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chapter 5 - chemical reactions
chapter 5 - chemical reactions

... 3. Indicate the state of substances: (g) for gas, (l) for liquid, (s) for solid, and (aq) for aqueous solution. 4. Balance the equation by introducing smallest integer (whole number) coefficients in front of each reactant and product as needed, (coefficient "1" is not shown). The chemical formula of ...
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... geometric isomers). This type of stereoisomer occurs when there is a source of rigidity in the molecule. Cycloalkanes and alkenes both exhibit cis-trans isomers. In cycloalkanes, the closed ring structure restricts rotation about the C-C bond, so the 2 substituents on each ring C may point up or dow ...
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... Table IV shows the association constant for a number of small molecules, i.e. their capacity to associate one with the other when placed in an aqueous solvent. The association constant (which is measured in M-1) is relatively high for molecules that are able to make salt bridges and is of the same o ...
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... more active to oxidation and product were generated in shorter time with high yield. On the other hand, the benzylic alcohols having acceptor groups such as on the phenyl ring have had low activities. Also the benzylic alcohols type 2 such as1phenyl alcohols and benzhydrol has been oxidized slower t ...
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Chem 2423-Test 2 - HCC Learning Web

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... above all in carbon-carbon bond formation, mainly through metal catalysed coupling reactions. In addition, many iodinated aromatic derivatives are used in medicine as drugs or diagnostic aids, contrasting agents, and radioactively labelled markers. The chemistry dealing with selective iodination of ...
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I - Holland Public Schools
I - Holland Public Schools

... * What does collision theory say? In order for a reaction to occur, the reactant particles must physically collide with each other In this case, 2 C2H2’s and 5 O2’s would need to collide in the same place at the same time VERY UNLIKELY * OK, so how does this work then? The chemical reaction is divid ...
Organic Chemistry
Organic Chemistry

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... enhancing their utility The development of such routes to use renewables is desirable in light of the strain on petroleum derived feedstocks. Catalytic hydrogenation of individual amino acids has been studied previously in our laboratory1-4 and elsewhere5,6. Given the complex composition of most bio ...
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Reprint

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Asymmetric induction



Asymmetric induction (also enantioinduction) in stereochemistry describes the preferential formation in a chemical reaction of one enantiomer or diastereoisomer over the other as a result of the influence of a chiral feature present in the substrate, reagent, catalyst or environment. Asymmetric induction is a key element in asymmetric synthesis.Asymmetric induction was introduced by Hermann Emil Fischer based on his work on carbohydrates. Several types of induction exist.Internal asymmetric induction makes use of a chiral center bound to the reactive center through a covalent bond and remains so during the reaction. The starting material is often derived from chiral pool synthesis. In relayed asymmetric induction the chiral information is introduced in a separate step and removed again in a separate chemical reaction. Special synthons are called chiral auxiliaries. In external asymmetric induction chiral information is introduced in the transition state through a catalyst of chiral ligand. This method of asymmetric synthesis is economically most desirable.
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