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UIUC, Feb 5th (2013) Superconductivities of doped Weyl semimetals Phys. Rev. B. 86, 214514 (2012) - Editors’ suggestion Gil Young Cho UC Berkeley Jens H Bardarson Yuan-Ming Lu Joel E Moore UIUC, Feb 5th (2013) Plan. • Part 1 : superconductivities of doped WSM – Motivations, Weyl semimetals? – BCS or FFLO superconductivity? – Topological Defects in FFLO SC-ivity • Part 2 : Proximate phases of Z2 spin liquid on Kagome lattice (GYC, YML and AV, in preparation) • Z2 spin liquid in Kagome lattice • Proximate phases of Z2 spin liquid Ashvin Vishwanath Part 1. I. Superconductivity of doped Weyl semimetals Hedgehogs in momentum space Weyl semimetals = 3D graphene? • graphene? Dirac fermion in 2D Honeycomb lattice of graphene 𝐻 = 𝑣𝐷 (𝜎𝑥 𝑘𝑥 + 𝜎𝑦 𝑘𝑦 ) − 𝜇 Here 𝝈𝒂 acts on sublattice basis (A-B sublattice) Weyl semimetals = 3D graphene? graphene: 𝐻 = 𝑣𝐷 (𝜎𝑥 𝑘𝑥 + 𝜎𝑦 𝑘𝑦 ) − 𝜇 Weyl SM: 𝐻 = 𝑣𝐷 (𝜎𝑥 𝑘𝑥 + 𝜎𝑦 𝑘𝑦 + 𝜎𝑧 𝑘𝑧 ) − 𝜇 ~ two-component Weyl fermion in HEP In general, WSM is described by 𝑣𝑎 ⋅ 𝑞 𝜎 𝑎 𝐻= 𝑎=1..3 with the chirality 𝑐 = 𝑠𝑔𝑛 ( 𝑣1 ⋅ 𝑣2 × 𝑣3 ) Material: iridates, layered top. Ins., Tl𝐵𝑖 𝑆𝑒1−𝑥 𝑆𝑥 2 , HgCr2Se3 What is interesting in WSM? Ref. Wan et. al. (2011), Hosur et. al. (2012), Burkov et.al. (2011), Yang et.al. (2011) A. “robust-ness” of Weyl nodes: - no mass term for a single Weyl node: e.g 𝐻 = 𝑣 𝜎 ⋅ 𝑘 - “pair annihilation” is the only way to gap out! B. “flat” fermi arc surface state 𝑒2 C. three-dimensional anomalous Hall effect: 𝜎𝑥𝑦 ~ Δ𝜃 ℎ D. interesting transport phenomena E. Need to break time-reversal or/and inversion symmetry Review article: Ari Turner, and Ashvin Vishwanath, arxiv: 1301.0330 (2013) Where can we find Weyl semimetal phase? Topological insulator + “large enough” Time-reversal symmetry breaking Material: Fe/Cr doped 𝑇𝑙𝐵𝑖 𝑆𝑒1−𝑥 𝑆𝑥 2 Ref. Burkov et.al. (2011), Gil Young Cho (2011) “Top. Ins.”-based Weyl semimetals Ref. Gil Young Cho (2011) • Minimal model for Topological Insulators 𝑧 𝑥 𝐻 = 𝑣𝐷 𝜏 𝜎 ⋅ 𝑘 + 𝜏 𝑀 e.g. near the Γ-point in 𝐵𝑖2 𝑆𝑒3 𝜏 𝑎 : orbital degrees of freedom 𝜎 𝑎 : spin degrees of freedom • We add a time-reversal breaking term coming from magnetic impurities (e.g. Fe or Cr) in bulk 0 𝑧 𝐻𝑧𝑒𝑒𝑚𝑎𝑛 = 𝑚𝜏 𝜎 “Top. Ins.”-based Weyl semimetals 𝐻 = 𝑣𝐷 𝑧 𝜏 𝜎⋅𝑘 + • Spectrum for 𝑚 > 𝑀 E 𝑥 𝜏 𝑀 + 𝑧 𝑚𝜎 𝐾𝑍∗ = ± 𝑚2 − 𝑀2 away from the high sym. point Kz 𝚪 Winding # is -1 Winding # is +1 Ref. Gil Young Cho (2011) “Top. Ins.”-based Weyl semimetals M a. Top. Ins. – Triv. Ins. transition ≈ a fourcomponent Dirac fermion. Insulator m Insulator Material: Fe- or Cr- doped 𝑇𝑙𝐵𝑖 𝑆𝑒1−𝑥 𝑆𝑥 2 b. A four-component Dirac fermion can be “splitted” into a pair of twocomponent Weyl fermions Ref. Gil Young Cho (2011) Superconductivities of doped Weyl semimetal? Fermi surfaces due to doping + Attractive interactions between the electrons Why superconductivities? GY Cho, J Bardarson, YM Lu, and JE Moore, Phys. Rev. B. 86, 214514 (2012) I. Strong spin-orbit coupling e.g. A doped topological Insulator can become a topological superconductor II. Topological Winding # around Weyl nodes III. Disconnected Fermi pockets for small doping GY Cho, J Bardarson, YM Lu, and JE Moore, Phys. Rev. B. 86, 214514 (2012) In this talk: Study possible superconducting states emerging from a doped Weyl semimetal Our approach is… Following the spirit of Fu and Berg (2010) A. Consider a “minimal” model for a Weyl semimetal & dope the model slightly B. Add a “phenomenological” attractive interaction to the model C. Classify possible superconductivities D. Compare energies of SC states Minimal Lattice model for Weyl semimetals Ref. Yang et.al (2011) A. The minimal model has two bands touching each other at two Weyl points E It can be modeled with “spin-ful” electrons 𝒄↑,↓ with spin-orbit coupling in a cubic lattice : Kz 𝒄𝒋,↓ 𝒄𝒊,↑ 𝚪 site j site i H = −𝑖𝜆𝑆𝑂𝐼 { 𝑐𝑖,𝛼 ∗ 𝜎 𝑥 𝛼𝛽 𝑐 𝑖+𝑥,𝛽 + 𝑐𝑖,𝛼 ∗ 𝜎 𝑦 +𝑀 𝛼𝛽 𝑐 𝑖+𝑦 ,𝛽 } + ℎ. 𝑐 𝑐𝑖,𝛼 ∗ (𝜎 𝑧 )𝑐𝑖,𝛽 − 𝑡 {𝑐𝑖,↑ ∗ 𝑐𝑗,↑ − 𝑐𝑖,↓ ∗ 𝑐𝑗,↓ } - Pauli matrices 𝜎 𝑎 acts on the spin index ↑, ↓ of the electron 𝑐↑/↓ Minimal Lattice model for Weyl semimetals Ref. Yang et.al (2011) Minimal model on cubic lattice (broken time-reversal symmetry) 𝐻 = 𝐻1 𝑘𝑥 , 𝑘𝑦 , 𝑀 + 𝐻2 (𝑘𝑧 , 𝑚) 𝐻1 𝑘𝑥 , 𝑘𝑦 , 𝑀 = 𝜎 𝑥 sin 𝑘𝑥 + 𝜎 𝑦 sin 𝑘𝑦 + 𝑀𝜎 𝑧 (2 − cos 𝑘𝑥 − cos 𝑘𝑦 ) 𝐻2 𝑘𝑧 , 𝑚 = 𝑚𝜎 𝑧 (cos 𝑘𝑧 − cos 𝑄) Important properties of the Hamiltonian I. Two Weyl nodes at 𝑘𝑧 = ±𝑄 and 𝑘𝑥 = 𝑘𝑦 = 0 II. no spin rotational symmetry ( spin~〈𝜎 𝑎 〉 ) (~ strong spin-orbit coupling) III. symmetry = lattice symmetry 𝐶4ℎ (~ pairing should be classified by 𝐶4ℎ ) Doping the minimal model A. There are two “fermi pockets” around the nodes with “spin-momentum locking” e.g. near the upper node 𝐻+ = 𝜎𝑥 𝑘𝑥 + 𝜎𝑦 𝑘𝑦 + 𝜎 𝑧 (𝑘𝑧 −𝑄) − 𝜇 Note: winding around the node is ±1 B. To study a superconducting instabilities, we add a “simplest” on-site attractive interaction 𝛿𝐻 = −𝑉0 𝑛↑ (𝑟)𝑛↓ (𝑟) 𝑟 e.g. phonon-mediated attractive interaction Possible BCS superconducting states A. The interaction is completely “local” and thus the electrons are paired in “singlet” channel (due to Pauli’s exclusion principle). Pairing interaction is local in real space = pairing gap is constant in momentum space B. So the mean-field state should be “singlet” BCS pairing 𝛿𝐻 = Δ 𝜓 ∗ 𝑢 𝑘 𝜓 ∗ 𝑑 −𝑘 + ℎ. 𝑐. note: the total momentum carried by the pairing is zero; so it should be “inter”-nodal pairing Possible BCS superconducting states BCS state: “inter-nodal” + “singlet” (trivial rep of the lattice sym.) Note: To be paired in singlet channel, spins need to be anti-parallel The nodes are “Weyl” nodes ! Possible FFLO superconducting states A. There is another competing superconducting state for the doped Weyl semimetal ~ FFLO pairing (FFLO state: “intra-nodal” + “singlet” ) 𝛿𝐻 = Δ± 𝜓 ∗ 𝑢 ±𝑄 + 𝑘 𝜓 ∗ 𝑑 ±𝑄 − 𝑘 + ℎ. 𝑐. note: the pairing “𝚫± ” carry crystal momenta ±𝟐𝑸 note: this FFLO is fully gapped B. Why this state can be better than BCS state? - the effective “DOS” participating to the BCS pairing is reduced because the spin states at 𝑘 and −𝑘 are not anti-parallel. - However, FFLO state connects anti-parallel spins Mean-field Energy of superconducting states So.. FFLO state wins against BCS state in the doped Weyl semimetal Physical properties of FFLO superconductivity in WSM ?? FFLO superconducting states A. We have two independent pairings “𝚫± ” for each node 𝛿𝐻 = Δ± 𝜓 ∗ 𝑢 ±𝑄 + 𝑘 𝜓 ∗ 𝑑 ±𝑄 − 𝑘 + ℎ. 𝑐. which can be compactly written as a wave in real space Δ 𝑟 = Δ cos(2𝑄 ⋅ 𝑟 + 𝛿𝜙) a. so there should be “density modulation” in FFLO state b. center of momentum is fixed by the positions of Weyl nodes (in the iridates, we have 24 Weyl nodes) B. FFLO state has a half-quantum vortex and a usual full quantum vortex half-quantum vortex : a unit winding in only one of the two pairings full quantum vortex: a composite of two half-quantum vortices Any “exotic” interesting bound state to these vortices? Lesson From superconducting doped Top. Ins. Any interesting bound mode to vortex? Ref. Fu and Berg (2010) Example. Topological SC from a doped Topological Insulator CuBiSe E i) kx Fermi surface is two-fold degenerate, related by Tsymmetry ii) Each fermi surface encloses a non-trivial winding # +1 or -1 iii) Vortex realizes “two zero modes” related by T-symmetry, or “a helical Majorana mode” 𝛾↑,𝑘 = 𝛾 ∗ ↑,−𝑘 , 𝐸 = +𝑣𝑘 𝛾↓,𝑘 = 𝛾 ∗ ↓,−𝑘 , 𝐸 = −𝑣𝑘 Vortex Similarty & Difference from doped Top. Ins. Similarities i) Fermi surface encloses a winding # ii) Fully gapped (robust topological feature) Differences i) No time-reversal symmetry = no helical state; at best chiral or gapped states at vortex ii) Order parameter space = 𝑆 1 × 𝑆 1 in FFLO, instead of 𝑆 1 in usual SC = more topological defect types in FFLO = half-quantum vortex in FFLO e.g. spinful p+ip superconductor; we have a direction 𝒅 ∈ 𝑺𝟏 and a phase 𝒆𝒊𝜽 ∈ 𝑺𝟏 see Ivanov (2000) Half-quantum vortex in FFLO superconducting states A. Half-quantum vortex corresponds to arg(Δ+ ) → arg(Δ+ ) + 2𝜋 arg Δ− → arg(Δ− ) i.e., only the phase of 𝚫+ winds once B. The Fermi surface around the node carries a unit “topological” winding number C. Hence there is ‘a zero mode’ or a chiral Majorana mode in the half-quantum vortex. (i.e., 𝛾𝑘 = 𝛾 ∗ −𝑘 , 𝐸 = +𝑣𝑘) A quick way to see a chiral zero mode in the vortex: One node of the doped Weyl semimetal is “half” of the “topological superconductor” Possible Majorana mode at a full vortex A. Bring two half-quantum vortices with opposite chiral Majorana modes Half-quantum vortices B. In the vortex, we have a “helical” Majorana mode which is not protected C. The helical Majorana mode will be gapped D. There are two possibilities for the gapped phase; weak pairing and strong pairing phases ref. Kitaev (2000) E. In the weak pairing phase, we have a bound Majorana zero mode at the end of the vortex A dangling Majorana mode Full quantum vortex Conclusion I. We found FFLO state is competing with BCS state (FFLO is energetically better than BCS in our model) II. FFLO state I. Density modulation with the momenta fixed by position of Weyl nodes II. Chiral Majorana mode at half-quantum vortex III. Possible Majorana zero mode at full vortex UIUC, Feb 5th (2013) Part 2. II. Proximate phases of 𝑍2 spin liquid on Kagome lattice (Gil Young Cho, Yuan-Ming Lu and Ashvin Vishwanath, in preparation) Yuan-Ming Lu Ashvin Vishwanath 𝑍2 spin liquid on Kagome lattice • Heisenberg interaction on Kagome lattice : Materials: dMIT, Herbertsmithite DMRG studies found a Z2 spin liquid! A. Gapped B. Topological Entanglement Entropy Ref. Yan Huse and White (2011) Jiang Wang and Balents (2012) Which Spin liquid ? Ref. Hastings (2000) Ran, Hermele, Lee, and Wen (2007) Hermele, Ran, Lee, and Wen (2008) • Many different spin liquids from the fermionic rep. of spin-1/2 The (relatively) low energy state is, “U(1) Dirac spin liquid“ (among the fermionic SL ansatz) This state features: A. Dirac spectrum for fermions B. U(1) Gauge theory Not consistent with DMRG result Is there a Z2 spin liquid near the U(1) Ref. Lu, Ran, and Lee (2011) Dirac spin liquid? Requirement 1: gauge theory should be broken from U(1) to Z2 Pairing of Dirac fermions! Requirement 2: Invariant under the lattice symmetry operation + Invariant under the spin rotation operation Requirement 3: Pairing should gap out the Dirac fermion There is one and only one such pairing satisfying the requirements! s-wave pairing of Dirac fermion What can we tell about this Z2 state? (Gil Young Cho, Yuan-Ming Lu and Ashvin Vishwanath, in preparation) Our claim is: If this Z2 spin liquid is the spin liquid found in DMRG study, it should have very specific proximate phases separated by a continuous transition from the spin liquid. A. Q=0 non-collinear magnetic ordered state B. VBS phase with the very specific bond-bond correlation Proximate phases Special 5-tuplets of masses of Dirac fermions = WZW term for 5-tuplet masses = Unconventional second order transitions Ref. Wiegmann and Abanov (2000), Senthil and Fisher (2006), Grover and Senthil (2008), Ryu, Mudry, Hou, and Chamon (2009), Herbut (2010) etc. Underlying physics of WZW term: • topological defect in one phase carries the quantum numbers related to the other phase • Condensation of the defect = destroying one ordering + inducing the other order Q=0 non-collinear magnetic order and Z2 spin liquid Monopole quantum #s of U(1) SL Vison∼ spin-1/2 𝑄 = 0 state Q=0 non-collinear magnetic orders 𝑛𝑟 = 𝑉= Result : Sachdev (1992) = Continuous transition ?! Nature of the VBS phase Order parameters for VBS pattern 𝑵 are at M-points in BZ • At least two of M-points should participate • All the lattice symmetries (except translational symmetries) are broken • 12-site unit cell (“quadrupled” unit cell) e.g. Diamond pattern found in DMRG has 12-site unit cell patterns BZ ky M- points Two Dirac nodes kx Ex. Bond ordering patterns at M-points BZ Ex. Bond ordering patterns at M-points BZ Conclusion I. We have studied the proximate symmetry broken phases of a particular Z2 spin liquid II. Q=0 non-collinear magnetic ordered state - This allows us to identify the fermionic Z2 spin liquid as the bosonic Q1=Q2 spin liquid III. VBS state - superposition of VBS patterns at M-points - 12-site unit cell with broken lattice symmetries IV. More direct probe? My previous research: Thanks! (1) Topological BF theory description of topological Insulator (2011) (2) Quantum Phase transition and fractionalization in a topological insulator thin film with Zeeman and excitonic masses (2011) (3) Weyl semimetal in magnetically doped topological insulator (2011) (4) Dyon condensation in topological Mott insulator (2012) (5) Gapless edge state of BF field theory and Z2 spin liquids, (2012) (6) Superconductivities of doped Weyl semimetals, (2012) (7) Two dimensional symmetry protected phases with PSU(N) and time reversal symmetry, (2012) (8) Proximate phases of Z2 spin liquid on Kagome lattice, in preparetion My collaborators: C. Xu (UCSB) J. E. Moore (UCB) Y.-M. Lu Y.B. Kim (U Toronto) (UCB) A. Vishwanath J.H Bardarson (UCB) (UCB)