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Guided Reading Section 1 (Unit 3) (Chapter 3) 1. An atom is_______________________________________________________________ _______________________________________________________________________________________________ 2. Which Greek thinker, as early as 400 B.C., supported the particle theory of matter? __________________________________________ 3. Where did the name atom originate?__________________________________________ _______________________________________________________________________________________________ Foundations of Atomic Theory 4. Finish these sentences: a. An element is a substance________________________________________________ _____________________________________________________________________. b. Elements combine to form________________________________________________ _____________________________________________________________________________________________ _______________________________________________. c. The transformation of a substance__________________________________________ _____________________________________________________________________________________________ _______________________________________________. 5. State the law of the conservation of mass.______________________________________ ________________________________________________________________________________________________ ________________________________________________ Dalton's Atomic Theory 6. In 1808, an English schoolteacher named _________________________________ proposed an explanation for the law of the conservation of mass. 7. Finish these statements that sum up his theory. a. All matter is composed of extremely small particles called ________________. b. Atoms of a given element are identical in __________________________________ ______________________; atoms of different elements ____________ in size, mass, and other properties. c. Atoms cannot be ______________________________________________________. d. Atoms of different elements combine in simple _______________________________ to form ______________________________________. e. In chemical reactions, atoms are__________________________________________ _____________________________. Modern Atomic Theory 8. Which aspects of Dalton's theory have been proven incorrect? a.___________________________________________________________________ b.___________________________________________________________________________________________ _____________________________________________ 9. What two important concepts remain unchanged? a.____________________________________________________________________ b.___________________________________________________________________________________________ 10. All atoms consist of _____________________________________. 11. The ____________________ is a very small region located at the _______________ of the atom. 12. The nucleus is made up of at least one positively charged particle called a ____________________ and usually one or more neutral particles called ______________________. 13. Surrounding the nucleus is a region occupied by negatively charged particles called ___________________________. 14. Protons, neutrons, and electrons are often referred to as _____________________________________. Discovery of the Electron 15. What did investigators notice when current was passed through a cathode-ray tube?_______________ __________________________________________________________________________________ 16. What two hypotheses did these investigators propose? a._________________________________________________________________________________ b._________________________________________________________________________________ 17. What did the English physicist J. J. Thomson conclude?______________________________________ ___________________________________________________________________________________ ___________________________________________________________________________________ 18. Cathode rays have _____________________ properties regardless of the element used to produce them. Therefore, it was concluded that ____________________ are present in atoms of all elements. 19. Which American physicist measured the charge of the electron? ______________________________ 20. Based on what was learned about electrons, what two inferences were made about atomic structure? a.__________________________________________________________________________________ __________________________________________________________________________________ b.__________________________________________________________________________________ _______________________________________________________________________________ 21. What was the name of the model that Thomson proposed? ___________________________________ Discovery of the Atomic Nucleus 22. What did Ernest Rutherford expect to happen when he bombarded a thin piece of gold foil with alpha particles?__________________________________________________________________________ 23. What happened instead? ______________________________________________________________ 24. How did Rutherford describe this?_______________________________________________________ ___________________________________________________________________________________ 25. What conclusions did Rutherford come to? a.______________________________________________________________________________________________ ____________________________________________________________________ b.______________________________________________________________________________________________ _____________________________________________________________________ c.______________________________________________________________________________________________ _____________________________________________________________________ 26. What did Rutherford call the positive bundle of matter at the center of the atom? __________________ 27. If the nucleus were the size of a marble, how would it compare to the size of the atom? ___________________________________________________________________________________ 28. Which of Rutherford's students proposed a model showing the positions of the electrons? ________________________ Composition of the Atomic Nucleus 29. Except for the simplest hydrogen atom, all atomic nuclei contain _______________ and __________________. 30. A proton has a positive charge _______________ in magnitude to the negative charge of an electron. 21. Atoms are electrically _____________________ because they contain equal numbers of protons and electrons. 32. Which particle determines the identity of an atom? _____________________ 33. What do we call the forces that hold together the protons and neutrons in a nucleus? ___________________ 34. Fill in the following table. Properties of Subatomic Particles Particle Electron Proton Neutron Symbols Relative Charge Mass Number Relative Mass (amu) Actual Mass (kg) Atomic Number 35. Define atomic number:_________________________________________________________ 36. Which number identifies an element? _____________________________________________ 37. How do we know that a silver atom has 47 electrons?_______________________________________________ Isotopes 38. What are the names of the three hydrogen isotopes, and how many neutrons does each have? a._________________________________________________ b._________________________________________________ c._________________________________________________ 39. Define isotope:_______________________________________________________________ ___________________________________________________________________________ 40. Isotopes of a particular element have the same number of _____________________ and ____________________, but different numbers of ________________________. Mass Number 41. What information is needed to identify an isotope?____________________________________ ___________________________________________________________________________ 42. Define mass number:___________________________________________________________ ___________________________________________________________________________ Designating Isotopes 43. What are the two methods for designating an isotope? a.______________________________________________________________________ b.______________________________________________________________________ 44. Give an example of each method using the uranium isotope used as fuel for nuclear power. a. ________________________________________ b.________________________________________ 45. In an isotope's nuclear symbol, what does the superscript (top number) indicate? ___________________________________________________________________________ 46. In an isotope's nuclear symbol, what does the subscript (bottom number) indicate? ___________________________________________________________________________ 47. How can we determine the number of neutrons?____________________________________ ___________________________________________________________________________ Relative Atomic Masses 48. Why do scientists use a relative atomic mass rather than the actual atomic mass? ______________________________________________________________________________________________ ________________________________________________________ 49. Which isotope has been chosen as the standard?_____________________________________ 50. What mass has arbitrarily been assigned to this isotope?______________________________ 51. Define atomic mass unit:_______________________________________________________ ___________________________________________________________________________ Average Atomic Masses of Elements 52. Most elements occur naturally as _________________ of isotopes. 53. Define average atomic mass:___________________________________________________ ______________________________________________________________________________________________ 54. What two factors does the average atomic mass depend on? a. _______________________________________________ b._________________________________________________________________________ 55. How do we calculate average atomic mass?________________________________________ ________________________________________________________________________________________ Electrons as Waves 56. Which scientist hypothesized that electrons have wave-like properties? ________________________ The Heisenberg Uncertainty Principle 57. State the Heisenberg uncertainty principle:_______________________________________________ ______________________________________________________________________________________________ The Schrodinger Wave Equation 58. Which scientist used the hypothesis that electrons have a dual wave-particle nature to develop an equation that treated electrons in atoms as waves? _________________________________________ 59. Together with the Heisenberg uncertainty principle, the Schrodinger wave equation laid the foundation for __________________________________________________________________. 60. What is quantum theory?______________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________ 61. Define orbital:______________________________________________________________________ ______________________________________________________________________________________________ ______________________________________________________________________ Atomic Orbitals and Quantum Numbers 62. In the Bohr atomic model, electrons of increasing energy occupy _________________ farther and farther from the nucleus. 63. How is Schrodinger's model different from Bohr's model?___________________________________ ______________________________________________________________________________________________ ______________________________________________________________________ 64. What are quantum numbers?___________________________________________________________ __________________________________________________________________________________ Spin Quantum Number 65. The electron exists in one of two possible spin states, which creates a _______________________________________________________. 66. A single orbital can hold a maximum of how many electrons? ___________________ 67. These two electrons must have __________________________ spin states.