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ATOMIC STRUCTURE The Theory of the Atom _______________, a famous Greek teacher who lived in the 4th Century B.C., first suggested the idea of the atom. • Said that all matter is composed of tiny, _____________ particles called __________ (atoms) In 1803, _______________ studied experiments and concluded that the properties of matter could be explained in terms of __________. Dalton’s _________________ was based on the following ideas: o Each __________ is composed of extremely small particles called atoms. o All atoms of a given element are ___________, but they differ from those of any other element. o Atoms are neither __________ nor _________ in any chemical reaction. o A given ____________ always has the same relative numbers and kinds of atoms. The Atom The smallest particle of an ___________ is an atom. The atom is made up of three ____________ particles: ___________, _____________, and ___________ Proton Discovered in ________ by E. Goldstein Has a ____________ charge Electron Discovered in 1897 by _________________ Has a _____________ charge Its __________ is much smaller than the other 2 subatomic particles; therefore its mass is usually _____________ Neutron Discovered in 1932 by __________________ Has no charge (i.e. It is ____________) Has about the same __________ as a ____________ Nuclear Atomic Structure The atom is made up of 2 parts/sections (1) The _____________ --- (in the center of the atom; contains protons and neutrons) (2) The ___________________ --- (surrounds the nucleus) The Nucleus Discovered by Ernest ________________ in _______. He shot a beam of positively charged “alpha particles”, which are ___________ nuclei, at a thin sheet of _______________. 99.9% of the particles went right on through to the _________. Some were slightly deflected. Some even _________________ towards the source! This would be like shooting a cannon ball at a piece of tissue paper and having it bounce off. Conclusions About the Nucleus (1) Most of the atom is more or less ___________________. (2) The nucleus is very _________. (Stadium Analogy) (3) The nucleus is very _________. (Large Mass ÷ Small Volume) (4) The nucleus is _____________ charged. • • • • Counting Subatomic Particles in an Atom The atomic # of an element equals the number of ____________ in the nucleus. The mass # of an element equals the sum of the _____________ and ______________ in the nucleus. In a neutral atom, the # of protons = # of ______________. To calculate the # of neutrons in the nucleus, ______________ the ___________ # from the __________ #. Practice Problems (1) Find the # of e-, p+ and n0 for sodium. (mass # = 23) 2) Find the # of e-, p+ and n0 for uranium. (mass # = 238) 3) What is the atomic # and mass # for the following atom? # e- = 15; # n0 = 16 Ions • When an atom loses or gains one or more _________, it acquires a net electrical charge and is called an _____. • An ion that has more electrons than protons has a ________ charge. An ion that has fewer electrons that protons has a _________ charge. Charge of ion = # of protons - # of electrons Practice Problems 1) A neutral magnesium atom (atomic number 12) has 12 protons and 12 electrons. If the atom loses 2 electrons, what is the charge of the resulting ion? 2) How many electrons would be found in the ion O2-? 3) If an ion has 28 protons and 26 electrons, what is its charge? What is its symbol (including charge)? • • • • • Isotopes An isotope refers to atoms that have the same # of ___________, but they have a different # of ___________. Because of this, they have different _________ #’s (or simply, different ___________.) Isotopes are the same element, but the atoms weigh a different amount because of the # of ______________. Examples---> (1) Carbon-12 & Carbon-13 (2) Chlorine-35 & Chlorine-37 (The # shown after the name is the mass #.) For each example, the elements have identical ___________ #’s, (# of p+) but different _________ #’s, (# of n0). Another way to write the isotopes in shorthand is as follows: The top number is the ________ #, and the bottom # is the __________ number. Calculating the # n0 can be found by _____________ the #’s! More Practice Problems (1) Find the # e-, p+ and n0 for Xe-131. 2) Find the # e-, p+ and n0 for C 3) Write a shorthand way to represent the following isotope: # e- = 1 # n0 = 0 # p+ = 1 Atomic Mass • Based on the relative mass of Carbon-12 which is exactly _______. • 1 p+ ≈ __ atomic mass unit (amu) 1 n0 ≈ __ amu 1e- ≈ __ amu • The atomic masses listed in the Periodic Table are a “weighted average” of all the isotopes of the element. Practice Problems: (1) Mrs. Smith’s geometry semester grades are calculated using a weighted average of three category scores: Tests/Quizzes= 60% of your grade Homework/Classwork= 30% of your grade Final Exam=10% of your grade • If a student had the following scores, what would they receive for the semester? Tests/Quizzes = 80 (B-) Homework/Classwork = 60 (D-) Final Exam Exam=65 (D) Step (1): Multiply each score by the % that it is weighted. Step (2): Add these products up, and that is the weighted average! A “normal average” would be calculated by simply adding the raw scores together and dividing by 3… 80 + 60 + 65 = 205 ÷ 3 = 68.3 = D (2) In chemistry, chlorine has 2 isotopes: Cl-35 (75.8% abundance) Cl-37 (24.23 % abundance) What is the weighted average atomic mass of chlorine? (3) Oxygen has 3 isotopes: O-16 (99.76%) O-17 (0.037%) O-18 (0.2%) Estimate oxygen’s average atomic mass.