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BALANCING CHEMICAL REACTIONS Reactants: Zn + I2 Product: Zn I2 1 Introduction – Chemical reactions occur when bonds between atoms are formed or broken – Chemical reactions involve changes in matter, the making of new materials with new properties, and energy changes. 2 3 Chemical Equations Depict the kind of reactants and products and their relative amounts in a reaction. 4 Al (s) + 3 O2 (g) ---> 2 Al2O3 (s) The numbers in the front are called stoichiometric coefficients The letters (s), (g), (l), and (aq) are the physical states of compounds. Symbols Used in Chemical Equations + Used to separate two reactants or two products “Yields,” separates reactants from products Used in place of for reversible reactions (s) Indicates a solid state; placed after the formula (l) Indicates a liquid state: placed after the formula (g) Indicates a gaseous state; placed after the formula (aq) Indicates an aqueous solution; the substance is dissolved in water; placed after the formula Δ Heat Pt Indicates that heat is supplied to the reaction A formula written above or below the yield sign indicates its use as a catalyst (in this example, platinum). 4 5 Conservation of Mass • Mass cannot be created or destroyed • The amount of mass you start out with is the amount you end with • Equation: MASSREACTANTS = MASSPRODUCTS 6 Examples: H2 + O2 H2O 2.00g + 2.00g = 4.00g 7.00g + 6.00g = 13.0g 250g + 450g = 700g Chemical Equations Because of the principle of the conservation of matter, an equation must be balanced. It must have the same number of atoms of the same kind on both sides. Lavoisier, 1788 7 Balancing Equations – When balancing a chemical rxn, you may add coefficients in front of the cpds to balance the reaction, but you may not change the subscripts. • Changing the subscripts changes the compound. 8 Subscripts vs. Coefficients 9 • The subscripts tell you how many atoms of a particular element are in a compound. The coefficient tells you about the quantity, or number, of molecules of the compound. Coefficients What is a coefficient? XY2 2XY XY2 A Number that goes in front of a variable What is the distributive property? 3(X+Y) = 3X+3Y 3(X2Y) 2(XY3)2 X= 6 Y= 3 4(H2O)2 X= 4 Y = 12 H = 16 O= 8 10 11 Steps to Balancing Equations 12 There are four basic steps to balancing a chemical equation. 1. Write the correct formula for the reactants and the products. DO NOT TRY TO BALANCE IT YET! DO NOT CHANGE THE FORMULAS! 2. Find the number of atoms for each element on the left side. Compare those against the number of the atoms of the same element on the right side. 3. Determine where to place coefficients in front of formulas so that the left side has the same number of atoms as the right side for EACH element in order to balance the equation. 4. Check your answer to see if: • The numbers of atoms on both sides of the equation are now balanced. • The coefficients are in the lowest possible whole number ratios. (reduced) Some Suggestions to Help You – You can use a RAP chart to keep atoms straight – Take one element at a time. Save H and O until last. – IF everything balances except for O, and there is no way to balance O with a whole number, double all the coefficients and try again. (Because O is diatomic as an element) – (Shortcut) Polyatomic ions that appear on both sides of the equation should be balanced as independent units 13 Balancing Equations 2 H2 + O2 2 H2O Reactant Atoms Atoms’ Symbol 2 4 H 2 4 O 1 2 2 Product Atoms 14 Balancing Equations 2 Al(s) + 3 Br2(l) Reactant Atoms Atoms’ Symbol Al2Br6(s) Product Atoms 1 2 Al 2 2 6 Br 6 15 16 Ca + 2 H2O → Ca(OH)2 + H2 BALANCED! Reactant Atoms Element Symbol 1,2,1,1 Product Atoms 1 Ca 1 2 4 H 4 1 2 O 2 17 2 Al(OH)3 + 3 H2SO4 → Reactant Atoms Al2(SO4)3 + 6 H2O Element Product BALANCED! Symbol Atoms 12 Al 2 3 6 O 1 6 5 8 12 H 2 12 1 3 SO4 3 2,3,1,6 18 Balancing Equations 5 O2(g)-->___CO 3 4 2O(g) __C3H8(g) + __ 2(g) + __H 2 4H10(g) +__O 5 2O(g) 2 __B 11 2(g) --->__B 4 2O3(g) + 10 __H Balancing Equations Sodium phosphate + iron (III) oxide sodium oxide + iron (III) phosphate 2 Na3PO4 + Fe2O3 ---->3Na2O +2 FePO4 19