• Study Resource
  • Explore
    • Arts & Humanities
    • Business
    • Engineering & Technology
    • Foreign Language
    • History
    • Math
    • Science
    • Social Science

    Top subcategories

    • Advanced Math
    • Algebra
    • Basic Math
    • Calculus
    • Geometry
    • Linear Algebra
    • Pre-Algebra
    • Pre-Calculus
    • Statistics And Probability
    • Trigonometry
    • other →

    Top subcategories

    • Astronomy
    • Astrophysics
    • Biology
    • Chemistry
    • Earth Science
    • Environmental Science
    • Health Science
    • Physics
    • other →

    Top subcategories

    • Anthropology
    • Law
    • Political Science
    • Psychology
    • Sociology
    • other →

    Top subcategories

    • Accounting
    • Economics
    • Finance
    • Management
    • other →

    Top subcategories

    • Aerospace Engineering
    • Bioengineering
    • Chemical Engineering
    • Civil Engineering
    • Computer Science
    • Electrical Engineering
    • Industrial Engineering
    • Mechanical Engineering
    • Web Design
    • other →

    Top subcategories

    • Architecture
    • Communications
    • English
    • Gender Studies
    • Music
    • Performing Arts
    • Philosophy
    • Religious Studies
    • Writing
    • other →

    Top subcategories

    • Ancient History
    • European History
    • US History
    • World History
    • other →

    Top subcategories

    • Croatian
    • Czech
    • Finnish
    • Greek
    • Hindi
    • Japanese
    • Korean
    • Persian
    • Swedish
    • Turkish
    • other →
 
Profile Documents Logout
Upload
AP Chemistry
AP Chemistry

... order to make relevant observations and collect data; use the collected data to form conclusions and verify hypotheses; and communicate and compare results and procedures (informally to other experimenters, and also in a formal, written report to the teacher). ...
Document
Document

... • Fuels (e.g. the RM1.92 RM2.10 Ron95) are made up mostly of alkanes. In excess oxygen • CnH2n+2 + (1.5n+½)O2  nCO2 + (n+1)H2O ...
ORGANIC CHEMISTRY
ORGANIC CHEMISTRY

Types of Chemical Reactions
Types of Chemical Reactions

phenol - Knockhardy
phenol - Knockhardy

... • the aromatic ring helps weaken the O-H bond and stabilises the resulting anion • it dissolves very slightly in water to form a weak acidic solution C6H5OH(aq) ...


Exam 1 Review Sheet Chapter 15 Chemistry 110b
Exam 1 Review Sheet Chapter 15 Chemistry 110b

Document
Document

... Because acid chlorides and anhydrides contain good leaving groups, these compounds are very reactive toward nucleophilic substitution by an alcohol, as shown in Equations 7-8. ...
Chapter 16. Biological Reagents
Chapter 16. Biological Reagents

... of glucose-6-phosphate by an enzyme and ATP to fructose 1,6-diphosphate. Show the structure of fructose 1,6-diphosphate. 16.2 The oxidation of ethanol by NAD+ is stereospecific. Only the pro-R hydrogen atom is removed. Which hydrogen atom is the pro-R hydrogen? 16.3 Show a crossed Claisen reaction b ...
The characteristic reaction of aromatic rings
The characteristic reaction of aromatic rings

... 1. In FC alkylation, carbocation rearrangements often occur ...
Discuss on Reactions of Alcohols
Discuss on Reactions of Alcohols

Mon Feb 15 lecture
Mon Feb 15 lecture

(Z)-Tamoxifen and Tetrasubstituted Alkenes and Dienes via a Regio
(Z)-Tamoxifen and Tetrasubstituted Alkenes and Dienes via a Regio

... Alkenol 18 was oxidized with Dess-Martin periodinane in CH2Cl2 to give the corresponding unsaturated aldehyde 20 (96%), which was transformed directly with methyl triphenylphosphonium bromide to give diene 21. Selective hydrogenation of the less hindered double bond (10% Pd/C, H2) afforded (Z)-Tamox ...
CHEMISTRY A
CHEMISTRY A

Hydrocarbon - TeacherWeb
Hydrocarbon - TeacherWeb

... hydrogen atoms, and electrons that are shared among all six carbons in the ring (Draw the structure.) 2. Aromatic Compound: an organic compound that contains a benzene ring ...
06_reactions
06_reactions

Unit F322 - Chains, energy and resources - Visually impaired
Unit F322 - Chains, energy and resources - Visually impaired

... In your answer, you should make clear how each structure fits with the information given above. __________________________________________ __________________________________________ __________________________________________ __________________________________________ ________________________________ ...
Experiment 7 — Nucleophilic Substitution
Experiment 7 — Nucleophilic Substitution

Optical Isomers or Enantiomers
Optical Isomers or Enantiomers

A Floral Fragrance, Methyl Benzoate
A Floral Fragrance, Methyl Benzoate

Activation of C–F bonds using Cp*2ZrH2: a
Activation of C–F bonds using Cp*2ZrH2: a

... Examination of a different olefin helps differentiate these pathways. Reaction of 1 with 1,1-difluoromethylenecyclohexane only occurs slowly upon heating to 80 ⬚C. One observes both the monofluoro and the difluoro reduction products, as shown in eqn. (1). This observation is inconsistent with the H/F meta ...
Reactions of Alkenes and Alkynes
Reactions of Alkenes and Alkynes

... Biological Reactions • Only one substrate molecule at a time is present in the active site of the enzyme where the reaction occurs (necessary reactant groups nearby) • More controlled • More common than laboratory radical reactions ...
Chapter 18  - Hope Charter School
Chapter 18 - Hope Charter School

Review Chapter 19
Review Chapter 19

... Alcohols are a common organic functional group. The prevalence of this group is in no small part due to its myriad of reaction pathways. Alcohols are weak acids, weak bases, nucleophiles and electrophiles. Sometimes it is necessary to cover over this reactivity to react a group e ...
Catalytic, Enantioselective Aldol Additions with Methyl and Ethyl
Catalytic, Enantioselective Aldol Additions with Methyl and Ethyl

< 1 ... 96 97 98 99 100 101 102 103 104 ... 148 >

Ring-closing metathesis



Ring-closing metathesis, or RCM, is a widely used variation of olefin metathesis in organic chemistry for the synthesis of various unsaturated rings via the intramolecular metathesis of two terminal alkenes, which forms the cycloalkene as the E- or Z- isomers and volatile ethylene.The most commonly synthesized ring sizes are between 5-7 atoms; however, reported syntheses include 45- up to 90- membered macroheterocycles. These reactions are metal-catalyzed and proceed through a metallacyclobutane intermediate. It was first published by Dider Villemin in 1980 describing the synthesis of an Exaltolide precursor, and later become popularized by Robert H. Grubbs and Richard R. Schrock, who shared the Nobel Prize in Chemistry, along with Yves Chauvin, in 2005 for their combined work in olefin metathesis. RCM is a favorite among organic chemists due to its synthetic utility in the formation of rings, which were previously difficult to access efficiently, and broad substrate scope. Since the only major by-product is ethylene, these reactions may also be considered atom economic, an increasingly important concern in the development of green chemistry.There are several reviews published on ring-closing metathesis.
  • studyres.com © 2025
  • DMCA
  • Privacy
  • Terms
  • Report