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Environmental Science Matter • Anything that has mass and takes up space • Solid, liquid, gas Energy • Does not take up space, no mass • Definition: Ability to do work Light Heat Electricity Element • Pure substance that cannot be broken down by ordinary chemical means • There are over 100 elements, below are the ones you will need to know. Carbon Hydrogen Oxygen Nitrogen Phosphorus Sulphur Sodium Potassium Fluorine Chlorine Calcium Iron Mercury Lead Element • Each element has a name and a 1-2 letter symbol. • The symbols are often the first letter of name or first letter and one additional. • Some symbols are based on latin names - e.g. natrium instead of sodium, ferrium instead of iron, plumbum instead of lead. Carbon C Hydrogen H Oxygen O Nitrogen N Phosphorus P Sulphur S Sodium Potassium Fluorine Chlorine Calcium Iron Na K F Cl Ca Fe Mercury Hg Lead Pb Compound • Substance that can be broken down by ordinary chemical means Water --> Hydrogen and Oxygen Sugar --> Carbon & Oxygen & Hydrogen Element • Elements are composed of atoms. • Different elements have different atoms. Carbon C Hydrogen H Oxygen O Nitrogen N Phosphorus P Sulphur S Sodium Potassium Fluorine Chlorine Calcium Iron Na Mercury Hg K Lead Pb F Cl Ca Fe Atom • Smallest particle of an element that has identity of element. • Composed of subatomic particles: • protons - positive charge • electrons - negative charge, much smaller than protons • neutrons - no charge, similar in size to protons Atom • Protons and neutrons occur in center of atom in region termed nucleus. • Below is a oxygen nucleus with 8 protons and 8 neutrons. • Different elements have different numbers of protons and neutrons in the nucleus. Nucleus Atom • Electrons occur outside the nucleus in regions called shells • The 1st shell holds 2 electrons. • The 2nd shell holds 8 electrons. • The 3rd shell holds 8 electrons. Oxygen Atom • Different elements have different numbers of electrons. • In neutral atoms, the number of electrons = the number of protons. • Oxygen has 8 electrons. Oxygen Atom • When placing electrons in shells, put the first 2 electrons in the first shell. They occur as a pair. Atom • Then add electrons to the 2nd shell. • The 2nd shell has 4 regions. • Put electrons individually in the 4 areas and then start pairing. • Observe the order in the next several slides. Atom • 3rd electron goes in 2nd shell Atom • 4th electron goes in next area of 2nd shell Atom • 5th electron goes in next area of 2nd shell. Atom • 6th electron goes in next area of 2nd shell Atom • When each of the 4 areas has one electron, then the electrons pair. • 7th electron pairs with 3rd. Oxygen Atom • 8th electron pairs with 4th. • Oxygen has only 8 electrons so we stop here. • Larger atoms have more electrons to fill this shell and then continue to 3rd shell which also has 4 areas. Sodium Atom •Sodium has 11 protons, 12 neutrons and 11 electrons. •The 11 protons and 12 neutrons go in the central nucleus. Sodium Atom • Put first 2 electrons in first shell (paired). Sodium Atom • Then add electrons to second shell. Sodium Atom • Then add electrons to second shell. Sodium Atom • Then add electrons to second shell. Sodium Atom • Then add electrons to second shell. Sodium Atom • Then add electrons to second shell. Sodium Atom • Then add electrons to second shell. Sodium Atom • Then add electrons to second shell. Sodium Atom • Then add electrons to second shell. Sodium Atom • When 2nd shell is full, add third shell. • Sodium has 11 electrons, so only 1 electron in 3rd shell. Periodic Table • The periodic table shows the elements and their symbols. • It gives info on the numbers of protons, neutrons and electrons. • The atomic number is the number of protons. All atoms of that element have that number of protons. • The atomic weight is the mass of the atom and indicates the number of protons, neutrons and electrons. Periodic Table Atomic Number = # protons Periodic Table Atomic Weight Atomic Weight • The atomic weight is the mass of the protons, neutrons and electrons. 8 Oxygen O 15.9994 • Since electrons have little mass, the atomic weight tells us the number of neutrons. • For example, Oxygen has an atomic number of 8 and atomic weight of 15.9994 = 16. • 8 is the number of protons. • Neutrons = 16 - 8 = 8 • Neutrons are similar in number to protons but not always the same. Isotopes • Atoms with the same number of protons but different number of neutrons. (The number refers to the weight.) C12 6 protons, 6 neutrons C14 6 protons, 8 neutrons Isotopes Uranium 235 Uranium 238 92 protons 143 neutrons 92 protons 146 neutrons • Uranium is used in nuclear power. • U238 is the most common isotope. • U235 is needed for nuclear power so mined Uranium is processed before use to get a higher percentage of U235. This is called enrichment. Theory • Scientific statement with high degree of certainty • Supported by many observations and tests Atomic Theory • Matter is composed of atoms Ions •Charged particles. • The number of protons does not equal the number of electrons. •Recall that electrons are on outer part of atom and protons are in central nucleus. •It is electrons that are gained or lost to form ions. •Protons do not change. Neutral Sodium Atom 11 protons 11 electrons 0 charge Sodium Ion 11 protons 10 electrons +1 charge Sodium Ion Symbol Na + •Note the charge is indicated by a superscript. •The + indicates +1 Sodium Ion Na + •Note that the outermost shell with electrons is full. •This is a stable condition. •Atoms form ions so that outermost shell is full. •Sodium ion is common and stable. Neutral Chlorine Atom 17 protons 17 electrons 0 charge 17 + 18 0 Chloride Ion 17 protons 18 electrons -1 charge 17 + 18 0 Chloride Ion Cl • Note that the 17 + 18 0 outermost shell with electrons is full. • The - subscript indicates a -1 charge. Molecules • 2 or more atoms or ions bonded together Na+ Cl- Ionic Bond Electrical Attraction between ions NaCl = Table Salt O H Covalent Bond Atoms Share Electrons Water H2O O H • • • • H Consists of 1 oxygen and 2 hydrogen atoms Has 2 covalent bonds Symbolized H2O The 2 as subscript indicates the number of atoms. Common Molecules H2O Water O H O H C O CO2 Carbon Dioxide NH3 N H H Ammonia H O O O2 Oxygen Gas Molecules N2 N N CH4 H C6H12O6 glucose Nitrogen Gas H C H Methane Gas H Chemical Reactions • Molecules are rearranged to form new molecules Start “Reactants” H2O O2 + H2 Finish “Products” • Note: This reaction is used to make hydrogen gas for fuel cells, an alternate fuel source. Chemical Reactions • Molecules are rearranged to form new molecules C6H12O6 + O2 CO2 + H2O N2 + H2 light CO2 + H2O C6H12O6 + O2 NH3 Respiration Photosynthesis Nitrogen Fixation Acid and Base • Acid - Molecule that breaks down in water to form H+ Hydrochloric Acid HCl H+ + Cl- HNO3 H+ + NO3- Nitric Acid • Base - Molecule that breaks down in water to form OHSodium Hydroxide NaOH Na+ + OH- pH • • Based on log scale Measure of H+ concentration ( pH = -log [H+] ) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 neutral acid base pH 1 means H+ concentration is 10-1 or .1 pH 7 means H+ concentration is 10-7 or .0000001 Thus pH 1 is more acidic than higher pH 7.