
Chemical Reactions
... There are many kinds of chemical reactions and several ways to classify them. One useful method of classifies reactions into four major types. These are: 1.) synthesis; 2.) decomposition; 3.) single replacement; and 4.) double replacement reactions. Not all reactions can be put into one of these cat ...
... There are many kinds of chemical reactions and several ways to classify them. One useful method of classifies reactions into four major types. These are: 1.) synthesis; 2.) decomposition; 3.) single replacement; and 4.) double replacement reactions. Not all reactions can be put into one of these cat ...
Topic 16 notes - A
... The isomer which rotates plane polarised light clockwise is given the prefix (+) or D-. The isomer which rotates plane polarised light anticlockwise is given the prefix (-) or L-. iii) Importance of optical isomers in biochemistry Optical isomers show identical chemical properties in most reactions. ...
... The isomer which rotates plane polarised light clockwise is given the prefix (+) or D-. The isomer which rotates plane polarised light anticlockwise is given the prefix (-) or L-. iii) Importance of optical isomers in biochemistry Optical isomers show identical chemical properties in most reactions. ...
Carbohydrates
... 1. Ketoses (Sugars with Ketone groups) vs Aldoses (Sugars with Aldehyde groups) 2. Fischer projections a. Aldose D family: triose – tetrose - pentose – hexose (Figure 23-3) b. Erythro and Threo: History as hydroxyl groups on same or opposite side of Fischer projection in tetroses (Section 23-4) c. D ...
... 1. Ketoses (Sugars with Ketone groups) vs Aldoses (Sugars with Aldehyde groups) 2. Fischer projections a. Aldose D family: triose – tetrose - pentose – hexose (Figure 23-3) b. Erythro and Threo: History as hydroxyl groups on same or opposite side of Fischer projection in tetroses (Section 23-4) c. D ...
Table
... Condensation Reaction Pathway to other compounds Ester+NaOH sodium salt of acid+ alcohol Hydrolysis; saponification Preparation Amines: RX+NH3 amine + HX RX+R2NH amine +HX Amide +H2Ocarboxyic acid + amine (hydrolysis reaction) Amides Carboxylic acid + amine amide + H2O (condensation reaction) ...
... Condensation Reaction Pathway to other compounds Ester+NaOH sodium salt of acid+ alcohol Hydrolysis; saponification Preparation Amines: RX+NH3 amine + HX RX+R2NH amine +HX Amide +H2Ocarboxyic acid + amine (hydrolysis reaction) Amides Carboxylic acid + amine amide + H2O (condensation reaction) ...
CHEMICAL REACTIONS
... (s) after the formula –solid Cu(s) (g) after the formula –gas H2 (g) (l) after the formula -liquid H2O(l) (aq) after the formula - dissolved in water, an aqueous solution. CaCl2 (aq) used after a product indicates a gas (same as (g)) O2 used after a product indicates a solid (same as (s)) ...
... (s) after the formula –solid Cu(s) (g) after the formula –gas H2 (g) (l) after the formula -liquid H2O(l) (aq) after the formula - dissolved in water, an aqueous solution. CaCl2 (aq) used after a product indicates a gas (same as (g)) O2 used after a product indicates a solid (same as (s)) ...
Organic Chemistry: An Indian Journal
... unsymmetrical ethers. The Williamson reaction generally involves the employment of an alkali-metal salt of the hydroxyl compound and an alkyl halide. These reactions are generally carried out using organic solvents or with phase-transfer catalysts in the presence of a base followed by refluxing for ...
... unsymmetrical ethers. The Williamson reaction generally involves the employment of an alkali-metal salt of the hydroxyl compound and an alkyl halide. These reactions are generally carried out using organic solvents or with phase-transfer catalysts in the presence of a base followed by refluxing for ...
Dehydration of 3,3-dimethyl-2-butanol to make alkenes March 1 & 3
... Organic Chemistry Lab II, Spring 2009 Dr. Milkevitch March 1 & 3, 2010 ...
... Organic Chemistry Lab II, Spring 2009 Dr. Milkevitch March 1 & 3, 2010 ...
Lecture 14a - UCLA Chemistry and Biochemistry
... from d= ~3.1-3.7 ppm and d= ~5.2-5.4 ppm Presence of the aromatic and ferrocene protons with the appropriate splitting pattern and integration The oxidation product only displays one protons for the five-membered ring at d= ~6.5 ppm 13C-NMR spectrum Presence of two additional carbon atoms (o ...
... from d= ~3.1-3.7 ppm and d= ~5.2-5.4 ppm Presence of the aromatic and ferrocene protons with the appropriate splitting pattern and integration The oxidation product only displays one protons for the five-membered ring at d= ~6.5 ppm 13C-NMR spectrum Presence of two additional carbon atoms (o ...
Week - Syllabus | Chaminade
... career interests, the multi-dimensionality of this discipline can be demonstrated much more easily. It is hoped that at the end of the semester, the student will be fulfilled intellectually, in addition to accumulating the knowledge, which is essential for his/her studies in molecular and/or biomedi ...
... career interests, the multi-dimensionality of this discipline can be demonstrated much more easily. It is hoped that at the end of the semester, the student will be fulfilled intellectually, in addition to accumulating the knowledge, which is essential for his/her studies in molecular and/or biomedi ...
Liquid-gas phase-boundary catalytic system
... protocols for producing orientated ordered inorganic-surfactant was reported but only based on simulation theory. The use of TiO2 as inorganic precursor and organic surfactant, however, has not been reported. In our recent report [5 ], well-aligned titanium dioxide was successfully synthesized by s ...
... protocols for producing orientated ordered inorganic-surfactant was reported but only based on simulation theory. The use of TiO2 as inorganic precursor and organic surfactant, however, has not been reported. In our recent report [5 ], well-aligned titanium dioxide was successfully synthesized by s ...
Taylor`s Organic Reactions Summary Sheet
... Undergo substitution reactions, and combustion reactions (clean) Substitution Reaction: A reaction in which a hydrogen atom is replaced by another atom or group of atoms; reaction of alkanes or aromatics with halogens to produce organic halides and hydrogen halides. ...
... Undergo substitution reactions, and combustion reactions (clean) Substitution Reaction: A reaction in which a hydrogen atom is replaced by another atom or group of atoms; reaction of alkanes or aromatics with halogens to produce organic halides and hydrogen halides. ...
Today`s literature presentation = 2/5th trivia + 2/5th
... Oxidation of alcohol to carbonyl rarely used. Heavy metals used in most of theses cause problems in removal, must be present <10 ppm levels. Many oxidizing agents are high energy species, giving rise to thermal hazards at scale. ...
... Oxidation of alcohol to carbonyl rarely used. Heavy metals used in most of theses cause problems in removal, must be present <10 ppm levels. Many oxidizing agents are high energy species, giving rise to thermal hazards at scale. ...
hc1(8)notes
... • Classify a reaction as a synthesis, decomposition, singledisplacement, double-displacement, or combustion reaction. • Predict the products of simple reactions given the reactants. ...
... • Classify a reaction as a synthesis, decomposition, singledisplacement, double-displacement, or combustion reaction. • Predict the products of simple reactions given the reactants. ...
Production of synthesis gas
... First , in the Air separation section the oxygen are produced with 99.5 vol% purity . Second , in the soot recovery and recycle section the Naphtha stripper recycle are produced which is fed to oxidizer reactor . Third, in the partial oxidation and heat recovery section the vacuum feedstock's is fe ...
... First , in the Air separation section the oxygen are produced with 99.5 vol% purity . Second , in the soot recovery and recycle section the Naphtha stripper recycle are produced which is fed to oxidizer reactor . Third, in the partial oxidation and heat recovery section the vacuum feedstock's is fe ...
BOC-ON - Sigma
... Active Analog of the C-Terminal Heptapeptide with ,-Hydroxynorleucine Sulfate Replacing Tyrosine Sulfate. J. Med. Chem. 1978, 21, 1030. 13 Cachia, P.J.; Sykes, B.D.; Hodges, R.S. Calcium-dependant Inhibitory Region of Troponin: A protein Nuclear Magnetic Resonance Study of the Interaction between T ...
... Active Analog of the C-Terminal Heptapeptide with ,-Hydroxynorleucine Sulfate Replacing Tyrosine Sulfate. J. Med. Chem. 1978, 21, 1030. 13 Cachia, P.J.; Sykes, B.D.; Hodges, R.S. Calcium-dependant Inhibitory Region of Troponin: A protein Nuclear Magnetic Resonance Study of the Interaction between T ...
Catalytic, Enantioselective Alkylations of N,O- and
... acetophenone developed. In addition, the alcohol proton disappeared, indicating Osilylation (Scheme 1). A second equiv of enol silane 4a was then added to the mixture and the reaction was monitored; no product formation was noted even after extended periods of time. After addition of the catalyst 2 ...
... acetophenone developed. In addition, the alcohol proton disappeared, indicating Osilylation (Scheme 1). A second equiv of enol silane 4a was then added to the mixture and the reaction was monitored; no product formation was noted even after extended periods of time. After addition of the catalyst 2 ...
Chem 3.5 Questions 09
... Compound G is a structural isomer of A with the same functional group. Compare and contrast the reactions of G with the reagents in question (a) to that of compound A. Your answer should include: ...
... Compound G is a structural isomer of A with the same functional group. Compare and contrast the reactions of G with the reagents in question (a) to that of compound A. Your answer should include: ...
Document
... anti-cancer reagent. Developed a new type of non-toxic compounds, which are highly effective for curing theschistosomiasis. 2. RNA and DNA cleavage reagents Discovered that the N-phospho-histidine could cleave RNA and DNA by hydrolysis on the phospho-diester bond, Also found that N-phospho-serine i ...
... anti-cancer reagent. Developed a new type of non-toxic compounds, which are highly effective for curing theschistosomiasis. 2. RNA and DNA cleavage reagents Discovered that the N-phospho-histidine could cleave RNA and DNA by hydrolysis on the phospho-diester bond, Also found that N-phospho-serine i ...
SPECTRA Q - the British School of Bahrain
... The spectrum of substance C is spectrum number .......................................... ...
... The spectrum of substance C is spectrum number .......................................... ...
Toluenediamine
... toluylenediamine is one of the standard processes of industrial organic chemistry. The worldwide production exceeded 900 million ton per year in 1998. The reduction of dinitrotoluene is characterized by its strong exotherm of >1100 kJ/mol. Due to this fact combined with the thermal instability of th ...
... toluylenediamine is one of the standard processes of industrial organic chemistry. The worldwide production exceeded 900 million ton per year in 1998. The reduction of dinitrotoluene is characterized by its strong exotherm of >1100 kJ/mol. Due to this fact combined with the thermal instability of th ...
Ch 26 C-C bond formation
... Usefulness of Metathesis Reactions • Because olefin metathesis is an equilibrium process and with many alkene substrates yields a mixture of starting material and two or more alkene products, it is useless for preparative processes. • However, with terminal alkenes, one metathesis product is ethyle ...
... Usefulness of Metathesis Reactions • Because olefin metathesis is an equilibrium process and with many alkene substrates yields a mixture of starting material and two or more alkene products, it is useless for preparative processes. • However, with terminal alkenes, one metathesis product is ethyle ...
Enantioselective synthesis

Enantioselective synthesis, also called chiral synthesis or asymmetric synthesis, is defined by IUPAC as: a chemical reaction (or reaction sequence) in which one or more new elements of chirality are formed in a substrate molecule and which produces the stereoisomeric (enantiomeric or diastereoisomeric) products in unequal amounts.Put more simply: it is the synthesis of a compound by a method that favors the formation of a specific enantiomer or diastereomer.Enantioselective synthesis is a key process in modern chemistry and is particularly important in the field of pharmaceuticals, as the different enantiomers or diastereomers of a molecule often have different biological activity.