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Transcript
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Ionic Compound Solubility
Ionic Compound Solubility
Nitrates (NO3-)
Chlorates (ClO3-)
Ionic Compound Solubility
Ionic Compound Solubility
Perchlorates (ClO4-)
Acetates (C2H3O2-)
Ionic Compound Solubility
Ionic Compound Solubility
Alkali Metal Compounds (Li+,Na+,K+,Rb+,Cs+)
Ammonium Compounds (NH4+)
Ionic Compound Solubility
Ionic Compound Solubility
Chlorides (Cl-)
Bromides (Br-)
Ionic Compound Solubility
Ionic Compound Solubility
Iodides (I-)
Sulfates (SO42-)
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All soluble
All soluble
Exceptions:
AgC2H3O2
All soluble
All soluble
Exceptions:
KClO4
All soluble
All soluble
All soluble
All soluble
Exceptions:
Those that contain Ag+,Hg22+, Pb2+,PbCl2
Exceptions:
Those that contain Ag+,Hg22+, Pb2+,PbCl2
Most are soluble
Exceptions:
SrSO4,BaSO4,CaSO4,PbSO4,
HgSO4,Hg2SO4,Ag2SO4
All soluble
Exceptions:
Those that contain Ag+,Hg22+, Pb2+,PbCl2
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Strong, Weak or Non Electrolytes
Strong, Weak or Non Electrolytes
Strong acids
Strong bases
Strong, Weak or Non Electrolytes
Strong, Weak or Non Electrolytes
Weak acids
Weak bases
Strong, Weak or Non Electrolytes
Strong, Weak or Non Electrolytes
Soluble ionic compounds
Insoluble ionic compounds
Strong, Weak or Non Electrolytes
Strong, Weak or Non Electrolytes
Molecules
Partially soluble ionic compounds
Common Oxidation State Changes
Common Oxidation State Changes
NO2-
C2O4
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Strong electrolytes
Strong electrolytes
All soluble metal hydroxides
Perchloric, HClO4;Chloric, HClO3; Hydrobromic, HBr;
Hydrochloric, HCl; Hydroiodic, HI; Nitric, HNO3;
Sulfuric, H2SO4
Weak electrolytes
Weak electrolytes
All molecular bases
All acids other than the seven strong acids
All nonelectrolytes
All strong electrolytes
All nonelectrolytes
Nonelectrolytes except acids and molecular bases
CO2
NO3-
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Common Oxidation State Changes
Common Oxidation State Changes
HNO3(dilute)
HNO3(concentrated)
Common Oxidation State Changes
Common Oxidation State Changes
Sn2+
MnO4-(in acid solution)
Common Oxidation State Changes
Common Oxidation State Changes
MnO2(in acid solution)
MnO4-(in neutral or basic solution)
Common Oxidation State Changes
Common Oxidation State Changes
H2SO4(hot, concentrated)
SO32-or SO2(aq)
Common Oxidation State Changes
Common Oxidation State Changes
Na2O2
H2O2
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NO2
NO
Mn2+
Sn4+
MnO2
Mn2+
SO42-
SO2
H2O + O2
NaOH
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Common Oxidation State Changes
Common Oxidation State Changes
HClO4
Cl2 (dilute basic solution)
Common Oxidation State Changes
Common Oxidation State Changes
Cl2 (concentrated basic solution)
Cr2O72-(in acidic solution)
Common Oxidation State Changes
Common Oxidation State Changes
S2O32-
NH3
Patterns of Chemical Reactivity
AX(aq)+ BY(aq)→
Patterns of Chemical Reactivity
Acid + Base →
Patterns of Chemical Reactivity
Definition
Acid
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ClO-
Cl-
Cr3+
ClO2-
NH4+
SO2
Precipitation Reaction - Metathesis
→ AY(s) + BX(aq)
Patterns of Chemical Reactivity
Definition
A substance that is able to donate a H+ ion (a
proton) and, hence, increases the concentration of
H+(aq) when it dissolves in water.
Acid/Base Neutralization - Metathesis
→ Salt + Water
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Patterns of Chemical Reactivity
Definition
Patterns of Chemical Reactivity
Definition
Base
Salt
Patterns of Chemical Reactivity
Patterns of Chemical Reactivity
Metallic Oxide + Acid →
Nonmetallic oxide + Base →
Patterns of Chemical Reactivity
Definition
Patterns of Chemical Reactivity
Definition
Metallic Oxide
Nonmetallic oxide
Patterns of Chemical Reactivity
Patterns of Chemical Reactivity
Definition
Acid + Non-hydroxide base →
Non-hydroxide base
Patterns of Chemical Reactivity
Patterns of Chemical Reactivity
Group IA metal + Nonmetal →
Group IIA metal + Nonmetal →
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Patterns of Chemical Reactivity
Definition
Patterns of Chemical Reactivity
Definition
An ionic compound formed by replacing one or
more hydrogens of an acid by other cations.
A substance that is an H+ acceptor; a base produces
an excess of OH-(aq) when it dissolves in water.
Double Displacement - Metathesis
Double Displacement - Metathesis
→ Salt + H2O
→ Salt + H2O
Patterns of Chemical Reactivity
Definition
Oxygen and a metallic element. Ex: Fe2O3
Oxygen and a nonmentallic element.
Ex: CO2
Patterns of Chemical Reactivity
Definition
A base that does not contain an OH- group.
Ex: Na2S
Synthesis - Redox
→ Salt (Metal ion + Nonmetal ion)
Double Displacement - Metathesis
→ Salt + Molecular gas
Synthesis - Redox
→ Salt (Metal ion + Nonmetal ion
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Patterns of Chemical Reactivity
Patterns of Chemical Reactivity
AB →
Metal + Metal ion →
Patterns of Chemical Reactivity
Patterns of Chemical Reactivity
2M(s) + 2H2O →
(Pattern for Group I)
M(s) + H2O →
(Pattern for Group II)
Patterns of Chemical Reactivity
Patterns of Chemical Reactivity
Mg(s) +H2O →
Halogen + Halogen ion →
Patterns of Chemical Reactivity
Patterns of Chemical Reactivity
Acid + Metal →
Molecular: Pb + H2SO4 →
Net Ionic: Pb + H+ + SO42- →
Patterns of Chemical Reactivity
Patterns of Chemical Reactivity
Concentrated:
Cu + H+ + NO3- →
Diluted:
Cu + H+ + NO3- →
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Decomposition - Redox
Single Displacement - (Metal Displacement) Redox
→A+B
→ Metal + Metal ion
Single Displacement – Metal Displacement
Pattern for Group II
Redox
Single Displacement – Metal Displacement
Pattern for Group I
Redox
→ M2+(aq) + 2OH-(aq) + H2(g)
→ 2M+(aq) + 2OH-(aq) + H2(g)
Single Displacement – Halogen Displacement
Redox
Single Displacement – Metal Displacement
Exception – Mg
Redox
→ Halogen + Halogen ion
Single Displacement
Exception
→ MgO(s) + H2 (g)
Single Displacement – Hydrogen Displacement
Redox
Molecular: → PbSO4 + SO2 + H2O
Net ionic: → PbSO4 + SO2 + H2O
→ Salt + Hydrogen
Single Displacement
Exception
Single Displacement
Exception
Diluted:
→ Cu + H2O + NO
Concentrated:
→ Cu2+ + H2O + NO2
2+
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Ionic Compound Solubility
Ionic Compound Solubility
Carbonates (CO32-)
Phosphates (PO43-)
Ionic Compound Solubility
Ionic Compound Solubility
Chromates (CrO42-)
Sulfites (SO32-)
Ionic Compound Solubility
Ionic Compound Solubility
Hydroxides (OH-)
Sulfides (S2-)
Ionic Compound Solubility
Polyatomic Ions
Oxides (O2-)
Acetate
Polyatomic Ions
Polyatomic Ions
Bromite
Bromate
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Group I, (NH4)3PO3
Group I, (NH4)2CO3
Group I, (NH4)2SO3
Group I, (NH4)2Cr3
Group I, Sr(OH)2, Ba(OH)2
Group I, (NH4)2S
Exceptions:
Ca(OH)2
Polyatomic Ions
CaO, SrO, BaO
C2H3O2-
or CH3COO
-
Polyatomic Ions
Polyatomic Ions
BrO3-
BrO2-
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Polyatomic Ions
Polyatomic Ions
Hypochlorite
Chlorite
Polyatomic Ions
Polyatomic Ions
Chlorate
Perchlorate
Polyatomic Ions
Polyatomic Ions
Cyanide
Thiocynate
Polyatomic Ions
Polyatomic Ions
Dihydrogen Phosphate
Hydrogen carbonate or bicarbonate
Polyatomic Ions
Polyatomic Ions
Hydrogen sulfide
Hydrogen sulfite or bisulfite
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Polyatomic Ions
Polyatomic Ions
ClO-
ClO2-
Polyatomic Ions
Polyatomic Ions
ClO4-
ClO3-
Polyatomic Ions
Polyatomic Ions
SCN-
CN-
Polyatomic Ions
Polyatomic Ions
HCO3-
H2PO4-
Polyatomic Ions
Polyatomic Ions
HSO4-
HS-
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Polyatomic Ions
Polyatomic Ions
Hydroxide
Iodate
Polyatomic Ions
Polyatomic Ions
Permanganate
Nitrite
Polyatomic Ions
Polyatomic Ions
Nitrate
Carbonate
Polyatomic Ions
Polyatomic Ions
Chromate
Dichromate
Polyatomic Ions
Polyatomic Ions
Hydrogen phosphate
Permanganate
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Polyatomic Ions
Polyatomic Ions
IO3-
OH-
Polyatomic Ions
Polyatomic Ions
NO2-
MnO4-
Polyatomic Ions
Polyatomic Ions
CO32-
NO3-
Polyatomic Ions
Polyatomic Ions
Cr2O72-
CrO42-
Polyatomic Ions
Polyatomic Ions
MnO42-
HPO42-
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Polyatomic Ions
Polyatomic Ions
Oxalate
Peroxide
Polyatomic Ions
Polyatomic Ions
Disulfide
Sulfite
Polyatomic Ions
Polyatomic Ions
Sulfate
Thiosulfate
Polyatomic Ions
Polyatomic Ions
Phosphite
Phosphate
Polyatomic Ions
Polyatomic Ions
Ammonium
Mercury (I)
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Polyatomic Ions
Polyatomic Ions
O22-
C2O42-
Polyatomic Ions
Polyatomic Ions
SO32-
S22-
Polyatomic Ions
Polyatomic Ions
S2O32-
SO42-
Polyatomic Ions
Polyatomic Ions
PO43-
PO33-
Polyatomic Ions
Polyatomic Ions
Hg22+
NH4+
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Common Transition Metal Oxidation States
Common Transition Metal Oxidation States
Cadmium (Cd)
Hafnium (Hf)
Common Transition Metal Oxidation States
Common Transition Metal Oxidation States
Chromium (Cr)
Iridium (Ir)
Common Transition Metal Oxidation States
Common Transition Metal Oxidation States
Cobalt (Co)
Iron (Fe)
Common Transition Metal Oxidation States
Common Transition Metal Oxidation States
Copper (Cu)
Lutetium (Lt)
Common Transition Metal Oxidation States
Common Transition Metal Oxidation States
Gold (Au)
Manganese (Mn)
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IV
II
III, IV
II, III, VI
II, III, V
II, III
III
I, II
II, III, IV, V, VI, VII
I, III
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Common Transition Metal Oxidation States
Common Transition Metal Oxidation States
Mercury (Hg)
Paladium (Pd)
Common Transition Metal Oxidation States
Common Transition Metal Oxidation States
Molybdenum (Mo)
Platinum (Pt)
Common Transition Metal Oxidation States
Common Transition Metal Oxidation States
Nickel (Ni)
Rhenium (Re)
Common Transition Metal Oxidation States
Common Transition Metal Oxidation States
Niobium (Nb)
Rhodium (Rh)
Common Transition Metal Oxidation States
Common Transition Metal Oxidation States
Osmium (Os)
Ruthenium (Ru)
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II, IV
Hg+, Hg2+, Hg22+
II, IV
II, III, IV, V, VI
II, III, IV, V, VII
II, III
II, III, IV
II, III, IV, V
II, III, IV, V, VIII
II, IV, VIII
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Common Transition Metal Oxidation States
Common Transition Metal Oxidation States
Scandium (Sc)
Tungsten (W)
Common Transition Metal Oxidation States
Common Transition Metal Oxidation States
Silver (Ag)
Vanadium (V)
Common Transition Metal Oxidation States
Common Transition Metal Oxidation States
Tantalum (Ta)
Yttrium (Y)
Common Transition Metal Oxidation States
Common Transition Metal Oxidation States
Technetium (Tc)
Zinc (Zn)
Common Transition Metal Oxidation States
Common Transition Metal Oxidation States
Titanium (Ti)
Zirconium (Zr)
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III, IV, V, VI
III
II, III, IV, V
I
III
III, IV, V
II
IV, VI, VII
III, IV
II, III, IV
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Strong, Weak or Non Electrolytes
Strong, Weak or Non Electrolytes
HClO2
Ca(OH)2
Strong, Weak or Non Electrolytes
Strong, Weak or Non Electrolytes
Pb(SO4)2
CO2
Strong, Weak or Non Electrolytes
Strong, Weak or Non Electrolytes
NaOH
H2SO4
Strong, Weak or Non Electrolytes
Strong, Weak or Non Electrolytes
NH3
CH3COOH
Strong, Weak or Non Electrolytes
Strong, Weak or Non Electrolytes
Cu(NO3)2
Sr(OH)2
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Nonelectrolyte (partially soluble ionic compound)
Weak acid/weak electrolyte
Nonelectrolyte
Nonelectrolyte (insoluble ionic compound)
Strong acid/strong electrolyte
Strong base/strong electrolyte
Weak acid/weak electrolyte
Weak (molecular) base/weak electrolyte
Strong base/strong electrolyte
Strong electrolyte (soluble ionic compound)
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