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Introduction to Biophysical Chemistry
Introduction to Biophysical Chemistry

... Assignments may be handed in either in class or before class to Ms. Priscilla Boon. If the office is closed, the homework may be slipped under the door. Graded homework will be returned in class; otherwise, it may be picked up from the teaching assistants. Please staple all work. Ch 24a Web Site Han ...
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... The are two useful results for large N . One is the central limit theorem and the other is the large deviation theory. Central limit theorem.– We define the scaled variable ...
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... uniform temperature is attained throughout the combined system. The system is then in thermal equilibrium. Experience shows, all systems which are in thermal equilibrium with a given system are also in thermal equilibrium with each other. This principle defines the temperature of a thermodynamic sys ...
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... Gas Chromatography (GC) GC is currently one of the most popular methods for separating and analyzing compounds. This is due to its high resolution, low limits of detection, speed, accuracy and reproducibility. GC can be applied to the separation of any compound that is either naturally volatile (i. ...
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Chapter 7: Conservation of Mechanical Energy in Spring Problems

... The previous example involved essentially just one particle, the car. The wall was fixed there as a device for exerting a constant force during the collision. A more complex example can be studied when two particles collide. We first make the approximation that the two particles are subjected to no ...
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... The previous example involved essentially just one particle, the car. The wall was fixed there as a device for exerting a constant force during the collision. A more complex example can be studied when two particles collide. We first make the approximation that the two particles are subjected to no ...
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Gibbs paradox

In statistical mechanics, a semi-classical derivation of the entropy that does not take into account the indistinguishability of particles, yields an expression for the entropy which is not extensive (is not proportional to the amount of substance in question). This leads to a paradox known as the Gibbs paradox, after Josiah Willard Gibbs. The paradox allows for the entropy of closed systems to decrease, violating the second law of thermodynamics. A related paradox is the ""mixing paradox"". If one takes the perspective that the definition of entropy must be changed so as to ignore particle permutation, the paradox is averted.
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