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chemistry
chemistry

... 71 Determine the total number of moles of sodium hydrogen carbonate that will completely react with 0.010 mole of citric acid. [1] ...
equilibrium - TeacherWeb
equilibrium - TeacherWeb

... Once equilibrium is established, the concentrations of A and B do not change. The equilibrium is dynamic, the forward and reverse reactions continue occurring at the same rate. To indicate that the reaction proceeds in both the forward and reverse directions, use a double arrow. ...
Stoichiometry of Chemical Reactions
Stoichiometry of Chemical Reactions

Stoichiometry of Chemical Reactions
Stoichiometry of Chemical Reactions

... of atoms on either side of the arrow and comparing these sums to ensure they are equal. Note that the number of atoms for a given element is calculated by multiplying the coefficient of any formula containing that element by the element’s subscript in the formula. If an element appears in more than ...
Original powerpoint (~1.9 MB)
Original powerpoint (~1.9 MB)

... is spontaneous even though H2O ...
Downloaded on 2017-02
Downloaded on 2017-02

... of HX does not occur in this situation. By contrast, desorption of HX from AlX2 was observed in calculations by Elliott and Greer, 12 but that model used higher OH coverage and thus higher-coordinated OH. In order to check the effect of cooperation between the remaining fragments on the second HX de ...
aq - HCC Learning Web
aq - HCC Learning Web

... • Aqueous solutions of lead(II) nitrate and potassium iodide produce a yellow precipitate of lead(II) iodide and an aqueous solution of potassium nitrate Pb(NO3)2(aq) + KI(aq)  PbI2(s) + KNO3(aq) • Aqueous solutions of calcium nitrate and sodium carbonate react to give a white precipitate of calciu ...
Chemistry 1250 - Sp17 Solutions for Midterm 1
Chemistry 1250 - Sp17 Solutions for Midterm 1

... This is a limiting reactant problem. These are just stoichiometry problems. There is more than one way to do a LR problem. In this case it’s asking for the limiting reactant and the mass of excess reactant remaining after completion of the reaction. 2 Fe(OH)3 (s) + 3 H2SO4 (aq) v Fe2(SO4)3 (aq) + 6 ...
The Bio-Organometallic Chemistry of Technetium and Rhenium
The Bio-Organometallic Chemistry of Technetium and Rhenium

... metal can readily change its oxidation and coordination numbers makes it difficult to develop high yielding reactions that result in the formation of only a single compound. This is made even more difficult in radiopharmaceutical chemistry where reactions are performed in water under highly dilute r ...
Topic 4 - Lloyd Crosby
Topic 4 - Lloyd Crosby

... A process in which an element loses one or more electrons, causing its oxidation number to increase The term was first applied to the combining of others elements, particularly metals, with oxygen. e. Reduction A process in which an element gains one or more electrons, causing its oxidation number t ...
Redox Introduction
Redox Introduction

... To indicate electron changes, we look at the oxidation numbers of the atoms in the reaction. The oxidation number is the charge an atom appears to have when we assign a certain number of electrons to given atoms or ions. Any change of oxidation numbers in the course of a reaction indicates an oxidat ...
Computers_in_chemistry - University of St Andrews
Computers_in_chemistry - University of St Andrews

... We want to construct a theoretical model that will predict solubility for druglike molecules … We expect our model to use real physics and chemistry and to give some insight … We don’t expect it to be fast by informatics standards, but it should be reasonably accurate … ...
Enzymes: “Helper” Protein molecules
Enzymes: “Helper” Protein molecules

...  Each enzyme is the specific helper to a specific reaction each enzyme needs to be the right shape for the job  enzymes are named for the reaction they help ...
Chemical Equilibrium – Le Chatelier`s Principle
Chemical Equilibrium – Le Chatelier`s Principle

... However, the value of Kc will depend on the ionic strength. All equilibrium constants depend on temperature and pressure (or volume). In this laboratory we will study Le Châtelier's Principle If a chemical system at equilibrium experiences a change in concentration, temperature, volume, or partial p ...
4.1 Writing and Balancing Chemical Equations
4.1 Writing and Balancing Chemical Equations

Problem 5. Inorganic chains and rings
Problem 5. Inorganic chains and rings

... or aluminates … Product B, in the form of well-crystallized sky-blue rods, remains stable at 0C if kept free of H2O and CO2… A solution of B in 50% potassium hydroxide turns grassy green upon heating or dilution; simultaneously, C is precipitated. In a pure form, salt D, which is a main constituent ...
N Goalby chemrevise.org 1 2.5 Transition Metals Substitution
N Goalby chemrevise.org 1 2.5 Transition Metals Substitution

... The copper complex ion has changed from having unidentate ligands to a multidentate ligand. In this reaction there is an increase in the entropy because there are more moles of products than reactants (from 2 to 7), creating more disorder. The enthalpy change is small as there are similar numbers of ...
Water: The Universal Solvent
Water: The Universal Solvent

... weighed out to make this solution? – 2.94 g K2Cr2O7 ...
K eq
K eq

...  does not increase the partial pressure of the other gases in the mixture adding an inert gas to the mixture has no effect on the position of equilibrium  does not effect the partial pressures of the gases in the reaction ...
H - sintak
H - sintak

... Since both graphite and oxygen are stable allotrophic forms, ∆H°ƒ (C, graphite) and ∆H°ƒ (O2, g) are zero. ∆H°rxn = (1mol) ∆H°ƒ (CO2, g) = -393.5 kJ ∆H°ƒ (CO2, g) = -393.5 kJ/mol ...
Equilibrium notes (complete)
Equilibrium notes (complete)

... • It’s like we dumped some water on the high gas side (reactants) • The reaction shifts to the right to compensate (want fewer gases at high pressure) • More reactants become products Cl2 ...
Unit #8 - consumerchem
Unit #8 - consumerchem

... : in the presence of a catalyst. i) Catalyst - 1. a substance that speeds up a chemical reaction without being used up. 2. Lowers the activation energy. 3. Enzymes are biological catalysts. ...
LIQUIDS
LIQUIDS

... an element into smaller and smaller pieces you would eventually come to a piece that could not be divided any further - a single ATOM of the element. Atoms are therefore very small. We can see this if we dilute a solution of potassium manganate(VI) many times. It is still coloured even when it is ve ...
SAT - mvhs-fuhsd.org
SAT - mvhs-fuhsd.org

17 ADSORPTION AND CATALYSIS S MODULE - 5
17 ADSORPTION AND CATALYSIS S MODULE - 5

... 5. Mordants are used during dyeing process with certain dyes. In such cases, the mordants fix the dye on the fabric by adsorption. ...
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Bioorthogonal chemistry



The term bioorthogonal chemistry refers to any chemical reaction that can occur inside of living systems without interfering with native biochemical processes. The term was coined by Carolyn R. Bertozzi in 2003. Since its introduction, the concept of the bioorthogonal reaction has enabled the study of biomolecules such as glycans, proteins, and lipids in real time in living systems without cellular toxicity. A number of chemical ligation strategies have been developed that fulfill the requirements of bioorthogonality, including the 1,3-dipolar cycloaddition between azides and cyclooctynes (also termed copper-free click chemistry), between nitrones and cyclooctynes, oxime/hydrazone formation from aldehydes and ketones, the tetrazine ligation, the isocyanide-based click reaction, and most recently, the quadricyclane ligation.The use of bioorthogonal chemistry typically proceeds in two steps. First, a cellular substrate is modified with a bioorthogonal functional group (chemical reporter) and introduced to the cell; substrates include metabolites, enzyme inhibitors, etc. The chemical reporter must not alter the structure of the substrate dramatically to avoid affecting its bioactivity. Secondly, a probe containing the complementary functional group is introduced to react and label the substrate.Although effective bioorthogonal reactions such as copper-free click chemistry have been developed, development of new reactions continues to generate orthogonal methods for labeling to allow multiple methods of labeling to be used in the same biosystems.
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