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Silica Sulfuric Acid Promotes Aza-Michael Addition Reactions under
Silica Sulfuric Acid Promotes Aza-Michael Addition Reactions under

... performed by stirring an intimate mixture of PTEA (1.0 mmol), morpholine (1.2 mmol) and silica (240-400 mesh, 100 mg) at room temperature. No aza-Michael addition product was formed even after 24 h, which indicate that the requirement of SiO2-SO3H is key factor for the successful outcome of the reac ...
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... production of ammonia because two molecules of gaseous ammonia occupy a smaller volume than the four molecules of gaseous reactants.  High pressure also increases the reaction rate because the gas molecules are closer and at higher concentrations. However, high-pressure equipment is expensive and r ...
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... oxygen, with smaller amounts of other gases, such as carbon dioxide and water vapor. Some days the air has more water vapor, or is more humid, than on other days. But regardless of the ratio of the components, air is still a mixture. ...
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... Negligible attractive forces between the particles: Also explains why a gas expands to fill its container ...
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158KB - NZQA

... Whereas HCOOH is a weak acid, it does not readily dissociate in water. HCOOH(aq) + H2O()  H3O+(aq) + HCOO–(aq) [H3O+] = 0.00398mol L–1 In the resulting solutions, HCl has a higher concentration of H 3O+, and therefore a lower pH (1) than HCOOH, which has a lower concentration of H3O+, and therefor ...
Reaction Rates
Reaction Rates

... The “end result” ...
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Reaction Rate Reading Packet

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Example of Boltzmann distribution.
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Porous silicon-based nanostructured microparticles as degradable
Porous silicon-based nanostructured microparticles as degradable

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KHSO4-SiO2-MeOH – An efficient selective solid
KHSO4-SiO2-MeOH – An efficient selective solid

... zeolite3c, acid resin4, etc that are generally in use suffer from certain limitations such as requirement in large volume, pore size dependency, substrate specificity, etc. Recently selective cleavage of only prenyl esters using silica-supported sodium hydrogen sulphate in a nonprotic solvent was re ...
Chemistry 116: General Chemistry
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QUIZ: History of Atomic Structure

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... Distinguish among kinetic, potential, and other forms of energy Apply the theory of conservation of matter in balancing chemical reactions. Classify changes of state in terms of endothermic and exothermic processes Classify mixtures as being homogenous or heterogeneous ...
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... coefficients (2 and 2). In pairs, have students use stoichiometry to determine which bottle will make the pop sound first. Answer: bottle 3 is the only bottle that will fully use all of the O2 and H2 to react in a combustion reaction (having .5/3 L of O2 and 2*.5/3 L H2, the optimal ratio for the co ...
Jon Abbatt - Earth, Atmospheric, and Planetary Physics
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Silica supported zinc chloride catalyzed acetylation of amines
Silica supported zinc chloride catalyzed acetylation of amines

... In the area of green chemistry, the development of heterogeneous catalysts has played an important role, since they offer several advantages such as clean reaction conditions, easy separation of the catalyst from the reaction medium, greater selectivity and generally give higher yield of products an ...
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Stöber process

The Stöber process is a physical chemistry process for the generation of monodisperse particles of silica. The process was discovered in 1968 by Werner Stöber et al. building on earlier work by G. Kolbe in published in 1956. The topic has since been widely researched. Tetraethyl orthosilicate is added to an excess of water containing a low molar-mass alcohol such as ethanol and containing ammonia. The resulting solution is then stirred. The resulting silica particles have diameters between 50 and 2000 nanometers depending on type of silicate ester used, type of alcohol used and volume ratios. A particle size up to 1000 micrometres has been reported in a modified emulsion technique. The reactions taking place are hydrolysis of the silyl ether to a silanol followed by condensation reactions. The particles have been analysed by light scattering.The process is believed to take place via a LaMer model (monomer addition) in which nucleation is a fast process, followed by a particle growth process without further nucleation. In an alternative model called controlled aggregation, the particles grow by aggregation of smaller particles. This model is supported by microgravity experiments and by SAXS analysis. Kinetics have been investigated with variation in pH.Reported morphological variations are a PEG graft and core-shell morphologies based on cyclen, polyamines and polystyrene.Microporous silica particles can be obtained through organic templating followed by calcination. Reported organic additives for this process are cetyltrimethylammonium bromide and glycerol
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