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1442 Final Review
1442 Final Review

... In any spontaneous process, the entropy of the system always increases. All spontaneous processes are exothermic. Any spontaneous process is accompanied by a positive free energy change. In order for a process to be spontaneous, the process must be exothermic and the entropy of the system must incre ...
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Press here to hemy 102 lab manual

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... of heat. The energy change of a reaction that occurs at constant pressure is termed the heat of reaction or the enthalpy change. The symbol ΔH is used to denote the enthalpy change. If heat is evolved, the reaction is exothermic (ΔH  0); and if heat is absorbed, the reaction is endothermic (ΔH  0) ...
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... hexane, two immiscible solvents. The lower water layer contains the compound hexanedioyl dichloride, Cl ...
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Liquid chromatography: a tool for the analysis of metal species

... and sodium ions for the common stationary phases containing sulphonate or carboxylate cation-exchange functional groups. This problem has been solved by a column-switching technique which enables the determination of trace concentrations of the common inorganic cations (Li, Na, K, Mg, Ca) and ammoni ...
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... cm3). The solution was boiled with analytical-grade metallic tin (10 g) until the solution became colorless and the deposited copper was covered with a grey coating of tin. The resultant solution was filtered and treated with an ammonia-water solution until the complete precipitation of a product. I ...
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Estimate the strength of given sodium carbonate solution

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... Analyze: We are given the concentration of the ionic compound used to make the solution and asked to determine the concentrations of the ions in the solution. Plan: We can use the subscripts in the chemical formula of the compound to determine the relative concentrations of the ions. Solve: Calcium ...
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... 53. How many atoms (molecules), how much volume and how many grams does one mole of chlorine gas have? 1 mol Cl2 = 22.4 Liters 1 mol Cl2 = 6.02 x 1023 molecules 1 mol Cl2 = 70.90 grams 54. State the Law of Conservation of Mass. States that mass is neither created nor destroyed in any process but is ...
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Liquid–liquid extraction



Liquid–liquid extraction (LLE) consists in transferring one (or more) solute(s) contained in a feed solution to another immiscible liquid (solvent). The solvent that is enriched in solute(s) is called extract. The feed solution that is depleted in solute(s) is called raffinate.Liquid–liquid extraction also known as solvent extraction and partitioning, is a method to separate compounds based on their relative solubilities in two different immiscible liquids, usually water and an organic solvent. It is an extraction of a substance from one liquid into another liquid phase. Liquid–liquid extraction is a basic technique in chemical laboratories, where it is performed using a variety of apparatus, from separatory funnels to countercurrent distribution equipment. This type of process is commonly performed after a chemical reaction as part of the work-up.The term partitioning is commonly used to refer to the underlying chemical and physical processes involved in liquid–liquid extraction, but on another reading may be fully synonymous with it. The term solvent extraction can also refer to the separation of a substance from a mixture by preferentially dissolving that substance in a suitable solvent. In that case, a soluble compound is separated from an insoluble compound or a complex matrix.Solvent extraction is used in nuclear reprocessing, ore processing, the production of fine organic compounds, the processing of perfumes, the production of vegetable oils and biodiesel, and other industries.Liquid–liquid extraction is possible in non-aqueous systems: In a system consisting of a molten metal in contact with molten salts, metals can be extracted from one phase to the other. This is related to a mercury electrode where a metal can be reduced, the metal will often then dissolve in the mercury to form an amalgam that modifies its electrochemistry greatly. For example, it is possible for sodium cations to be reduced at a mercury cathode to form sodium amalgam, while at an inert electrode (such as platinum) the sodium cations are not reduced. Instead, water is reduced to hydrogen. A detergent or fine solid can be used to stabilize an emulsion, or third phase.
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