other by their atomic numbers. In fact, atoms of two different elements may have masses that are very close to each other. For example, 39.9624 amu for an atom of argon-40 and 39.9640 amu for an atom of potassium-40. This is often the case for many compounds, especially inorganic. It was always the case for compounds known to Dalton. Most organic compounds (whose composition was not known to Dalton) do not follow that rule: C12H22O11 (sugar), C27H46O (cholesterol), C17H21NO4 (cocaine). Fill out the following table. Use abbreviation N/A for “not applicable”. Basic unit (atom, Organic or Ionic or molecule, Inorganic? covalent? or formula unit)? Substance Name Formula or Symbol Element or compound? Aluminum bromide AlBr3 E IO Ionic FU Methanol CH3OH C O Cov Molec Nitogen dioxide NO2 C IO Cov Molec Tin Sn E N/A N/A Atom Iron (II) carbonate FeCO3 C IO Ionic FU Ammonium nitrite NH4NO2 IO Ionic FU Sulfur trioxide SO3 C IO Cov Molec Tetraphosporus P4 E N/A N/A Molec