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CHEM1411,chapter 1-2-3 exercises 1. In 1828, the diameter of the U.S. dime was changed to approximately 18 mm. What is this diameter when expressed in nanometers? A) 1.8 109 nm B) 1.8 107 nm C) 1.8 101 nm D) 1.8 10–5 nm E) 1.8 10–10 nm 2. Which of the following is an example of a physical property? A) corrosiveness of sulfuric acid B) toxicity of cyanide C) flammability of gasoline D) neutralization of stomach acid with an antacid E) lead becomes a liquid when heated to 601oC 3. Express the number 0.000053 in scientific notation. A) 5.3 10-2 B) 5.3 10-3 C) 5.3 10-4 D) 5.3 10-5 E) 5.3 10-6 4. How many significant figures does the result of the following sum contain? 8.5201 + 1.93 A) 1 B) 2 C) 3 D) 4 E) 5 5. A piece of a metal alloy with a mass of 114 g was placed into a graduated cylinder that contained 25.0 mL of water, raising the water level to 42.5 mL. What is the density of the metal? A) 0.154 g/cm3 B) 0.592 g/cm3 C) 2.68 g/cm3 D) 6.51 g/cm3 E) 7.25 g/cm3 Page 1 6. An automobile engine has a piston displacement of 1,600 cm3. Express this volume in liters. 7. Which of the following elements is most likely to be a good conductor of electricity? A) N B) S C) He D) Cl E) Fe 8. A phosphide ion has: A) 10 protons and 13 electrons B) 12 protons and 15 electrons C) 15 protons and 15 electrons D) 15 protons and 18 electrons E) 18 protons and 21 electrons 9. What is the formula for the binary compound formed by potassium and nitrogen? A) KN B) K2N C) NK2 D) K3N E) NK3 10. Give the formula for cobalt(II) chlorate dihydrate A) CoCl2·2H2O B) CoClO3(H2O)2 C) Co(ClO3)2(H2O)2 D) Co(ClO3)2·2H2O E) Co2(ClO3)3·2H2O 11. How many protons are there in one atom of nickel? 12. Give the formula of copper(II) bromide. Page 2 13. There are two stable isotopes of chlorine: chlorine-35, with a mass of 34.968853 amu; and chlorine-37, with a mass of 36.965903. Given that the average atomic mass of a chlorine atom is 35.45 amu, which of the following statements is true? 35 A) Chlorine contains almost exclusively of 17 Cl , with very little 37 17 Cl. 35 B) Chlorine contains more 17 Cl than 37 17 Cl. C) Chlorine contains roughly equal amounts of 35 D) Chlorine contains more 37 17 Cl than 17 Cl. E) Chlorine contains almost exclusively of 37 17 35 17 Cl and 37 17 Cl. 35 Cl, with very little 17 Cl. 14. The mass of 1.21 1020 atoms of sulfur is A) 3.88 1021 g. B) 2.00 mg. C) 32.06 g. D) 6.44 mg. E) 2.00 10–4 g. 15. How many atoms are in 5.54 g of F2? A) 6.02 1023 atoms B) 0.146 atoms C) 0.292 atoms D) 8.78 1022 atoms E) 1.76 1023 atoms 16. What is the mass of 3.00 moles of ethanol, C2H6O? A) 4.99 10–24 g B) 138 g C) 6.52 10–2 g D) 50 g E) 1.81 1024 g 17. When 22.0 g NaCl and 21.0 g H2SO4 are mixed and react according to the equation below, which is the limiting reagent? 2NaCl + H2SO4 Na2SO4 + 2HCl A) NaCl B) H2SO4 C) Na2SO4 D) HCl E) No reagent is limiting. Page 3 18. When octane (C8H18) is burned in a particular internal combustion engine, the yield of products (carbon dioxide and water) is 93%. What mass of carbon dioxide will be produced in this engine when 15.0 g of octane is burned with 15.0 g of oxygen gas? A) 13. g B) 12. g C) 21 g D) 54. g E) 43. g 19. Calculate the percent composition by mass of carbon in Na2CO3. 20. Commonly used gases in the laboratory are generally obtained from pressurized metal gas cylinders, but for small amounts of occasionally used gases, it is sometimes easier just to prepare them chemically as needed. For example, nitrogen monoxide, NO(g), can be prepared in the lab by the following chemical reaction: 3Cu(s) + 8HNO3(aq) 2NO(g) + 3Cu(NO3)2(aq) + 4H2O(l) If 15 g of copper metal was added to an aqueous solution containing 6.0 moles of HNO3, how many moles of NO(g) would be produced, assuming a 75% yield. Page 4 Answer Key 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 20. B E D D D 1.6 L E D D D 28 CuBr2 B D E B A B 11.3% 0.12 mole NO Page 5