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B - eko.olunet.org
B - eko.olunet.org

... Purity Grade of Compounds 3. In chemical experiments, the purity of the starting material and the composition of impurities/additives are of great importance. For his experiments, Thomas needed KBr with at least 95.0% purity. In order to determine the purity of an available inorganic compound, he w ...
CH100: Fundamentals for Chemistry
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... component substances by physical means only by a chemical process  The breakdown of a pure substance results in formation of new substances (i.e. chemical change)  For a pure substance there is nothing to separate (its only 1 substance to begin with) ...
Unit 5 Student Packet
Unit 5 Student Packet

CHEM 101 Final (Term 14​1)
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... C) The pressure at the triple point for substance A is higher than that of substance B, but the normal boiling and normal melting point for substance A are lower than those of substance B. D) The pressure at the triple point, normal boiling and normal melting point for substance B and for substance ...
Department of Chemistry First Year Syllabus
Department of Chemistry First Year Syllabus

Gas-Phase Reactions of Fe (CH2O)+ and Fe (CH2S)+ with Small
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... bonding differences between Fe(CH2O)+ and Fe(CH2S)+. To do this, product ion structures were probed by collision-induced dissociation, specific ion-molecule reactions, and use of labeled compounds, and experimental bond energies were obtained by using ion-molecule bracketing and competitive collisio ...
AP Chemistry Review Preparing for the AP
AP Chemistry Review Preparing for the AP

... Review your incorrect MC from the Practice Exam and understand the concepts. Know the 6 strong acids HCl, HI, HBr, H2SO4, HClO4, HNO3 and the one weak by formula acetic acid CH3COOH, everything else is weak. Remember that strong acids/bases don’t make buffers!!! You should be 100% confident what ion ...
2H 2 O(g)
2H 2 O(g)

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Exames anteriores a 1994
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AP - 04 - Reactions in Aqueous Solutions
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Chapter 5
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...  Energy of the universes (system + surroundings) is constant.  Any energy transferred from a system must be transferred to the surroundings (and vice versa). From the first law of thermodynamics: When a system undergoes a physical or chemical change, the change in internal energy is given by the h ...
Theoretical Study of Gas-Phase Reactions of Fe(CO)5 with OH
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Chapter 4 - Colby College Wiki
Chapter 4 - Colby College Wiki

... concentration. If it takes 17.8 mL of the potassium hydroxide solution to turn the indicator (phenolphthalein) slightly pink, what is the concentration of the hydrobromic acid solution? • The above process is known as a titration – the careful addition of one solution to another until one component ...
CHEM110P1_06_2015_Y_P1
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THERMOCHEMISTRY or Thermodynamics
THERMOCHEMISTRY or Thermodynamics

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Hydrogen Bonding
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revised Chemical Kinetics
revised Chemical Kinetics

... This is because molecules must collide in order to react. The more concentrated the reactants, the greater the number of molecules in any given volume, and therefore, the greater the number of molecular collisions. Not every molecular collision between reactant molecules will lead to reaction, but s ...
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Bioorthogonal chemistry



The term bioorthogonal chemistry refers to any chemical reaction that can occur inside of living systems without interfering with native biochemical processes. The term was coined by Carolyn R. Bertozzi in 2003. Since its introduction, the concept of the bioorthogonal reaction has enabled the study of biomolecules such as glycans, proteins, and lipids in real time in living systems without cellular toxicity. A number of chemical ligation strategies have been developed that fulfill the requirements of bioorthogonality, including the 1,3-dipolar cycloaddition between azides and cyclooctynes (also termed copper-free click chemistry), between nitrones and cyclooctynes, oxime/hydrazone formation from aldehydes and ketones, the tetrazine ligation, the isocyanide-based click reaction, and most recently, the quadricyclane ligation.The use of bioorthogonal chemistry typically proceeds in two steps. First, a cellular substrate is modified with a bioorthogonal functional group (chemical reporter) and introduced to the cell; substrates include metabolites, enzyme inhibitors, etc. The chemical reporter must not alter the structure of the substrate dramatically to avoid affecting its bioactivity. Secondly, a probe containing the complementary functional group is introduced to react and label the substrate.Although effective bioorthogonal reactions such as copper-free click chemistry have been developed, development of new reactions continues to generate orthogonal methods for labeling to allow multiple methods of labeling to be used in the same biosystems.
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