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Chem 101 Lesson 4 Reading Guide Modern Atomic Theory: Chapter 11.1 11.11 pages 302-331 Directions: Fill in the answer or select the correct answer from the choices given in parentheses. If a number in parentheses follows the question (like (F11.4)) it means you should look at Figure 11.4 in the text for the answer. This is a longer Chapter than normal, so occasionally, Section numbers will be given to let you know that the following questions will come from the new referenced section and following sections. 1. ______________________ is the distance a light wave travels to complete one cycle, the distance between two peaks on a wave. (F11.3) 2. _____________________ refers to the number of wave cycles completed in 1 second or the number of peaks that pass a given point in one second. 3. The wavelength of red light is _________(longer, shorter) than the wavelength of blue light. (F11.6) 4. Light with a longer wavelength has ___________(more, less) energy than light with a shorter wavelength. This means that red light has __________(more, less) energy than blue light. (F11.6) 5. The visible spectrum refers to energy that has wavelengths between _______ and ______ nm. (F11.4) 6. Ultraviolet light has a wavelength (less than, greater than) visible light, while infrared light has a wavelength (less than, greater than) visible light. (F11.4) 7. The wavelength and frequency of light are inversely related, which means as wavelength increases, the frequency decreases and vice versa. Refer to Figure 11.4 to answer this question. Comparing X-rays and microwaves, which has the larger a) frequency? _________________ b) wavelength? _______________ c) energy? ____________ 8. Energy from an excited atom is released as a _______________, which is a form of light. Section 11.4-11.5 9. Spectral lines seen for hydrogen were caused by excited electrons dropping from __________________ energy levels in the atom to __________________ energy levels in the atom. The red colored line corresponded to the electron transition with the _____________ amount of energy, while the violet colored line corresponded to the electron transition with the ____________ amount of energy. (F11.11) 10. Experimental evidence for Bohr’s model of the atom came from the ______________atom. 11. Observing that each element has its own unique set of spectral lines leads us to believe that the differences between energy levels in atoms of different elements must be _______________( the same, different). Section 11.7 12. The lowest energy state for hydrogen electrons is the ______orbital or ground state. 13. It has been determined that the energy levels of electrons in hydrogen atoms contain sublevels with different shapes. They have been designated as ____, _____, ______, and _______. 14. The number of sublevels in each main energy level corresponds to the number of the main energy level. For example, energy level 1 contains only ________ sublevel, while energy level 2 contains ______ sublevels. 15. Indicate the maximum number of electrons that can exist in each of the following sublevels. s ____ p ____ d _____ f _____ 16. Electrons that have higher energies exist _____________ (closer to , farther from) the nucleus. Section 11.8 17. What is the Pauli Exclusion Principle? Section 11.9 18. Write the electron configuration and orbital diagram for the 1st 18 elements on the periodic table. Use the back of this page or your own paper. Section 11.10 19. Within a given energy level, the order in which the sublevels are filled is ___, ____, ____, then ____. 20. The d orbitals of an energy level are always filled after the ___ orbitals of the next higher energy level have been filled. 21. Which sublevel gains electrons after each of the following sublevels is filled? a) 2p _______ b) 3p ______ c) 3d _______ d) 5s _____ 21. In the following representation of part of an electron configuration, indicate what each number and letter represent. (choose from principle energy level, sublevel or shape, and number of electrons in the sublevel) 3p4 22. Write the electron configuration for the element nitrogen, whose atomic number is 7. 23. The shapes of the orbitals are described as follows: s _________________ p ______________ 24. Group IA elements are called _____________ ___________. 25. Group IIA elements are called ______________________ ______________ _______________. 26. Group VIIA elements are called _____________________. 27. Group VIIIA elements are called _____________ or __________ gases. 28. The periodic table can be divided into four major blocks based on the type of orbitals that are being filled. Referring to section 6.6 in your text, complete the following. (F11.31, F11.34) s- block elements = elements in Groups _____ and _____ p-block elements = elements in Groups ___ through _______ The s- and p- block elements together are referred to as the ______- _________ or _________________________________ elements. d-block elements = the ____________________________ metals or elements f-block elements = the _______ - ____________________________ elements The atomic radius is the distance from the nucleus to the outermost electrons. The atomic radius is half of the atomic size and the trends shown in Figure 11.36 for atomic size also apply to the atomic radius. 29. The atomic radius __________________( decreases, increases) as you move up a group of elements due to the elements at the top of the table having _______________ (fewer, more) energy levels occupied by electrons. 30. The atomic radius __________________ (decreases, increases) as you move from left to right in a period due to the increase in the number of _______________ in the nucleus which _______________ the nuclear charge leading to a greater attraction for the electrons in the atom. 31. Metals tend to _________ (gain, lose) their outermost electrons when they react. 32. Metallic character is a measure of how easily an element loses its outermost electrons. It is observed that as you move down a group of elements, the metallic character of the elements _____________(decreases, increases), and as you move from right to left across a period, the metallic character of the elements ________________ (decreases, increases). 33. What can you conclude about the relationship between the metallic character of an element and its atomic radius? In other words, if you have an element with a large amount of metallic character, would you expect it to have a large or small atomic radius? ______________________________________ 34. Elements in the same group or family react in _________________ (different, similar) ways. 35. The outermost electrons of an atom are the electrons involved in chemical reactions. These electrons are called __________________ electrons and are equal to the total number of _____ and _____ electrons in the outermost energy level. Because of this, the maximum number of these electrons in an atom is ______________. 36. We can predict the number of valence electrons by noting the ____________ number of the family they are in, if they are a representative element. 37. Indicate the number of valence electrons in the following elements. B ____ Ca ____ K _____ P ______ Cl _____ 38. Any atom bearing a charge has had electrons removed or added and is called an _______. 39. The amount of energy needed to remove an electron from a neutral atom in the gaseous state is called the __________________________ energy. 40. The ionization energy (I.E.) __________________ (decreases, increases) up a group of elements, while it _____________________ (decreases, increases) from left to right across a period. 41. Ionization energy ____________________ (decreases, increases) as the atomic radius increases. 42. Which of the following elements has the larger I.E. ? Ba or Ca _______ Al or Cl _____ 43. In general, when metals and nonmetals react, the metal atom becomes a ion with a ________________ (negative, positive) charge, while the nonmetal ___________( gains, loses) electrons and becomes an ion with a _______________(negative, positive) charge.