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Transcript
Modern Physics
(Bohr Model And X-Rays)
Part-1
Neils Bohr gave forward his model of atom with answeres most of the flaws that Rutherford
model had. This model introduced quantization principal and this model is regarded as first
quantum mechanical model. We will explore in detail, this structure of atom.
We will also look into X - ray formation which is a converse process of photoclectric effect and
will examine Moreley's law in pantium.
THE BOHR THEORY OF HYDROGE ATOM (AND HYDROGEN LIKE ATOM):
Bohr gave following postulates for electron in hydrogen atom :• An electron in an atom could resolve in certain stable orbits without the emission of radiant
energy.
• An electron resolves around the nucleus only in those orbits for which the angular momentum
is some integral multiple of
L=
, where n
. Thus angular of electron is QUANTAIZED.
principal quantum number.
• An electron might a transition from one of its specified non-radiating orbits to another of
lower energy. When it does so, a single photon is amitted having energy equal to the energy
difference between the initial and final slater.
The frequency of emitted photon is given by
h = Ei - Ef
Dumb Question:- Are these equations valid for all atoms ?
Ans:- No, equations are valid only for single electron system, i.e. systems where only one
electron is present. Ideally this equation applies only to Hydrogen atom, Singly ionized helium
He+, and doubly ionized Lithium Li+ +.
In Bohr's model, radius of nth orbit is given by rn =
=
if values of constant are evaluate then,
and speed of electron is given by Vn
rn = 0.529 n2/z
where n
z
and Vn = 2.19 X 106
m/sec.
Principal quantum number/shell number.
atomic number of nucleus involved.
Why ?
from Bohr's postulate, angular momentum of electron in nth orbit is L =
mechanics L = mvnrn
mvnrn =
also from
............................................... (1)
for electron to resolve in its orbit, Electrostatic force is providing the required centripetal
force.
Solving (1) & (2) simultaneously yields the required result.