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Problem Set 4
Problem Set 4

Molecules of Life – Part 2
Molecules of Life – Part 2

... A. Proteins make up greater than 50% of an organisms dry weight (referred to as biomass). B. This is another important example of the theme: Structure = Function. (These are very large 3-D Molecules.) C. The monomer “building blocks” are Amino Acids (There are 20 different Amino Acids that can be in ...
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An Active Metamaterial Platform for Chiral Responsive Optoelectronics
An Active Metamaterial Platform for Chiral Responsive Optoelectronics

... Chiral metamaterials are an important metamaterial species that give rise to enormously strong chiroptical responses. The past few years have witnessed an explosive development of chiral optical metamaterials that exhibit circular dichroism and optical rotation orders of magnitude larger than natura ...
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Circular dichroism



Circular dichroism (CD) is dichroism involving circularly polarized light, i.e., the differential absorption of left- and right-handed light. Left-hand circular (LHC) and right-hand circular (RHC) polarized light represent two possible spin angular momentum states for a photon, and so circular dichroism is also referred to as dichroism for spin angular momentum. This phenomenon was discovered by Jean-Baptiste Biot, Augustin Fresnel, and Aimé Cotton in the first half of the 19th century. It is exhibited in the absorption bands of optically active chiral molecules. CD spectroscopy has a wide range of applications in many different fields. Most notably, UV CD is used to investigate the secondary structure of proteins. UV/Vis CD is used to investigate charge-transfer transitions. Near-infrared CD is used to investigate geometric and electronic structure by probing metal d→d transitions. Vibrational circular dichroism, which uses light from the infrared energy region, is used for structural studies of small organic molecules, and most recently proteins and DNA.
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